Wallsstevenson7057

Fascinatingly, the hybrid nanozyme can inhibit the formation of monosodium urate monohydrate effectively based on the architecture of ARP-PtNCs. Thus, ARP-PtNC nanozyme has the potential in gout and hyperuricemia therapy. Rational design of ingenious peptide-metal hybrid nanozyme with unique physicochemical surface properties provides a versatile and designed strategy to fabricate multi-enzymatic cascade systems, which opens new avenues to broaden the application of nanozymes in practice.In Ti3C2 quantum dots (Ti3C2 QDs)/Bi2O3 photocatalysts system, Ti3C2 QDs can act as a co-catalyst to greatly boost the photocatalytic performance of Bi2O3. Ti3C2 QDs with excellent light adsorption ability can improve the light response of the system, and the fascinating electronic property can function as a channel for electron transfer. Moreover, Ti3C2 QDs possess larger specific area and more active edge atoms thanks to the size effect. The best Ti3C2 QDs/Bi2O3 composite with the loading amounts of 75 mL of Ti3C2 QDs solution showed much higher photocatalytic performance (nearly 5.85 times) for tetracycline (TC) degradation than that of pristine Bi2O3 under visible light irradiation. These different photocatalytic performances shed light on the key role of Ti3C2 QDs in stimulating the photocatalytic activity of Bi2O3. Moreover, Ti3C2 QDs/Bi2O3 composites exhibited excellent stability in recycling experiments and actual water sample treatment.Although electrode materials based on metal organic frameworks (MOFs) were widely studied in the electrochemistry field, the origin of poor conductivity is still a bottleneck restricting their development. Herein, we constructed a conductive circuit by growing a layer of hydroxide on the surface of the Fe-MOF, and composite materials (Fe-MOF@Ni(OH)2) are applied in the fields of supercapacitor, OER, and electrochemical sensing. Fe-MOF@Ni(OH)2 not only maintains the intrinsic advantages of Fe-MOF, but also improves the electrical conductivity. Fe-MOF@Ni(OH)2 exhibits a high specific capacity of 188 mAh g-1 at 1 A g-1 . The energy density of the asymmetric supercapacitor (Fe-MOF@Ni(OH)2-20//AC) reaches 67.1 Wh kg-1. During the oxygen evolution reaction, the overpotential of the material is 280 mV at 10 mA cm-2, and the Tafel slope is 37.6 mV dec-1. The electrochemical sensing tests showed the detection limit of BPA is 5 μM. Hence, these results provide key insights into the design of multifunctional electrode materials.To regulate the charge flow of the photocatalyst in photocatalytic hydrogen reactions is highly desirable. In this study, a highly efficient sulphur vacancies-CdS@CuS core-shell heterostructure photocatalyst (denoted CdS-SV@CuS) was developed through the surface modification of CdS-sulphur vacancies (SV) nanoparticles by CuS based on photoinduced interfacial charge transfer (IFCT). AVE0010 This novel photocatalyst with modulated charge transfer was prepared by hydrothermal treatment and subsequent cation-exchange reactions. The SV confined in CdS and the IFCT facilitate the charge carrier's efficient spatial separation. The optimized CdS-SV@CuS(5%) catalyst exhibited a remarkably higher H2 production rate of 1654.53 μmol/g/h, approximately 6.7 and 4.0 times higher than those of pure CdS and CdS-SV, respectively. The high photocatalytic performance is attributed to the rapid charge separation, caused by the intimate interactions between CdS-SV and CuS in the core-shell heterostructure. This is the first time that a straightforward method is adopted to construct a metal sulphide core-shell structure for superior H2-production activity by IFCT.Constructing flexible perovskite structured ceramic fibrous materials would potentially facilitate applications of photocatalysis, wearable devices, and energy storage. However, current perovskite structured ceramic fibrous materials were fragile with small deformation resistance, which have limited their wide applications. Herein, flexible zirconium doped strontium titanate (ZSTO) nanofibrous membranes were fabricated via combining sol-gel and electrospinning methods. The microstructures (pore and crystal) of ZSTO nanofibers were affected by zirconium doping contents and closely relevant to flexibility of resultant membranes. The probable mechanism for flexibility of ZSTO nanofibrous membranes was presented. Furthermore, the silver phosphate modified ZSTO (AZSTO) exhibited superior photocatalytic performance towards tetracycline hydrochloride (TCHC) and antibacterial performance towards Gram-negative and Gram-positive bacteria with visible-light irradiation, including 85% degradation towards TCHC within 60 min, >99.99% inhibition rate and > 3 mm inhibition zone against Gram bacteria. Furthermore, the·superoxide free radical (O2-) and holes played significant roles in the degradation of TCHC that verified by radical scavenger experiment. Additionally, the membranes exhibited good reusability over five cycles without tedious recycling operations needed for micro/nanoparticle-based catalysts. The successful fabrication of ZSTO nanofibrous membranes would provide a new insight into photocatalysts, antibacterial materials, and wearable device.Due to the inherent differences in surface tension between water and oil, it is a challenge to fabricate air superhydrophilic-superoleophobic materials despite their promising potential in the field of oil/water separation. Herein, a facile approach is developed to fabricate air superhydrophilic-superoleophobic SiO2 coating by combination of controllable modifying SiO2 nanoparticle surface by both hydrophilic groups (i.e., -OH groups) and oleophobic groups (i.e., fluorinated groups) with constructing porous and hierarchical structures. Hydroxyl-modified SiO2 nanoparticles (NPs) are synthesized using a base-catalysed procedure in the presence of ammonia or NaOH. Chitosan quaternary ammonium salt (HACC) is introduced to bind SiO2 by forming a unique hydrogen bond between HACC and -OH, followed by adding pentadecafluorooctanoic acid (PFOA) to complex with HACC to form fluorinated groups. The SiO2 coatings are fabricated on various substrates (e.g., glass, foam and Cu mesh) by spraying procedure and characterized using SEM, FTIR, XPS, etc.