Thomasgreen4343

5-induced BP effects with significant interactions. Our results highlighted that short-term PM2.5 exposure and its respiratory tract depositions were dose-responsive related to higher BP, prevalence of prehypertension and hypertension among children, even when PM2.5 below CAAQS II.Sulfidized nanoscale zerovalent iron (SNZVI) with improved reactivity and selectivity has shown great potential for environmental remediation. However, it is unclear if SNZVI could be applied for the remediation of soil washing solution, and how a soil-washing surfactant affects the reactivity and selectivity of SNZVI. Here, we assess the impact of Triton X-100 (TX-100) on the reactivity and selectivity of a sulfidized commercial NZVI toward tetrabromobisphenol A (TBBPA). While sulfidation of NZVI improved its reactivity and electron efficiency toward TBBPA, TX-100 could further improve these promoting effects, which was 8-21 and 4-7 times higher than those without TX-100, respectively, depending on TX-100 concentration. Because TX-100 could induce the solubilization of TBBPA, sorb onto the SNZVI surface, and favor the subsequent sorption and degradation of TBBPA. SNZVI performance for successive treatments of TBBPA contaminated water was also greatly improved by TX-100. Moreover, washing the TBBPA-contaminated soil with TX-100 could efficiently extract the TBBPA, and almost all of the TBBPA in the soil washing solution could be efficiently degraded by SNZVI. These results suggest that TX-100 is a good additive to SNZVI for improving its performance, and SNZVI coupled with TX-100 can be a promising technology for the remediation of TBBPA-contaminated soil.The real-time monitoring of NO in the low-concentration range from the ppb- to ppm-level is of great importance in the field of healthcare; however, accomplishing this is still challenging owing to the technical issues regarding highly efficient and selective sensing materials. In this study, we demonstrate the highly sensitive and selective detection of NO by Bi-doped SnO2 two-dimensional ultrathin nanosheets with porous structures, fabricated using a facile one-step electrospinning method. It was found that the SnO2 with 0.75 mol% Bi exhibits the highest sensitivity of 217-10 ppm of NO at a relatively low temperature of 75 °C. Further, a low detection limit of 50 ppb; high selectivity; and good stability have also been achieved. Further detailed analysis indicates that the promising sensing properties can be attributed to the ultrathin nanosheet structure, which has a high surface area and abundant pores. These results indicate that 2D metal-oxide ultrathin nanosheets achieve superior gas-sensing performance, and Bi-doped SnO2 is a potential material for use in the real-time and low-power detection of NO.Mn-based catalysts are expected to be applied for removing NOx due to its excellent low-temperature activity. However, the practical use of these catalysts is extremely restricted with the co-poisoning of alkali metal and SO2 in the flue gas. Here the MnO2/TiO2 catalyst was employed to elucidate the co-poisoning mechanisms of K and SO2 for the low temperature selective catalytic reduction (SCR) of NO. The physicochemical properties of catalysts under different toxicity conditions were studied by experiments. The adsorption of NH3, SO2, NO, and K on active component (MnO2) and support (TiO2) was studied by density functional theory. This work unravels a promotion effect of support on the alkali and sulfur resistance. The SO2&K co-poisoning catalyst had higher SCR activity than the SO2-poisoned and K-poisoned catalyst alone. For a single toxic condition (1) SO2 was preferentially bonded with the terminated O site of MnO2 inhibiting the dehydrogenation of NH3 and redox cycle. (2) The presence of Lewis base (K atom) on the catalyst decreased the binding energy of a Lewis base (NH3) and hindered the adsorption of NH3. For the synergistic effect of K and SO2, the majority of K adsorbed on the support (TiO2) lead to increase alkalinity, which could promote the adsorption of SO2 on the TiO2 and reduce the toxicity of the active component (MnO2).Galaxolide (HHCB), one of the most widely used synthetic musks in personal care products (PCPs), has been recognized as an emerging contaminant with potential human health concerns. To overcome such adverse effects, a systematic molecular design, screening and performance evaluation approach was developed to generate functionally improved and environmentally friendly HHCB derivatives. Among the 90 designed HHCB derivatives, 15 were screened with improved functional properties (i.e., odor stability and intensity) and less environmental impacts (i.e., lower bio-toxicity, bio-accumulation ability, and mobility) using 3D-QSAR models and density functional theory methods. Their human health risks were then assessed by toxicokinetic analysis, which narrowed the candidates to four. Derivative 7, the designed molecule with the least dermal adsorption potential, was evaluated for its interaction with other PCPs additives (i.e., anti-photosensitivity materials and moisturizer) and such impacts on human health risks using molecular docking and molecular dynamic simulation. The environmental fate of Derivative 7 after transformation (i.e., photodegradation, biotransformation, and chlorination) was also discussed. Biotransformation and chlorination were recognized as optimum options for Derivative 7 mitigation. This study provided the theoretical basis for the design of functionally improved and environmentally friendly HHCB alternatives and advanced the understanding of their environmental behaviors and health risks.The explosively growing demand for electrical energy is generating a great deal of spent lithium-ion batteries (LIBs). Therefore, a simple and effective strategy for the sustainable recycling of used batteries is urgently needed to minimize chemical consumption and to reduce the associated environmental pollution. In this work, 2-naphthalenesulfonic acid is innovatively proposed for the highly-selective recovery of valuable