Steincarlsen5580

The developed method was validated, observing matrix effect in all matrices. Intra- and inter-day precision were estimated, and relative standard deviation were lower than 19%. Recoveries were satisfactory, and mean values ranged from 70% to 110%. Limits of quantification were between 25 and 100 µg kg-1. Finally, the analytical method was applied to different fruits and vegetables (oranges, tomatoes, aubergines and grapes).In this study, a comparative study of carbon fiber reinforced polymer (CFRP) bar and steel-carbon fiber composite bar (SCFCB) reinforced coral concrete beams was made through a series of experimental tests and theoretical analyses. The flexural capacity, crack development and failure modes of CFRP and SCFCB-reinforced coral concrete were investigated in detail. They were also compared to ordinary steel-reinforced coral concrete beams. The results show that under the same conditions of reinforcement ratios, the SCFCB-reinforced beams exhibit better performance than CFRP-reinforced beams, and stiffness is slightly lower than that of steel-reinforced beams. Under the same load conditions, the crack width of SCFCB beams was between that of steel-reinforced beams and CFRP bar-reinforced beams. Before the steel core yields, the crack growth rate of SCFCB beam is similar to the steel-reinforced beams. SCFCB has a higher strength utilization rate-about 70-85% of its ultimate strength. Current design guidance was also examined based on the test results. It was found that the existing design specifications for FRP-reinforced normal concrete is not suitable for SCFCB-reinforced coral concrete structures.In this review, we describe a simple and general procedure to accomplish selective photochemical reaction sequences for two chromophores that are responsive to similar light frequencies. The essence of the method is based on the exploitation of differences in the molar absorptivity at certain wavelengths of the photosensitive groups, which is enhanced by utilizing light-absorbing auxiliary filter molecules, or "sunscreens". Thus, the filter molecule hinders the reaction pathway of the least absorbing molecule or group, allowing for the selective reaction of the other. The method was applied to various photochemical reactions, from photolabile protecting group removal to catalytic photoinduced olefin metathesis in different wavelengths and using different sunscreen molecules. Additionally, the sunscreens were shown to be effective also when applied externally to the reaction mixture, avoiding any potential chemical interactions between sunscreen and substrates and circumventing the need to remove the light-filtering molecules from the reaction mixture, adding to the simplicity and generality of the method.Increasing the strain rate at superplastic forming is a challenging technical and economic task of aluminum forming manufacturing. New aluminum sheets exhibiting high strain rate superplasticity at strain rates above 0.01 s-1 are required. This study describes the microstructure and the superplasticity properties of a new high-strength Al-Zn-Mg-based alloy processed by a simple thermomechanical treatment including hot and cold rolling. The new alloy contains Ni to form Al3Ni coarse particles and minor additions of Zr (0.19 wt.%) and Sc (0.06 wt.%) to form nanoprecipitates of the L12-Al3 (Sc,Zr) phase. The design of chemical and phase compositions of the alloy provides superplasticity with an elongation of 600-800% in a strain rate range of 0.01 to 0.6/s and residual cavitation less than 2%. A mean elongation-to-failure of 400% is observed at an extremely high constant strain rate of 1 s-1. The strain-induced evolution of the grain and dislocation structures as well as the L12 precipitates at superplastic deformation is studied. The dynamic recrystallization at superplastic deformation is confirmed. The superplastic flow behavior of the proposed alloy is modeled via a mathematical Arrhenius-type constitutive model and an artificial neural network model. Both models exhibit good predictability at low and high strain rates of superplastic deformation.Following status epilepticus (SE, a prolonged seizure activity), microglial activation, and monocyte infiltration result in the inflammatory responses in the brain that is involved in the epileptogenesis. Therefore, the regulation of microglia/monocyte-mediated neuroinflammation is one of the therapeutic strategies for avoidance of secondary brain injury induced by SE. 2-cyano-3,12-dioxooleana-1,9-dien-28-oic acid methyl ester (CDDO-Me; RTA 402) is an activator of nuclear factor-erythroid 2-related factor 2 (Nrf2), which regulates intracellular redox homeostasis. In addition, CDDO-Me has anti-inflammatory properties that suppress microglial proliferation and its activation, although the underlying mechanisms have not been clarified. In the present study, CDDO-Me ameliorated monocyte infiltration without vasogenic edema formation in the frontoparietal cortex (FPC) following SE, accompanied by abrogating monocyte chemotactic protein-1 (MCP-1)/tumor necrosis factor-α (TNF-α) expressions and p38 mitogen-activated protein kinase (p38 MAPK) phosphorylation. Furthermore, CDDO-Me inhibited nuclear factor-κB (NFκB)-S276 phosphorylation and microglial transformation, independent of Nrf2 expression. Similar to CDDO-Me, SN50 (an NFκB inhibitor) mitigated monocyte infiltration by reducing MCP-1 and p38 MAPK phosphorylation in the FPC following SE. Therefore, these findings suggest, for the first time, that CDDO-Me may attenuate microglia/monocyte-mediated neuroinflammation via modulating NFκB- and p38 MAPK-MCP-1 signaling pathways following SE.Homogeneous palladium-catalyzed (Pd-catalyzed) cyclocarbonylation of unsaturated allylic alcohols and alkynols in the presence of hydrogen forms lactone products with important applications in the food, perfume, and polymer industry. Protein Tyrosine Kinase inhibitor In this work, the cyclocarbonylation of 2-methyl-3-buten-2-ol was studied for the first time using a very active Pd-DPEphos (bis[(2-diphenylphosphino)phenyl]ether) catalyst in the presence of the ionic liquid (IL) [BMIM]Cl (1-butyl-3-methylimidazolium chloride) in dichloromethane to selectively produce 4,4-dimethyl-γ-butyrolactone. The effect of different parameters such as temperature, gas partial pressures, time of reaction, substrate and ligand concentrations were investigated and found to provide optimal conditions for lactonization (95 °C, 28 bar (CO/H2/N2 20/5/3)), 18 h, 0.1 M substrate, and 16 mol% DPEphos), which were significantly milder than previously reported systems for cyclocarbonylation. Importantly, the study further showed that presence of the IL in the reaction mixture provided stabilization of the catalyst system and prevented formation of Pd-black, which allowed reuse of the catalytic system in consecutive reactions after intermediate extraction of the lactone product.