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Limitations of the study were the use of a small single center convenience sample that may reduce the generalizability of the findings.
The ARAT is consistent when scored by physiotherapists in a chronic stroke population. The inter-rater reliability range was (0.70 to 0.90) which is categorized as good.
The ARAT is consistent when scored by physiotherapists in a chronic stroke population. The inter-rater reliability range was (0.70 to 0.90) which is categorized as good.
To evaluate impact of first therapy session, containing functional electrical stimulation (FES) and therapeutic exercises (TE) on erector spinae (ES) and rectus abdominis (RA) force generation in persons with spinal cord injury (SCI).
Five men with SCI were divided in two groups - FES+TE received concurrent FES on ES and RA and TE, TE only TE. Participants performed exercises for improving sitting balance and posture. Muscles' electrical activity was evaluated by electromyography; amplitude (AEMG) and median frequency (MF) were used for analysis.
AEMG of ES left (L) increased 292.9% (g=-0.92), right (R) 175% (g=-1.01), RA L 314.3% (g=-0,81, P<0.05), R 266.7% (g=-0.08) in FES+TE. AEMG of ES L increased 47.6% (g=-0.46), R 96.4% (g=-0.95); RA L 7.1% (g=-0.97), but R decreased 6.7% (g=0.12) in TE. MF of ES L increased 108.5% (g=-0.74), R 184% (g=-1.25); RA L 886.7% (g=3-05, P<0.05), R 817.6% (g=-2.55, P<0.05) in FES+TE. MF of ES L increased 95.2% (g=-1.02), R 161.4% (g=-1.64); RA L 3,2% (g=-0.06), R 30.8% (g=-0.46) in TE.
In SCI persons, single session exercises and concurrent functional electrical stimulation may be more effective on muscles` force generation than only exercises. However, replication of the results is needed before clinical implementation.
In SCI persons, single session exercises and concurrent functional electrical stimulation may be more effective on muscles` force generation than only exercises. However, replication of the results is needed before clinical implementation.
Developmental coordination disorder (DCD) compromises bone health purportedly due to lower levels of physical activity. The potential of an exercise intervention to improve bone health parameters in adolescents with DCD has not previously been studied. This study thus aimed to determine the impact of a multimodal exercise intervention on bone health in this population at-risk of secondary osteoporosis.
Twenty-eight adolescents (17 male, 11 female) aged between 12-17 years (M
=14.1) with DCD participated in a twice weekly, 13-week generalised multimodal exercise intervention. Peripheral quantitative computed tomography scans of the tibia (4% and 66%) were performed over a six month period. Generalised estimating equations were used to examine the impact of fitness measures on bone parameters over time.
An overall improvement trend was observed for bone health, with significant increases at the 66% tibial site for bone mass (4.12% increase, d
=0.23, p=0.010) and cortical area (5.42% increase, η
=12.09, p=0.014). selleck chemical Lower body fitness measures were significantly associated with improvements in bone health parameters, tempered by the degree of motor impairment.
A multimodal exercise intervention may be effective in improving bone health of adolescents with DCD. Given the impact of motor impairments, gains may be greater over an extended period of study.
A multimodal exercise intervention may be effective in improving bone health of adolescents with DCD. Given the impact of motor impairments, gains may be greater over an extended period of study.The Microcystin-Leucine-Arginine (MC-LR) is the most toxic and widely distributed microcystin, which originates from cyanobacteria produced by water eutrophication. The MC-LR has deleterious effects on the aquatic lives and agriculture, and this highly toxic chemical could severely endanger human health when the polluted food was intaken. Therefore, the monitoring of MC-LR is of vital importance in the fields including environment, food, and public health. Utilizing the complementary base pairing between DNA molecules, DNA nanotechnology can realize the programmable and predictable regulation of DNA molecules. In analytical applications, DNA nanotechnology can be used to detect targets via target-induced conformation change and the nano-assemblies of nucleic acids. Compared with the conventional analytical technologies, DNA nanotechnology has the advantages of sensitive, versatile, and high potential in real-time and on-site applications. According to the molecular basis for recognizing MC-LR, the strategies of applying DNA nanotechnology in the MC-LR monitoring are divided into two categories in this review DNA as a recognition element and DNA-assisted signal processing. This paper introduces state-of-the-art analytical methods for the detection of MC-LR based on DNA nanotechnology and provides critical perspectives on the challenges and development in this field.137Cs is radioactive and highly hazardous to human health and the environment and its efficient removal from water is still challenging. In this study, potassium antimony tin sulfide (KATS-2) was synthesized using a hydrothermal method and utilized for the first time for cesium removal from water. KATS-2 showed a high maximum ion exchange capacity (358 mg g-1) and distribution coefficient (1.59 × 105 mL g-1) toward Cs+. In particular, KATS-2 showed rapid ion exchange kinetics and reached the adsorption equilibrium within 5 min with 99% removal efficiency. The adsorption was good at a wide active pH range (1-12) even in extreme alkaline conditions (Kd = 3.26 × 104 mL g-1 at pH 12). The