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The inhibitory effect of the binary combination on PAH-d10 root uptake was attributed to decreased root lipid content and phytoavailable concentrations of PAHs-d10 in soil as a consequence of biodegradation, aging effect and cation-π interaction. The antagonism between warming and Cu on spinach uptake could be explained by their opposite effects on PAH-d10 biodegradation and the inhibition of the cation-π interaction caused by warming. Additionally, the shoot uptake of PAHs-d10 was mainly controlled by their soil to air to shoot partitioning. The findings suggest that the interactive effects of climate warming and co-existing pollutants should be taken into account for the assessment of plant uptake and health risk of PAHs. The adsorption and desorption behaviors of Cd(II) and Pb(II) on goethite have important effects on the mobility and bioavailability of these compounds in soils. However, while the respective adsorption isotherms have been extensively investigated, the kinetic process has often been overlooked. Thus, in batch adsorption and stirred-flow experiments this study investigated the thermodynamic and kinetic behaviors of Cd(II) and Pb(II) on goethite as a function of the pH and the loading concentration. CD-MUSIC and integrated kinetic models were proposed to predict metal adsorption behavior, after careful consideration of the surface properties and site heterogeneity of goethite. The results showed that both the surface species and the binding ability of the two metals differed. While Cd(II) formed two corner-sharing species, (≡FeOH)2Cd+ and (≡FeOH)2CdOH, Pb(II) formed two weak corner-sharing species, (≡FeOHa)2Pb+ and (≡FeOHa)2PbOH, and one strong edge-sharing species, (≡FeOHb)2Pb+. Optimized binding constants (logK) and desorption rate coefficients (kdi) were calculated to quantify the contribution of each surface species to equilibrium adsorption and time-dependent adsorption/desorption under various conditions. Compared with Cd(II), the adsorption of Pb(II) on goethite has two kinds of reaction processes with different affinities, which was attributed to the site heterogeneity of goethite. The proposed model has the potential to be applied to various chemical conditions and goethite samples. Salinity variability strongly affects the behaviors of oil degrading bacteria for spilled oil biodegradation in the marine environment. However, limited studies explored the strategies of microbes on salinity-mediated crude oil biodegradation. In this study, a halotolerant bio-emulsifier producer, Exiguobacterium sp. click here N41P, was examined as a model strain for Alaska North Slope (ANS) crude oil (0.5%, v/v) biodegradation. Results indicated that Exiguobacterium sp. N41P could tolerant a wide range of salinity (0-120 g/L NaCl) and achieve the highest degradation efficiency under the salinity of 15 g/L NaCl due to the highest biofilm formation ability. Moreover, increased salinity induced decreased cell surface hydrophobicity and a migration of microbial growth from oil phase to aqueous phase, leading to limited bio-emulsifier productivity and depressed degradation of insoluble long-chain n-alkanes while enhancing the degradation of relative soluble naphthalene. Research findings illustrated the microbial eco-physiological mechanism for spilled oil biodegradation under diverse salinities and advanced the understanding of sophisticated marine crude oil biodegradation process. Hospitals consume a large amount of water, so they also generate large amounts of wastewater, which contain a wide variety of contaminants. It is important to consider that hospital effluents are a mixture of pollutants that can interact with each other and have a negative impact on aquatic species of water bodies. The aim of this study was to evaluate the effects induced by a hospital effluent using Danio rerio embryos. In this study, Danio rerio embryos were exposed to different concentrations of the hospital effluent and a lethality test was evaluated and the malformations present in zebrafish embryos were evaluated. The lethal concentration of effluent 50% was 6.1% and the effective malformation concentration was of 2.5%. The teratogenic index was 2.45%. The main malformations identified were yolc sac malformation, pericardial edema, hatching abnormalities, hypopigmentation, tail deformation, chorda malformation, without fin, chorion deformation and craniofacial malformation. The risks that this type of water represents for the survival of living organisms, as well as the presence of malformations in them, are reference indicators for a future regulation focused on the adequate treatment of hospital effluents. Wetland buffer zones (WBZs) are riparian areas that form a transition between terrestrial and aquatic environments and are well-known to remove agricultural water pollutants such as nitrogen (N) and phosphorus (P). This review attempts to merge and compare data on the nutrient load, nutrient loss and nutrient removal and/or retention from multiple studies of various WBZs termed as riparian mineral soil wetlands, groundwater-charged peatlands (i.e. fens) and floodplains. Two different soil types ('organic' and 'mineral'), four different main water sources ('groundwater', 'precipitation', 'surface runoff/drain discharge', and 'river inundation') and three different vegetation classes ('arboraceous', 'herbaceous' and 'aerenchymous') were considered separately for data analysis. The studied WBZs are situated within the temperate and continental climatic regions that are commonly found in northern-central Europe, northern USA and Canada. Surprisingly, only weak differences for the nutrient removal/retention capabiland now unsuitable for conventional farming. V.Antibiotic resistance genes (ARGs) harbored by plant microbiomes have been implicated as a potential risk to public health via food chain, especially directly edible fruits and vegetables. Here, we investigated the microbiome and antibiotic resistome in soil-strawberry ecosystem using shotgun metagenomic sequencing. The results showed that the enterobacterial population dominated the endophytes of strawberry fruits. Moreover, 85 subtypes of ARGs, including several clinically important ARGs, were detected in the strawberry fruit metagenomes. Additionally, host tracking analysis in combination with antibiotic-resistant bacterial isolate screening suggested that fruit-borne ARGs were mainly carried by members of the Enterobacteriaceae family. Unexpectedly, most of fruit-borne isolates were found to be resistant to several clinically important antimicrobials, e.g., erythromycin and cephalexin. Our findings provide broad insights into endophytic antibiotic resistomes of direct edible strawberry fruits and their potential hosts, and highlight the potential exposure risks of plant microbiomes to the human food chain.

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