Waltondaley2540

Annual gross primary productivity (AGPP) serves as the basis for forming biomass and carbon sinks. Analysing the effects of ecosystem types on AGPP spatial variations would be beneficial for clarifying the spatial variability in AGPP, which would serve ecological management practices such as ensuring regional food security. Based on published eddy covariance measurements in China, we collected AGPP data from 128 ecosystems and analysed the effects of ecosystem types on the spatial variations in AGPP to reveal the AGPP spatial variability and its influencing factors over terrestrial ecosystems of China. The results showed that AGPP significantly differed among ecosystem types and vegetation regions, with the lowest AGPP appearing in grasslands, while different ecosystem types had comparable AGPP within the same vegetation region. The AGPP of all ecosystem types showed a decreasing latitudinal trend but slight longitudinal and altitudinal trends. Mean annual air temperature (MAT) and mean annual precipitation (MAP) were found to affect the spatial variations in AGPP over most ecosystem types, while other factors played little role. The mean annual leaf area index (LAI) and the maximum leaf area index (MLAI) were also found to affect the spatial variations in AGPP over most ecosystem types. Calpeptin price Factors influencing the AGPP spatial variations differed among ecosystem types, but all included climatic and biotic factors. Therefore, climate inducing spatial distribution of ecosystem types and the non-zonal water supply made AGPP values and factors affecting the spatial variations in AGPP differ among ecosystem types, while different ecosystem types within the same vegetation region had comparable AGPP values. The spatial variation in AGPP over terrestrial ecosystems of China resulted from the integrated effects of climatic and biotic factors. Our study provided data support for improving the understanding of global AGPP spatial variability.Global climate change has led to profound alterations of the Arctic environment and ecosystems, with potential secondary effects on mercury (Hg) within Arctic biota. This review presents the current scientific evidence for impacts of direct physical climate change and indirect ecosystem change on Hg exposure and accumulation in Arctic terrestrial, freshwater, and marine organisms. As the marine environment is elevated in Hg compared to the terrestrial environment, terrestrial herbivores that now exploit coastal/marine foods when terrestrial plants are iced over may be exposed to higher Hg concentrations. Conversely, certain populations of predators, including Arctic foxes and polar bears, have shown lower Hg concentrations related to reduced sea ice-based foraging and increased land-based foraging. How climate change influences Hg in Arctic freshwater fishes is not clear, but for lacustrine populations it may depend on lake-specific conditions, including interrelated alterations in lake ice duration, turbiditprove interpretation of spatial variation and time trends of Hg in Arctic biota.Microbial methane oxidation is the major biological methane (CH4) sink in the carbon cycle. Methanotrophs can use various electron acceptors in addition to oxygen; understanding the role and contribution of methanotrophs is thus an important topic. However, anaerobic oxidation of methane (AOM) mediated by methanotrophs is poorly explored and understood. This article summarizes the role aerobic methanotrophic bacteria play in AOM. Though AOM was originally considered to be mediated by anaerobic methanotrophic archaea, intra-aerobic methane-oxidizing bacteria (Candidatus Methylomirabilis oxyfera) appear to be involved in nitrite-dependent AOM. In addition, aerobic methanotrophs of the Methylomonadaceae and Methylocystaceae, are more versatile than previously assumed and can also be involved in nitrate/nitrite- or mineral oxide-dependent AOM under oxygen-limitation. Furthermore, the simultaneous reduction of nitrous oxide and oxidation of CH4 may be another new metabolic trait of aerobic methanotrophs. We discuss the potential metabolic pathways of CH4 oxidation under hypoxic conditions. It is of great ecological importance not only for the quantification of CH4 oxidation and emissions, but also for the definition of a new function of aerobic methanotrophs in anaerobic/hypoxic environments.This study describes a new bioaugmentation alternative based on the application of aqueous aerated extracts from a biomixture acclimated with ibuprofen, diclofenac and triclosan. This bioaugmentation strategy was assayed in biopurification systems (BPS) and in contaminated aqueous solutions to accelerate the removal of these emerging contaminants. Sterilized extracts or extracts from the initial uncontaminated biomixture were used as controls. In BPS, the dissipation of 90% of diclofenac and triclosan required, respectively, 60 and 108 days less than in the controls. The metabolite methyl-triclosan was determined at levels 12 times lower than in controls. In the bioaugmented solutions, ibuprofen was almost completely eliminated (99%) in 21 days and its hydroxylated metabolites were also determined to be at lower levels than in the controls. The plasmidome of acclimated biomixtures and its extract appeared to maintain certain types of plasmids but degradation related genes became less evident. Several dominant OTUs found in the extract identified as Flavobacterium and Fluviicola of the phylum Bacteroidetes, Thermomicrobia (phylum Chloroflexi) and Nonomuraea (phylum Actinobacteria), may be responsible for the enhanced dissipation of these contaminants. This bioaugmentation strategy represents an advantageous tool to facilitate in situ bioaugmentation.The structure of humic substances (HSs) and the humification process are critical topics for understanding the dynamics of carbon on the