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It is our understanding that pollen cryopreservation is a safe and practical alternative for conserving genetic material that is often neglected by potential users. The technique has the potential to overcome challenges of breeding programs, such as flowering asynchrony between different parent genotypes, and the production of insufficient pollen in nature. Generally, pollen cryopreservation techniques tend to be simple enough to be used routinely in research, plant breeding and germplasm conservation programs.We report the optical and thermoelectric properties of the two-dimensional Dirac material T-silicene (TS) sheet and nanoribbons (NRs) by first-principles calculations. Both the optical and thermoelectric properties of TS can be modified by tailoring the sheet into nanoribbons of different widths and edge geometries. The optical response of the structures is highly anisotropic. A π interband transition occurs in the visible range of incident light with parallel polarization. The optical response for asymmetric arm-chair TS nanoribbons (ATSNRs) is larger than for symmetric ATSNRs. The absorptions of asymmetric ATSNR are redshifted due to a decrease in the bandgap with the width of the NRs. Plasma frequencies of the sheet and the NRs are identified from the imaginary part of the dielectric function and electron energy loss spectra curves. Thermoelectric properties like electrical conductivity, Seebeck coefficient, power factor, and electronic figure of merit are also studied. Compared with graphene, the TS sheet possesses a higher electrical conductivity and a better figure of merit. Among the NRs, asymmetric ATSNRs exhibit a better thermoelectric performance. Fingolimod ic50 All these intriguing features of TS may shed light on fabricating smart opto-electronic and thermoelectric devices.Curcumin was entrapped in multilayered emulsions to increase its stability and bioavailability. Curcumin emulsion stabilized by whey protein isolate (WPI) was coated with chitosan (CHI) or carboxymethyl konjac glucomannan (CMKGM) alone to form secondary emulsions and their combination in sequence to form the tertiary emulsion, in which, the polyelectrolyte concentrations were 1.0% WPI for the primary emulsion, 0.4% CMKGM for the secondary emulsion -CMKGM, 0.2% CHI for the secondary emulsion -CHI, and 0.1% CMKGM for the tertiary emulsion. link2 The characteristics of the emulsions, including their particle size, ζ potential, microstructure, creaming stability, and biopolymer distribution, were investigated and their colon-targeted delivery potential was evaluated through both in vitro and in vivo studies as well. The curcumin-loaded secondary and tertiary emulsions were stable with a narrow size distribution and were generated by layer-by-layer assembly according to confocal laser scanning microscope observation. When CMKGM was located at the outermost layer, the corresponding secondary and tertiary emulsions showed a greatly reduced release of curcumin in the simulated gastric fluid, but exhibited increased release in the β-mannanase-containing simulated colonic fluid. In vivo evaluation in mice demonstrated that the bioavailability of curcumin in the CMKGM-coated secondary and tertiary emulsions was increased by about 4 folds compared with that of free curcumin and curcumin could be released in a sustainable manner. These results demonstrated that multilayered emulsions coated with CMKGM could promote curcumin absorption in the gastrointestinal tract and hence is a promising colon-targeted delivery system for curcumin.Three structurally intriguing polyoxoniobates (PONbs) based on the trivacant B-type α-Keggin ion TeNb9O33, H4K(CN3H6)2[Cu4(2,2'-bipy)4(H2O)2][TeNb9V2O37]·29H2O (1, 2,2'-bipy = 2,2'-bipyridine), H0.5K5Na2.5[Cu(en)H2O]3[TeNb9V3O39]·10H2O (2, en = ethylenediamine), and K3Na5[Cu(1,3-dap)H2O]3[TeNb9V3O39]·11H2O (3, 1,3-dap = 1,3-diaminopropane), are assembled by the conventional aqueous solution methods using a series of N-containing organic ligands. In 1, each of the two VO4 units is attached to two coplanar NbO6 octahedra on the Nb3O13 cluster of the TeNb9O33 unit. Differently, three VO4 units in 2 and 3 are linked to two edge-sharing NbO6 octahedra, respectively. Compounds 1-3 represent the first oxo NbTeV clusters and also the first vanadoniobates based on the trivacant Keggin PONb units. All three compounds were characterised by single-crystal X-ray structural analysis, TGA and IR, ESI-MS and 51V NMR spectroscopy. Furthermore, the magnetic properties of compounds 1 and 2 were also studied.The unexpected linear group 13 E[triple bond, length as m-dash]E triple bonds were herein uncovered with the D3h-symmetry E2M5+ (M = Li, Na, and K) clusters, where the linear M-E[triple bond, length as m-dash]E-M form is perfectly surrounded by M3 motifs. The increasing nonbonded electron density of the heavier main-group elements is the key issue for the trans-bent geometry, and yet it is strongly suppressed in E2M5+, creating two degenerate π bonds and one multi-center σ bond.We report a filamentous chaperone-based protein hydrogel capable of stabilizing enzymes against thermal inactivation. The hydrogel backbone consists of a thermostable chaperone protein, the gamma-prefoldin (γPFD) from Methanocaldococcus jannaschii, which self-assembles into a fibrous structure. Specific coiled-coil interactions engineered into the wildtype γPFD trigger the formation of a cross-linked network of protein filaments. The structure of the filamentous chaperone is preserved through the designed coiled-coil interactions. The resulting hydrogel enables entrapped enzymes to retain greater activity after exposure to high temperatures, presumably by virtue of the inherent chaperone activity of the γPFD.We analyze the emergence of wiggling