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4 mg g-1 with outstanding cycling stability. Moreover, the low energy consumption of 0.23 Wh g-1 is also suitable for practical application. The dual strategy opens a window to design advanced electrode materials for CDI.Latent fingerprint recognition technique has received increasing attention because it helps to precisely identify human information for many applications. selleck In this study, bifunctional core-shell magnetic fluorescent microspheres have been synthesized via a facile interface Pechini-type sol-gel method using citric acid and polyethylene glycol as chelating agent and cross-linking agent, respectively. The obtained Fe3O4@YVO4Eu3+ microspheres possess a typical core-shell structure, large magnetization, and strong fluorescence emission. The surface morphology and roughness of the microspheres can be flexibly tuned by controlling the multistep interface deposition process and subsequent calcination temperatures. Due to their well-integrated bifunctionalities, these magnetic fluorescent microspheres show outstanding performance in the visualization of latent fingerprints on various substrates with high definition and excellent anti-interference, and therefore they have great potential for application in identity recognition.In the inflammatory peri-implant microenvironment, excessive polarization of macrophages to the proinflammatory M1 phenotype can trigger the secretion of inflammatory cytokines, which promote bone resorption and impede osteogenesis around implants. The direct consequence of this process is the failure of prosthetic implants due to aseptic loosening. To reverse the inflammatory microenvironment and prevent prosthesis loosening, a mussel adhesion-inspired surface strategy was used for bioengineering of titanium implants with integrin-binding ability. In our design, a mussel-inspired catecholic peptide with tetravalent 3,4-dihydroxy-l-phenylalanine (DOPA) and Arg-Gly-Asp (RGD) sequences was synthesized. The peptide can easily anchor to the surface of medical titanium materials through a mussel adhesive mechanism. We found that peptide-decorated titanium implants could effectively inhibit peri-implant inflammation in a wear particle model and could promote the polarization of macrophages to a pro-healing M2 phenotype by interfering with integrin-α2β1 and integrin-αvβ3. Moreover, the peptide coating increased the adherence of osteoblasts and promoted osteogenesis on titanium implants even under inflammatory conditions. This work suggested that this biomimetic catecholic integrin-binding peptide can provide facile tactics for surface bioengineering of medical prostheses with improved interfacial osteogenesis under inflammatory conditions, which might contribute greatly to the prevention of prosthesis loosening and the improvement of clinical outcomes.The dynamics of a series of soft colloids comprised of polystyrene cores with poly(N-isopropylacrylamide) (PNIPAM) coronas was investigated by diffusing wave spectroscopy (DWS). The modulus of the coronas was varied by changing the cross-link density and we were able to interpret the results within a hard-soft mapping framework. The soft, swellable particle properties were modeled using an extended Flory-Rehner theory and a Hertzian pair potential. Following volume fraction jumps, softness effects on the concentration dependence of dynamics were determined, with a 'soft colloids make strong glass-forming liquid'-type of behavior observed close to the nominal glass transition volume fraction, φg. Such behavior from the current systems cannot be fully explained by the osmotic deswelling model alone. However, inspired by the soft-hard mapping from Schmiedeberg et al, [Europhys. Lett. 2011, 96(3), 36010] we estimated effective hard-sphere diameters and achieved a successful mapping of the α-relaxation times to a master curve below φg. Above φg, the curves no longer collapse but show strong deviations from a Vogel-Fulcher type of divergence onto soft jamming plateaux. Our results provide evidence that osmotic deswelling itself cannot fully explain the observed dynamics. Softness also plays an important role in the dynamics of soft, concentrated colloids.A reasonable introduction of MOFs-derived Ni2P with high dispersity is a valid way to reduce the recombination rate of photogenerated electron-holes, thus for more effective visible-light-driven water splitting. In this study, Ni-MOF-74/Ni2P precursor was obtained by low-temperature phosphating method. A ternary heterojunction Ni-MOF-74/Ni2P/MoSx with a unique structure is obtained by a solution-based mixing method. The unique structure of Ni-MOF-74/Ni2P provides advantages for MoSx load. The UV-visible diffuse reflectance spectroscopy proves that the introduction of Ni2P improves the utilization of visible light by the composite catalyst 10%-NPMS and promotes more electrons generation, thereby improving photocatalytic hydrogen production activity. It is proved that the introduced Ni2P can accelerate the separation of photogenerated carriers by characterization (PL, EIS, LSV, etc.) analyses. The composite catalyst 10%-NPMS with the best hydrogen production activity was obtained by adjusting the ratio between Ni-MOF-74/Ni2P and MoSx. The photocatalytic hydrogen evolution of the composite catalyst 10%-NPMS (286.16 μmol) is 28.30, 2.78, 3.79 and 2.41 times that of pure Ni-MOF-74, Ni2P, MoSx and binary 10%-Ni-MOF-74/MoSx within 5 h, respectively. And the hybrid 10%-Ni-MOF-74/Ni2P/MoSx exhibits excellent photocatalytic hydrogen evolution performance and good stability. This research will provide a new strategy for synthesizing unique ternary composite materials by using metal organic framework materials as precursors.Herein, the CaTiO3/Cu/TiO2 all-solid-state Z-scheme heterojunction is successfully designed via Cu nanoparticles situating at the interface between CaTiO3 and TiO2 with a new synthesis route. Interestingly, TiO2 nanosheets are generated in-situ on the surface of CaTiO3 in the second step hydrothermal reaction. The lifetimes of photoexcited carriers, photoluminescence emission spectra and transient photocurrent response tests have confirmed that the efficient Z-scheme charge transmission path of the CaTiO3/Cu/TiO2 is beneficial to facilitate the separation of photogenerated carriers and reduce their recombination efficiency. As expected, the hydrogen generation rate of CaTiO3/Cu/TiO2 is increased to 23.550 mmol g-1h-1 with the appropriate amount of copper loading, which is about 981 times and 93 times higher than that of pristine CaTiO3 (0.024 mmol g-1h-1) and CaTiO3/TiO2 (0.253 mmol g-1h-1), respectively. Furthermore, the CaTiO3/Cu/TiO2 sample shows good stability in cycle experiments. Particularly, experimental results show that the non-noble metal Cu nanoparticles can be an effective electron mediator. And these merits strongly demonstrate that the CaTiO3/Cu/TiO2 composites have potential application in photocatalytic field. This study can provide fundamental guidance for designing rationally efficient non-noble metal vector Z-scheme system photocatalysts with outstanding photocatalytic H2 generation performance.Carbon dots (CDs) are the unique class of luminescent nanomaterials consist of various chromophoric units heterogeneously distributed throughout the nanoparticle, resulting intriguing multistate emissive properties. Herein, we have critically investigated the specific locations of the blue and green-emitting centers inside dual emissive CDs by steady-state and time-resolved polarized emission study. It is further clarified by a temperature-dependent fluorescence study for both the emitting domains. Results suggest that the blue chromophoric units are located at the interior part of CDs, while green units are mostly at the exterior region. Furthermore, we have investigated the solvent-dependent inter-chromophoric interactions between the two emissive domains by the Time-Resolved Area Normalized Emission Spectroscopy (TRANES). Results suggest that at polar aprotic solvent acetone, time-dependent positive evolution of green-emitting states and negative evolution of blue emissive domains have been observed. This reversible emitting properties evolve due to the excited state energy migration from blue emissive domains to green emissive domains at polar aprotic medium, while in the case of polar protic solvent water, this phenomenon is missing. This switchable inter-chromophoric interaction are correlated further with the inter-particle interactions of CDs.