planet. This study aimed to assess the structural patterns of 80 humic acid (HA) samples isolated from different soils, namely, Histosols, Ferralsols, Cambisols, Mollisols, Planosols and vermicompost, by spectroscopic characterization using solid-state 13C nuclear magnetic resonance cross-polarization/magic angle spinning combined with chemometric techniques. All 80 HAs had a similar structural pattern, regardless of their source of origin, but they had different relative quantities of organic C species. The different structural amounts of the various organic C fractions generated different properties in each of the HAs. This explains why there were similarities in the HS functions but why the intensities of these functions varied among the samples from the different soil types and environments, confirming that HSs are a group of compounds with a structural identity distinct from the molecules that give rise to them. There appears to be no single definition for the humification process; therefore, for the soils from each source of origin, a specific humification process occurs that depends on the characteristics of the local environment. Humification can be understood as a process that is similar to a chemical reaction, where the key factor that determines the formation of the products is the structural characteristics of the reactants (organic substrates deposited in the soil). The degree to which the reaction progresses is governed by the reaction conditions (chemical, physical, and biological properties of the soil). The structural patterns for HSs obtained in this study justify the existence of HSs structured as self-assembled, hydrophilic and hydrophobic domains that, under certain conditions, can undergo transformations, altering the balance of organic carbon in the environment.Discovered in Ethiopia, coffee became a popular beverage in Asia, Europe, Latin America, Australia, Africa and the North America as a drink after water and the largest goods after petroleum. However, the coffee industry generates a huge biomass as its byproducts of which the spent coffee grounds (SCG) is concerning, especially in the production chain away from the farm. Therefore, the valorization and revalorization of the SCG has a huge impact on the socioeconomic and environmental sustainability of the industry, up to the realization of the circular bioeconomy. With the advancing biorefinery concept, even an almost complete recovery of the SCG is reported at an experimental level. Such kind of studies increased with time following the action of the Sustainable Development Goals by the United Nations Development Program promulgated in 2015. The current review highlights on the background, socioeconomic, environmental contexts of coffee production and the SCG valorization and revalorization studies. Refereeing to 154 screened articles published in over 30 years' time, the SCG revalorization efforts and its integrated biorefinery as a green management approach are uniquely addressed. Plenty of studies have reported the production of bio-products from the SCG, such as the derivation of adsorbents, biochar, bioethanol, biogas, biodiesel, bio-oil, compost, construction material aggregates, cosmetics, electricity and food ingredients. In conclusion, the recovery potential of the SCG is promising and can substantially contribute to a sustainable and green bioeconomy. Nevertheless, the recovery of bioactive materials through SCG fermentation is still lacking. Most studies are conducted on a lab scale, which needs to be piloted and commissioned. Furthermore, the link between climate change and variability vis-à-vis the sustainable management of the SCG remains unaddressed.As a by-product of wastewater treatment, waste activated sludge (WAS) has complex composition, strong hydrophilic extracellular polymeric substance (EPS), which make it difficult to dewater. In this study, an electro-peroxone oxidation-Fe(III) coagulation (E-peroxone-Fe(III)) sequential conditioning approach was developed to improve WAS dewaterability. At E-peroxone oxidation stage, hydrogen peroxide was generated through 2-electron path on a carbon polytetrafluoroethylene cathode, and reacted with the sparged O3 to produce hydroxyl radicals. At the subsequent coagulation stage, Fe(III) was dosed to coagulate the small WAS fragments and release water from WAS. Along E-peroxone-Fe(III) subsequent conditioning process, the physicochemical properties of WAS, main components, functional groups and evolution of protein secondary structure, and typical amino acids in EPS, as well as the type and semi-quantitative of elements in WAS, were investigated. The results indicated that under the optimal conditions, the redST or SRF (R2CST = 0.992, p less then 0.05 or R2SRF = 0.921, p less then 0.05) occurred, which could be related to the WAS dewaterability.Weathered petroleum-contaminated soil (WPCS) with a high proportion of heavy hydrocarbons is difficult to remediate. Our previous research demonstrated that Fe2O3-assisted pyrolysis was a cost-effective technology for the remediation of WPCS. However, the pyrolysis behaviors, products, and mechanisms of the WPCS with Fe2O3 are still unclear. In this study, a combination of Thermogravimetric-Fourier transform infrared spectroscopy (TG-FTIR) and pyrolysis gas chromatography/mass spectrometry (Py-GC/MS) techniques were used to explore these pyrolysis characteristics. The thermal desorption/degradation of light and heavy hydrocarbons in the WPCS mainly occurred at 200-400 °C and 400-550 °C, respectively. The activation energy of thermal reaction of heavy hydrocarbons was decreased in the presence of Fe2O3 during the WPCS pyrolysis processes. In the process, the released inorganic gaseous products were mainly H2O and CO2, while the released organic gaseous compounds were primarily cycloalkanes, alkanes, acids/esters, alcohols, and aldehydes.