temporal localized states in a passively mode-locked vertical external-cavity surface-emitting laser composed by a gain chip and a resonant saturable absorber mirror. We show that the wiggling instability stems from the interplay between the third-order dispersion induced by the micro-cavities and their frequency mismatch. The latter is identified as an experimentally crucial parameter defining the range of existence of stable emission. We reveal the homoclinic scenario underlying the wiggling phenomenon, and we show how it allows us to control the oscillation parameters.We report on an ytterbium-free, erbium-doped single-mode all-fiber laser reaching a record output power of 107 W at 1598 nm, with a slope efficiency of 38.6% according to the absorbed pump power at 981 nm. The erbium-doped gain fiber, co-doped with cerium, aluminum, and phosphorus, was fabricated in-house with adjusted doping concentrations to reduce erbium ions clustering, thereby increasing efficiency while keeping the numerical aperture low to ensure a single-mode laser operation. The addition of cerium co-dopant in the core glass of an erbium system is used for the first time, to the best of our knowledge, in order to adjust the fiber's numerical aperture without increasing the erbium concentration. Numerical modeling, validated by the experimental results, demonstrates that adding aluminum and phosphorus at high concentration mitigates erbium ions clustering, with an estimated erbium paired ions of only 5.0% in the reported gain fiber.In this Letter, we experimentally demonstrate liquid crystal-based moiré lenses with a wide and tunable focal length by direct-writing photoalignment. Our moiré lenses, which consist of two cascaded diffractive optical elements, have a large range of refractive power between $\pm 0.85\;\rm m^- 1$ at 532 nm and a mutual rotation between $\pm 90^\circ$ with high diffraction efficiency ($\gt\!75\%$). Based on the as-designed moiré lenses, we propose high-dynamic-resolution optical edge detection without any axial shift or substitution of components. The minimum edge width is 13.2 µm and can be adjusted within 100 µm by mutual rotation of this device, which has great potential to be used in adaptive and compact optical systems.We show that anisotropic planar anti-guiding waveguide structures with two radiation channels toward the surrounding cladding materials can support unidirectional guided resonances (UGRs), where radiation is canceled in one of the radiation channels and redirected into the other. Their formation is subtle as it requires breaking the so-called polar anisotropy-symmetry of the structures. link3 Then, UGRs appear at specific wavelengths and light propagation directions, are robust, and are characterized by phase singularities in the channel in which radiation is canceled. The mechanism we describe allows for ready selection of the radiation direction, as well as tuning of the wavelength and the propagation angle at which UGRs occur.We propose a reliable scheme for one-step synthesizing of a quantum fan-out gate in a system of neutral atoms. By introducing the off-resonant driving fields with Gaussian temporal modulation, the dynamics of the system is strictly restricted to the ground-state subspace on the basis of unconventional Rydberg pumping, which exhibits more robustness than the constant driving method against the fluctuation of system parameters, such as operating time and environment noise. As a direct application of this quantum fan-out gate, we discuss in detail the preparation of multipartite Greenberger-Horne-Zeilinger (GHZ) state for neutral atoms. The result shows that a high fidelity better than 99% can be obtained within the state-of-the-art experiments.In this Letter, we report the significant enhancement of the photonic spin Hall effect (SHE) in a plasmonic metasurface with $\rm S_4$ symmetry. We find that an enhanced SHE of reflected light can occur in both horizontally and vertically polarized incident beams, and the maximum transverse displacement can approach half of the beam waist. Such a large displacement is caused by the non-resonant and near-zero pseudo-Brewster angles in the plasmonic metasurface. Owing to $\rm S_4$ symmetry, a unidirectional SHE is obtained in the metasurface, i.e., large and tiny transverse displacements are realized for a linearly polarized beam incident from the opposite side. This Letter provides a new, to the best of our knowledge, way to achieve an enhanced photonic SHE and offers more opportunities for designing spin-based nanophotonic devices.A hybrid optical fiber comprising metal electrodes, high performance polymers, and a highly nonlinear glass core is presented in this work as a novel, to the best of our knowledge, platform for mid-infrared nonlinear devices. The fiber allows for electrical tuning of the temperature by joule heating using a set of embedded tungsten wires. Unlike temperature tuning by an external heater, this results in a strong modulation, which introduces alternating signs of its dispersion. Enhanced spectral broadening through supercontinuum generation in the mid-infrared due to this modulation is investigated numerically.We demonstrate curved modifications with lengths of up to 2 mm within borosilicate glass produced by single 1030 nm picosecond laser shots with an Airy beam profile. Plasma ignition in the sidelobes of the beam as well as surface damage prove to be the crucial limitations for confined bulk energy deposition on a curved trajectory. A combined experimental and numerical analysis reveals optimum laser parameters for confined bulk energy deposition. This way, we achieved single pass perforation of a 525 µm thick glass sheet and separation by a subsequent etching step, resulting in a well-defined convex edge down to a radius of curvature of 774 µm.