Tennantgodfrey8436

Under conditions of significant flow-induced disentanglement, the rate of change of the effective restoring force initially decreases with extension (effective spring softening) and then increases (hardens) as the maximum chain length is approached. When balanced by flow-induced chain stretching, we find that there can be two configuration states within the same De regime, as covered by the NEMD simulations; therefore, a region of conformational coexistence can indeed exist. However, we demonstrate that this coexistence of configurational microstates is only possible when the magnitude of the CCR parameters is consistent with the rate of flow-induced disentanglement, as observed in the NEMD simulations.The vibrational energy relaxation paths of hydrogen-bonded (H-bonded) OH excited in pure water and in isotopically diluted (deuterated) water are elucidated via non-equilibrium ab initio molecular dynamics (NE-AIMD) simulations. The present study extends the previous NE-AIMD simulation for the energy relaxation of an excited free OH vibration at an air/water interface [T. Ishiyama, J. Chem. Phys. 154, 104708 (2021)] to the energy relaxation of an excited H-bonded OH vibration in bulk water. The present simulation shows that the excited OH vibration in pure water dissipates its energy on a timescale of 0.1 ps, whereas that in deuterated water relaxes on a timescale of 0.7 ps, consistent with the experimental observations. To decompose these relaxation energies into the components due to intramolecular and intermolecular couplings, constraints are introduced on the vibrational modes except for the target path in the NE-AIMD simulation. In the case of pure water, 80% of the total relaxation is attributed to the pathway due to the resonant intermolecular OH⋯OH stretch coupling, and the remaining 17% and 3% are attributed to intramolecular couplings with the bend overtone and with the conjugate OH stretch, respectively. This result strongly supports a significant role for the Förster transfer mechanism of pure water due to the intermolecular dipole-dipole interactions. In the case of deuterated water, on the other hand, 36% of the total relaxation is due to the intermolecular stretch coupling, and all the remaining 64% arises from coupling with the intramolecular bend overtone.Infrasonic signals refracted by thermal gradients in the rarefied upper atmosphere are modeled using a combination of ray tracing and weak shock theory to develop an understanding of thermospheric infrasound signals produced by energetic, transient sources. Canonical arrival structures in the form of u-wave signatures are identified for returns refracted at lower altitudes within the thermosphere, and possible multi-pathing produced by effective sound speed inflections are investigated to elucidate more complex arrival structures, which are found to be spatially localized. Variability in the source characteristics is investigated and it is found that whereas some waveform phase information is lost due to finite amplitude effects, arrival characteristics are strongly dependent on the peak overpressure near the source. Variability in the propagation path is considered using archived atmospheric specifications and implies that despite uncertainties related to the dynamic and sparsely sampled nature of the atmosphere, thermospheric signatures might be useful in estimating the yield for explosive sources. Last, thermospheric arrivals from a failed rocket launch, as well as those from several large chemical explosions, are analyzed and it is found that qualitative trends match those predicted, and analyses here provide additional insight into such signatures.Collision modelling represents an active field of research in musical acoustics. Common examples of collisions include the hammer-string interaction in the piano, the interaction of strings with fretboards and fingers, the membrane-wire interaction in the snare drum, reed-beating effects in wind instruments, and others. At the modelling level, many current approaches make use of conservative potentials in the form of power-laws, and discretisations proposed for such models rely in all cases on iterative root-finding routines. Here, a method based on energy quadratisation of the nonlinear collision potential is proposed. It is shown that there exists a suitable discretisation of such a model that may be resolved in a single iteration, while guaranteeing stability via energy conservation. Entinostat Applications to the case of lumped as well as fully distributed systems will be given, using both finite-difference and modal methods.Semi-occluded vocal tract exercises (SOVTEs) are increasingly popular as therapeutic exercises for patients with voice disorders. This popularity is reflected in the growing research literature, investigating the scientific principles underlying SOVTEs and their practical efficacy. This study examines several acoustic, articulatory, and aerodynamic variables before, during, and after short-duration (15 s) SOVTEs with a narrow tube in air. Participants were 20 healthy young adults, and all variables were measured at threshold phonation levels. Acoustic variables were measured with a microphone and a neck accelerometer, and include fundamental frequency, glottal open quotient, and vocal efficiency. Articulatory variables were measured with ultrasound, and include measures of the tongue tip, tongue dorsum, and posterior tongue height, and horizontal tongue length. Aerodynamic variables were measured with an intraoral pressure transducer and include subglottal, intraoral, and transglottal pressures. Lowering of the posterior tongue height and tongue dorsum height were observed with gender-specific small changes in the fundamental frequency, but there were no significant effects on the transglottal pressure or vocal efficiency. These findings suggest that the voices of healthy young adults already approach optimal performance, and the continued search for scientific evidence supporting SOVTEs should focus on populations with voice disorders.A numerical model of full-scale N-wave sonic boom propagation through turbulence is described based on the nonlinear Khokhlov-Zabolotskaya-Kuznetzov (KZK) propagation equation and the most advanced turbulence model used in atmospheric acoustics. This paper presents the first quantitative evaluation of a KZK-based model using data from the recent Sonic Booms in Atmospheric Turbulence measurement campaigns, which produced one of the most extensive databases of full-scale distorted N-waves and concurrent atmospheric parameters. Simulated and measured distributions of the perceived level (PL) metric, which has been used to predict public annoyance due to sonic booms, are compared. For most of the conditions considered, the present model's predictions of the PL variances agree with the measurement to within normal uncertainty, while about half of the mean value predictions agree. The approximate PL distribution measured for high turbulence conditions falls within about 2 dB of the simulated distribution for nearly all probabilities.