effect of coexisting ions was also investigated, and a high selectivity toward Cs+ was maintained even in artificial seawater (Kd = 3.28 × 103 mL g-1). Powder X-ray diffraction and thermogravimetric analysis demonstrated that KATS-2 was chemically and thermally stable. The results showed that owing to its excellent adsorption performance as well as chemical and thermal stability, KATS-2 is a promising adsorbent for Cs+ removal from contaminated water.The functionalization and incorporation of noble metals in metal-organic frameworks have been widely used as efficient methods to enhance their applicability. Herein, a sulfone-functionalized Zr-MOF framework labeled Zr-BPDC-SO2 (BPDC-SO2 =dibenzo[b,d]-thiophene-3,7-dicarboxylate 5,5-dioxide) and its Pd-embedded composite were efficiently synthesized by adjusting their functional groups. The obtained compounds were characterized to assess their potential for gas sensing applications. X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, specific surface area measurements, and thermogravimetric analysis were employed to characterize the new sensor materials. The gas sensing properties of the novel functionalized sensor materials were systematically investigated under various temperature, concentration, and gas type conditions. Owing to the strong hydrogen bonds of the sulfonyl groups and Zr6 clusters in the framework with the hydroxyl groups of ethanol, Zr-BPDC-SO2 emerged as an effective sensor for ethanol detection. In addition, Pd@Zr-BPDC-SO2 exhibited efficient hydrogen sensing performance, in terms of sensor dynamics and response. More importantly, the material showed a higher sensing response to hydrogen than to other gases, highlighting the important role of Pd in the Zr-MOF-based hydrogen sensor. The results of the sensing tests carried out in this study highlight the promising potential of the present materials for practical gas monitoring applications.Ozonation might increase the risk of wastewater due to byproduct formation, especially in the presence of bromide. In this study, a new analytical method was developed to identify new brominated disinfection byproducts (Br-DBPs) during ozonation, using comprehensive two-dimensional gas chromatography-single quadrupole mass spectrometry (GC×GC-qMS) connected with an electron capture detector in parallel. The obtained data were analyzed using a mass-to-charge ratio (m/z) difference extraction method. Over 1304 DBPs were detected in an ozonated phenylalanine solution. Further screening of 635 DBPs was conducted using the m/z difference extraction method. Finally, the structures for 12 Br-DBPs were confirmed and for 4 Br-DBPs were tentatively proposed by comparison with the NIST library and standard compounds. Eight of the confirmed Br-DBPs are first reported and identified 2-bromostyrene, 1-bromo-1-phenylethylene, 2-bromobenzaldehyde, 3-bromobenzaldehyde, 4-bromobenzaldehyde, 2-bromophenylacetonitrile, 3-bromophenylacetonitrile and 4-bromophenylacetonitrile. These DBPs and 2,4,6-tribromophenol were detected at nanogram- to microgram-per-liter concentrations during ozonation of authentic water samples like algal bloom waters, wastewater treatment plant effluents, and surface water. The toxicities of these compounds were generally higher than that of bromate. The developed analytical method is a powerful technique for analyzing complex compounds and provides a novel way of identifying byproducts in future studies.Room-temperature gas sensors have emerged as effective platforms for sensing explosive or toxic gases in ambient environment. However, room-temperature gas sensor usually suffers from extremely poor sensitivity and sluggish response/recovery characteristics due to the low reacting activity at low temperature. Herein, we present a room-temperature NO2 sensor with greatly enhanced sensitivity and rapid response/recovery speed under ultraviolet (UV) illumination. The sensor based on In2O3/ZnO yolk-shell nanofibers exhibits remarkable sensitivity (Rg/Ra = 6.0) to 1 ppm NO2 and rapid response/recovery time (≤36, 68 s) under UV illumination, obviously better than negligible sensing performance and inefficient response/recovery properties in dark condition. Such excellent gas sensing properties of the In2O3/ZnO yolk-shell nanofibers were not only attributed to the improved photo-generated charge separation efficiency derived from the effect of heterojunction, but also related to the enhanced receptor function towards NO2 endowed by increased reactive sites and gas adsorption. These proposed strategies will provide a reference for developing high-performance room-temperature gas sensors.Fast and efficient cleanup of high-viscosity oil spills on the sea is still a global challenge today. Traditional recycling methods are either energy demanding or inefficient. Hydrophobic/oleophilic sorbents are promising candidates to handle oil spills, but they have limited ability to recover high viscosity oil. In this work, we report a superhydrophobic/oleophilic carbon nanotubes (CNT) and polypyrrole (PPy) coated melamine sponge (m-CNT/PPy@MS). The CNT/PPy coating enables the sponge to convert light and electricity to heat, ensuring that the absorbent can adapt to various working environments. The rapid heat generation on the sponge surface can significantly reduce the viscosity of crude oil and accelerate the absorption rate, thereby achieving the purpose of rapid recovery of oil spills. Under one sun illumination (1.0 kW/m2) and an applied voltage (8 V), the surface temperature of the m-CNT/PPy@MS can reach 118.6 °C. The complete penetration time of oil droplets is 93.5% less than that of an unheated sponge.
