Thyssenmccray4089

The mineral composition and surface physico-chemical properties, i.e., specific surface area (SSA), cation exchange capacity (CEC), and surface charge of recent sediments and their submicron mineral fractions from different sedimentological environments of the Eastern Adriatic were investigated. The influence of organic matter on these properties was also investigated. It was shown that illite and mixed-layered clay minerals (MLCM) were ubiquitous and showed no size-related preferences while the occurrence of smectites, chlorites, and kaolinites varied. The smectites content increased and the chlorites decreased slightly with decreasing particle size. The sediments from the carbonate-rich environment contained no smectites or chlorites and had the highest kaolinite content. For the first time, in the recent sediments of the Adriatic Sea the poorly- and the well-crystallised kaolinite (Kl and KlD) were distinguished. While Kl predominates in the submicron-sized fraction, KlD occurred only in micron-sized fractions. Authigenic aragonite of submicron-sized was determined in a distinct environment of the semi-enclosed marine lake. The differences in mineral composition and particle size of sediments and their separated fractions were reflected in a wide range of the SSA and CEC values obtained. The highest values of SSA and CEC were determined in the phyllosilicates-rich submicron-sized fractions range, 109 m2g-1 and 87.4 cmol+kg-1, respectively. The submicron-sized fraction from aragonite-rich marine lake showed the lowest values of SSA (56.4 m2g-1) and CEC (38.8 cmol+kg-1), which are still unexpectedly high for carbonate-rich environments. The removal of organic matter resulted in a significant increase in SSA and CEC, up to 150% and 76%, respectively. selleck inhibitor Secondary Organic aerosols (SOA) are important components of PM 2.5. In order to control the heavy haze pollution, it is essential to find out the contributions of main SOA precursors. Nowadays, the tracer-based method has been widely used in analyzing the contributions of the precursors to SOA. However, it is not well known that whether the SOA tracers can be oxidized or how the instability of the SOA tracers would influence the accuracy of the tracer-based method for source apportionment. In this paper, the heterogeneous oxidation experiments of SOA tracers produced from isoprene and toluene as well as their mixtures under different conditions were conducted in a 2 m3 indoor chamber. The relative rate constants approach was used to determine the effective rate constants of the ozone reactions of the tracers. Concentrations of 2-Methyl Erythritol, a tracer of isoprene SOA, and 2, 3-Dihydroxy-4-oxopentanoic Acid, a tracer of toluene SOA, were analyzed using GC-MS. The effects of different seed aerosols and initial VOC0/NO on the heterogeneous oxidation of the tracers were investigated. The effects of co-existing components in the SOA produced from the mixture of isoprene and toluene on the heterogeneous oxidation of the tracers by ozone were also studied. Biochar pyrolysed at 300 °C, 500 °C, 700 °C was modified by hydrochloric acid (HCl), hydrofluoric acid (HF), sodium hydroxide (NaOH), hydrogen peroxide (H2O2), nitric acid (HNO3) and potassium permanganate (KMnO4), and subsequently evaluated for removal efficiency of 1,2,4-trichlorobenzene (1,2,4-TCB) by biochar supported nanoscale zero-valent iron (nZVI) and palladium (Pd) composites. Under the initial 1,2,4-TCB concentration of 10 mg L-1 and the solid-liquid ratio of 0.16 g L-1, the synthesized composites of nZVI-Pd with BC700 modified by HF (FBC700-nZVI-Pd) and nZVI-Pd with BC300 modified by NaOH (SBC300-nZVI-Pd) demonstrated significantly enhanced removal efficiencies for 1,2,4-TCB achieving 98.8% and 94.7% after 48 h, respectively. The physicochemical properties of biochar including specific surface area, aromaticity and hydrophobicity after the modification by HF and NaOH were improved. Increased the supporting sites for Fe/Pd nanoparticles and the contact between composites and 1,2,4-TCB were mainly responsible for enhanced removal efficiency for 1,2,4-TCB. Both the adsorption by biochar and reduction by Fe/Pd nanoparticles effectively contributed to the removal of 1,2,4-TCB. It is estimated that the proportion of reduction was about twice that of adsorption in the first 12 h, which produced 1,2-DCB, benzene and other degradation products. Therefore, biochar treated with HF and NaOH and supported Fe/Pd nanoparticles could be effective functional materials for remediation of groundwater contaminated by 1,2,4-TCB. Pb-based perovskite nanoparticles (PbPNPs) are amongst others used within highly efficient solar cells. PbPNPs can be released into the environment during their production, recycling or waste processing. In this study we investigated the fate and toxicity of PbPNPs on soil bacterial community under simulated natural environmental conditions across a range of pH, humic acid, and divalent cation concentrations. Increasing pH decreased PbPNPs-particle aggregation as well as Pb-ion release. The presence of only humic acid (HA) prevented the aggregation of PbPNPs-particles, whereas the presence of only divalent cations promoted the aggregation of PbPNPs-particles. The amount of Pb-ions released from the PbPNPs-particles was reduced in the presence of either HA or the divalent cations. Results of toxicity testing of PbPNPs by determining the metabolic potential of a bacterial community indicated that increasing pH alleviated particle toxicity. The presence of only HA reduced the toxicity of PbPNPs, while the presence of only divalent cations enhanced the particle toxicity. The coexistence of HA and divalent cations enhanced PbPNPs aggregation and reduced toxicity, with both Pb-ions and the interaction between the PbPNPs-particles and bacterial cells contributing to the toxic effects. Our study emphasized that environmental conditions play important roles that influencing the fate and toxicity of PbPNPs. The brown planthopper (BPH), Nilaparvata lugens, is a resurgent pest with an unexpected response to jinggangmycin (JGM), a broadly applied antibiotic used to control rice sheath blight disease. JGM stimulates BPH fecundity, but the underlining molecular mechanisms remain unclear. Here we report that JGM sprays led to increased glucose concentrations, photosynthesis and gene expression, specifically Rubsico, sucrose phosphate synthase, invertase 2 (INV2) and INV3 in rice plants. JGM sprays led to high-glucose rice plants. Feeding BPH on these plants led to increased insulin-like signaling and vitellogenin synthesis. Treating BPH with metformin, a gluconeogenesis inhibitor, reversed the influence of feeding on high-glucose rice, which was rescued by glucose injections. Silencing insulin-like peptide 2 using per os dsRNA led to reduction in juvenile hormone (JH) III titers and other fecundity parameters, which were reversed by topical applications of the JH analog, methoprene. We infer that JGM acts via two broad mechanisms, one through increasing rice plant sugar concentrations and a second by upregulating BPH insulin-like signaling.