Velezrosenthal2628

Rational design of near-infrared (NIR) absorbing molecules is crucial for developing photofunctional materials. Here, we synthesized dinuclear and mononuclear Re(i) tricarbonyl phthalocyanine complexes that exhibit a sharp intense Q band in the NIR region. The unsymmetric coordination of electron-deficient metal unit(s) concomitantly produced a remarkable red shift of the Q band and improved the tolerance of the phthalocyanine ring to oxidation. This study presents a simple and effective strategy for the construction of NIR absorbers with high stability.Bismuth based structures are among the most promising candidates for thermoelectric applications. Recently, a semiconducting binary compound with stoichiometry of Sn2Bi has been synthesized, showing a strong spin-orbit coupling effect and high electron-hole asymmetry. Motivated by the experiment, we performed a density functional theory calculation combined with the semiclassical Boltzmann transport equation to investigate the thermoelectric properties of the stabilized Sn2Bi monolayer. It is demonstrated that the mobility is strongly dependent on the strain. It is 2389 (186) cm2 V-1 s-1 for hole (electron) in relaxed monolayer, but it becomes 1758 (1758) cm2 V-1 s-1 by applying a 2.5% tensile strain. Spin-orbit coupling (SOC) induces a huge spin splitting in the conduction and valence bands as high as 350 and 270 meV, respectively, coming from p orbitals of bismuth atoms. Also, the thermoelectric efficiency of the monolayer could be directly controlled by doping and strain where the maximum room temperature figure of merit of 1.01 is obtained under the strain of 3% for n-type doping with inclusion of SOC, making it a promising candidate for thermoelectric applications.Alginate-based hydrogels are increasingly being used as biomaterials for tissue engineering, drug carriers, and wound dressing; however, their poor mechanical strength limits their applications. Nanofiber reinforcement is an effective method for increasing the mechanical strength of hydrogels. However, the macro preparation of nanofiber-reinforced hydrogels with a bulk structure is challenging. Herein, we describe the fabrication of nanofiber-reinforced bulk alginate hydrogel composites. The mechanical properties of hydrogels were significantly improved, and the reinforcement law of nanofiber was systematically studied. The maximum tensile stress (0.76 MPa) was obtained with 30% nanofiber content, which was 87% higher than that of pure alginate hydrogel. The compressive stress of the composite hydrogel exhibited "J-curve" behavior with gradually increasing nanofiber content, which indicated that the composited hydrogels were suitable as biomaterials. Furthermore, in 2 h, the hydrogels killed more than 90% of the bacteria that were present, and the bacteriostatic rate reached 100% after 12 h of treatment. More importantly, the sterile environment continued to be maintained, and the composited hydrogel also had satisfactory cytocompatibility and cell adhesion. MRTX849 in vitro Compared with pure alginate hydrogel, the roughness of the composited hydrogel surface was increased, which resulted in stronger cell adhesion. Therefore, the composite hydrogel demonstrated improved mechanical and biological properties, and exhibited the potential for clinical application.Correction for 'Time-dependent shear rate inhomogeneities and shear bands in a thixotropic yield-stress fluid under transient shear' by Yufei Wei et al., Soft Matter, 2019, 15, 7956-7967, DOI 10.1039/C9SM00902G.It is highly desirable for porous coordination polymers (PCPs), including metal-organic frameworks (MOFs) and Prussian blue analogues (PBAs), to retain their intrinsic characteristics in electrocatalysis, instead of being used as precursors or templates for further total conversion to other compounds via high-temperature calcination. Here, a S-treated two-dimensional (2D) CoFe bimetallic PBA grown on carbon fiber paper (CFP) (named S-CoFe-PBA/CFP) is assembled and applied as a highly efficient oxygen evolution reaction (OER) electrocatalyst in 1 M KOH. The resultant S-CoFe-PBA/CFP demonstrates significantly improved OER catalytic activity; overpotentials of only 235, 259, and 272 mV are needed to drive current densities of 10, 50, and 100 mA cm-2, respectively, with a super low Tafel slope of 35.2 mV dec-1. Even more noteworthy, a current density of 90 mA cm-2 can be achieved when a potential of 1.5 V vs. RHE is applied, which is 6.4 times higher than that of commercial Ir/C in the same environment. The outstanding electrocatalytic performance can be ascribed to two reasons caused by the S-treatment process. On one hand, H+ from intermediates of *OH and *OOH can be captured by -SOx distributed on the surface of the catalyst, thus accelerating the breaking of O-H; on the other hand, partial phase transformation of CoFe-PBA leads to the in situ formation of amorphous CoSx nanogauze on the surface, and the resultant electronic interactions between the two phases contribute much to the improvement of charge transfer and adsorption for OER intermediates. This work provides a new avenue for the design of highly efficient PCP-based OER electrocatalysts.In this work, the important role played by metal ions such as Fe(ii/iii), Cr(iii) and Ni(ii) in the formation and binodal behaviour of aqueous biphasic systems (ABS) composed of HCl and the ionic liquid, [P44414]Cl, or the polymer, PEG-600, is investigated. The concentration of metal ions used in this work exceeds several g L-1 for an industrial foreseen application. Experiments have also been carried out by varying the concentration of metal ions at different temperatures. Fe exhibits a totally different behaviour compared to Ni and Cr. In particular, the binodal curves in the presence of the ionic liquid are far from the classical curves found in the literature, displaying an onion-shape form, while for Ni and Cr, the curves follow the classical trend. When any of the three metal ions is mixed with the polymer and HCl medium, only Fe(iii) induces a biphasic system. Insights into the chemical driving forces at work are discussed.