metals. Impressively, lithium and cobalt are simultaneously separated through a single-step process, in which 99.3% of lithium is leached out as Li+ enriched solutions while 99% of cobalt is precipitated as cobalt-naphthalenesulfonate. The obtained lithium enriched solutions are recovered as Li2CO3. The cobalt-naphthalenesulfonate with high purity (99%) is ready to be transformed into Co3O4, and then generated into LiCoO2 by reacting with the above-obtained Li2CO3. The cathode material LiCoO2 with micro/nanostructures exhibits excellent electrochemical properties. Characterization results confirm the coordination structure of the extracted cobalt complex (Co(NS)2•6H2O). Finally, compared to other selective metal extraction techniques, this strategy avoids additional separation and purification processes, thus improving the recycling efficiency. Overall, this route can be extended to selectively extract valuable metals from other types of cathode materials in spent LIBs as a sustainable approach.Nano-bio interface is of great importance in dictating the interaction between the nanomaterials and biological system and thus the toxicity to aquatic organisms. Herein, two specific faceted TiO2 nanocrystals, 101 and 001 facet, were exposed to Daphnia magna to explore facet-dependent toxicological responses in aquatic environment. Due to the different influences on oxidative stress process, the half-maximal effective concentration (EC50) value of 001 TiO2 (1.27 g L-1) to D. magna was less than that of 101 TiO2 (1.68 g L-1). Suwannee river humic acid (SRHA) could significantly reduce the oxidative stress responses of TiO2 nanocrystals and thus alleviate their toxicities to D. SIS17 in vivo magna in aquatic environment. The protective effect of SRHA against TiO2 toxicity exhibited a facet-dependent manner. Compared to 101 TiO2, a more obvious detoxification effect was observed for 001 TiO2. The high SRHA concentration could endow both faceted TiO2 nanocrystals with a similar toxicity due to the formation of SRHA-corona on TiO2 surface. This facet-affected toxicity of nanomaterials in aquatic environment would provide us new insights in predicting the exposure risk of nanomaterials in nature waters.Antimony (Sb) contamination has brought great environmental problems to the surrounding soils. However, few studies focused on the response of bacterial communities in earthworm gut to Sb. Eisenia fetida was cultured in four soils with Sb contents (5,25,50,100 mg•kg-1) to investigate the distribution of Sb species in earthworm gut and the response mechanism of bacterial communities to Sb contamination. The results showed that Sb accumulated in the gut and tissues of earthworms, and the mortality of earthworms showed a dose-response relationship with the increase of Sb content. Sb(III) and Sbexe were the major species in gut, whereas Sb(V) and Sbsrp were predominant in surrounding soil. There were significant differences in bacterial diversity between earthworm gut and soil, but there was no significant between the two with different Sb content. The network constructed by gut bacterial community of earthworm was less stable and more sensitive to Sb species than that in soil. Sb(III) had the greatest influence on the gut bacterial community of earthworm, which not only directly affected the community through Xanthomonadaceae, Rhodomicrobiaceae and Anaerolineaceae, but also indirectly influenced through Chthoniobacteraceae. This study fills a research gap on the effect of Sb contamination on the gut bacterial community of earthworm.The aggregation of metal nanoparticles and collapse of precursor metal organic frameworks (MOFs) structure during the carbonization process largely hamper the catalytic performance of MOFs-derived carbon catalysts. Here, we report hollow and porous one-dimensional Fe/N-doped carbon nanofibers (Fe/NCNFs) for activating peroxymonosulfate (PMS), which was obtained by immobilizing Fe-MIL-101 on polyacrylonitrile (PAN) nanofibers via electrospinning technique followed by pyrolysis. The presence of one-dimensional PAN channel suppresses the agglomeration tendency of metal particles during the carbonisation process of Fe-MIL-101, resulting in a uniform dispersion of nanoparticles and an increase of catalytic active sites. The resultant Fe/NCNFs-9 possesses unique hierarchical architecture, large active surface area, well-dispersed Fe species, and abundant Fe-N active sites. These superiorities contributed to the better catalytic performance of Fe/NCNFs-9 compared with PAN derived carbon (PAN-C-9) and Fe-MIL-101 derived carbon (Fe-C-9). Through a series of inhibitor experiments and electrochemical tests, the radical pathway is dominant on BPA removal with the participation of the non-radical pathway in the multi-sites Fe/NCNFs-9/PMS/BPA system. Surprisingly, this strategy could successfully disperse Fe species and effectively reduce the Fe leaching. This work supplies a novel method to design efficient MOFs-derived carbon catalysts toward micropollutants removal.Selective and fast adsorption of five broad-spectrum β-lactam antibiotics included amoxicillin, cephalexin, cefazolin, penicillin G and oxacillin was achieved by novel surface molecular imprinting polymers (MIPs) with magnetic hybrid carbon material as the substrate. The characteristics of MIPs were studied by scanning electron microscope, Fourier transform infrared spectrometer, thermogravimetric analysis, etc. And through a series of adsorption experiments to examine the kinetics, isotherms, thermodynamics, selectivity and reusability for sorption of β-lactam antibiotics onto the MIPs. The adsorption equilibriums were accomplished in about 60 min with adsorption capacities of 4.57-24.55 mg g-1, while the adsorption process was preferably fitted with pseudo-second-order kinetic model and Freundlich model. The imprinting factors ranged from 1.88 to 9.94 indicated the MIPs possessed excellent recognition ability, and its good reusability was demonstrated after five times adsorption-desorption cycles without a large drop in adsorption capacity.