Organic co-solvents, which are universally employed in adsorption studies of hydrophobic organic chemicals (HOCs), can inhibit HOC adsorption by competing for active sites on the adsorbent. The adsorbent structure can influence co-solvent interference of HOC adsorption; however, this effect remains unclear, leading to an incomplete understanding of the adsorption mechanism.

In this study, dioctyl phthalate (DOP) was used to investigate competitive adsorption on functionalized graphene sheet in a water-methanol co-solvent system through molecular dynamics simulations and quantum chemical calculations.

The simulations showed that the functional groups in the graphene defects had a strong adsorption affinity for methanol. The adsorbed methanol occupied a large number of active sites at the graphene center, thereby weakening DOP adsorption. However, the methanol adsorbed at the graphene edges could not compete with DOP for the active sites. -COOH had the strongest binding affinity for methanol among the funtionalized graphene sheet, especially in visualizing the competition for active sites, and provides theoretical guidance for the removal of HOCs and practical application of graphene.The introduction of oxygen-defects has been a versatile strategy to enhance photocatalysis efficiency. In this work, a 2D/3D Bi/BiO2-x/Bi2WO6 heterojunction photocatalyst with rich oxygen-defective was in sequence prepared through a facile solvothermal method, which displays favorable photocatalytic activity towards organic contaminants under visible-NIR light irradiation. The enhancement in photocatalytic performance can be attributed to the synergistic effect between oxygen-vacancy-rich heterojunction and the localized surface plasmon resonance induced by metallic Bi. The functional group interaction, surface morphology, crystal structure, element composition, and tuned bandgap were investigated by FT-IR, SEM, Raman shift, ICP-MS, and XPS technique. The spectrum response performance of the photocatalyst was verified by UV-visible DRS analysis. Results of photodegradation experiments toward organic contaminants showed that the prepared photocatalyst can degrade 90% of phenol in 20 mins under visible-NIR light irradiation, both Z-scheme heterojunction and the introduction of Bi metal contribute to the enhancement in the photocatalytic activity. The results of the DFT calculation suggest that the valence band-edge hybridization within BiO2-x and Bi2WO6 can effectively enhance the photocatalytic performance by increasing the migration efficiencies of electron-hole pairs. Moreover, a possible mechanism was proposed on the results of EIS, ESR and GC-MS tests. This work offers a novel insight for synthesizing efficient visible-NIR light photocatalysis by activating the semiconductors with Bi metal.