Tillmankumar4868

Water dependency of energy generation systems including renewable energy resources pollute water. Efforts are being made to control energy-related water pollution. Here in, eight keratin derived biopolymers were developed to sequester the toxic trace elements from synthetic wastewater. Chemical modifications of biopolymers affect their physical and chemical characteristics, hence, enhance the sorption of contaminants from wastewaters. KBP-I (processed chicken feathers), KBP-II (acid modified), KBP-III & KBP-IV (modified with ionic liquids), KBP-V (amine modified), KBP-VI & KBP-VII (POSS modified) and KBP-VIII (sodium sulfite modified) were characterised for their surface morphology, structural integrity, functional group changes, crystallinity behaviour, surface area and pore size distribution using different analytical techniques. Developed biopolymers were then tested against synthetic wastewater spiked with nine transition and redox sensitive elements (100 μg L-1 each). Among the eight biopolymers, KBP-I removed 87-93% of As and Cd, KBP-IV removed 80-85% of Cu and VV, KBP-V removed 60-90% of Co, Ni and Zn, whereas KBP-VI removed 95% of CrVI. The developed keratin biopolymers show prospects to effectively treat the metals contaminated wastewater.Manganese oxides (MnO2), important environmental oxides, have drawn significant attention in areas such as detoxification of micro-hazardous organic contaminants with electron-donating functional groups such as -OH. However, studies on whether these oxidized processes might further impact the fate of some esters like organophosphorus pesticide (OPPs) remain poorly understood. Herein, we propose a new mechanism involved in the enhanced removal of methyl parathion in mixtures of MnO2 and phenol. Specifically, the removal of methyl parathion (up to 73.7%) was significantly higher for a binary system than for MnO2 alone (approximately 9.3%) and was primarily due to adsorption rather than degradation. The extent of methyl parathion adsorption was dependent significantly on pH, reactant loading and metal ion co-solutes (such as Ca2+, Mg2+, Fe3+ and Mn2+). SGC-CBP30 order Both spectroscopic (FT-IR, SEM-EDX and XPS) and chromatographic (LC/HRMS) analyses showed that the remarkable increase in the number of organics (e.g., polymers) onto the MnO2 surface dominated methyl parathion adsorption via hydrogen bonding, n-π and π-π interactions, van der Waals forces and pore-diffusion. The results from this study provided evidence for the role of manganese oxides in adsorption of methyl parathion in soil-aquatic environments involving phenolic compounds.Para-Cresol is a water-soluble organic pollutant, which is harmful to organisms even at low concentrations. Therefore, it is important to rapidly detect the p-cresol in wastewater as well as natural water. In this work, a new, simple and stable biosensor was developed for on-site quantitatively determination and near real-time monitoring p-cresol in wastewater. The new biosensor was designed and fabricated using a screen-printed carbon electrode (SPCE) modified by waste-derived carbon nanotubes (CNTs) immobilized with laccase (LAC). The fabrication processes and performance of the biosensors were systematically characterized and optimized by Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscope (FESEM), transmission electron microscopy (TEM) and electrochemical methods. With improved conductivity, the proposed biosensor could provide the direct quantitation of p-cresol. The linear range of the biosensor is 0.2-25 ppm of p-cresol with a detection limit of 0.05 ppm. Additionally, the biosensor exhibited high reproducibility, stability and reusability during the validation. More importantly, the biosensor was successfully applied for the rapid detection of p-cresol in environmental lab wastewater under the interference of metal ions and other organics, and the results were consistent with high-performance liquid chromatography (HPLC). Finally, the biosensor with a portable potentiostat was approved as an easy-to-use, sensitive and inexpensive platform that could provide near real-time monitoring of p-cresol concentration in wastewater during Fenton oxidation treatment process.The role of silicon in plant resistance to biotic and abiotic stresses is clear; however, its role in interspecific interactions is not well understood. Biogenic silica (BSi) accumulation and ecological characteristics in single-species communities (Phragmites australis, Cyperus malaccensis, and Spartina alterniflora) and ecotones (P. australis-C. malaccensis and C. malaccensis-S. alterniflora) of Shanyutan marsh, China, were monitored from January to December in 2016. The BSi content of the three plant species decreased at the end of winter and beginning of spring, and continued to increase after March. In ecotones, the density of P. australis, the lengths of C. malaccensis and S. alterniflora, and the BSi content of C. malaccensis were greater than those in single-species communities. However, in single-species communities, the densities of C. malaccensis and S. alterniflora, the length of P. australis, the biomass and BSi stocks of the three species, and the BSi content of P. australis and S. alterniflora were greater than those in the ecotones. The three species may apply different strategies to compete for resources during interactive growth. Phragmites australis may improve its competitive ability by increasing vegetation density, aboveground biomass, and Si allocation to the leaves and withered body. Spartina alterniflora appears to enhance root biomass accumulation and the Si uptake and allocation capacity of roots. Cyperus malaccensis appears to allocate greater biomass and BSi to aboveground organs, as well as improve the absorption capacity of roots to resist competition pressure from P. australis. Cyperus malaccensis mixed with S. alterniflora increased its belowground biomass and BSi stocks. These results help clarify the mechanisms and processes of Si translocation during mixed plant growth, and increase our understanding of the strategies involved in plant competition.