Shortclemmensen5645

The disposal of solid residues in sanitary landfills results in the formation of a complex, variable, and recalcitrant wastewater, known as leachates. Supercritical water oxidation (ScWO) can be applied to treat leachates although most studies are based on removing the most relevant contaminants, such as organic matter and ammonia. Therefore, comprehensive analysis of this process is essential for large-scale applications. In this study, we investigated a system composed of ScWO and ion exchange using zeolite (ScWO/zeolite) for the reuse possibilities of treated leachates based on different regulations for municipal wastewater reuse. This system was applied to both raw leachate (RL) and leachate treated via conventional processes at the studied landfill (PL). The continuous ScWO reactor operated under a pressure of 23 MPa at 600 °C without the addition of oxidants. A commercial zeolite (clinoptilolite) in a fixed-bed glass column was used for ion exchange. The intensified system significantly improved the characteristics of RL by removing 89% of COD and 99% of NH3-N. Moreover, the contaminant concentrations of PL were within the limits for discharge and reuse, except arsenic and molybdenum contents. The unexpected high concentrations of arsenic in RL and PL necessitated the requirement of further investigation of the complex and toxic characteristics of leachates. Nevertheless, the intensified process was conducted without the addition of oxidants or auxiliary substances and resulted in a less expensive and more environmentally -friendly process that can be applied for the treatment of leachates with similar characteristics.A total of 51 water and 43 sediment samples were collected from the locations surrounding the two e-waste dismantling zones in Taizhou, the Fengjiang resource recycling industrial zone (FJ, shut down in 2017) and the Taizhou resource recycling base (TZ, newly constructed in recent years). The concentrations of polybrominated diphenyl ethers (PBDEs) ranged from 1.7 to 44 ng/L in water and from not detected (nd) to 7100 ng/g in sediment. Novel brominated flame retardants (NBFRs) ranged from 0.29 to 1.6 ng/L in water, and from nd to 5300 ng/g in sediment. The levels of PBDEs and NBFRs in the water were comparable between FJ and TZ, while their concentrations were higher in the sediment from FJ than those from TZ. The levels of BDE-28, BDE-153, pentabromotoluene (PBT), pentabromobenzene (PBB), ∑PBDEs and ∑BFRs in the water from FJ or TZ were found to be significantly negatively associated with the distance from the zone center. However, in the sediments from FJ and TZ, the BFRs levels did not decrease from the center to the outer regions. BDE-209 and decabromodiphenyl ethane (DBDPE) were predominant in the sediments and the ratio of DBDPE/BDE-209 were as high as 5.6 (mean 0.97). The mass burden of PBDEs, BDE-209, DBDPE, 1,2-bis(2,4,6-tribromophenoxy) ethane (BTBPE), and HBB in the riverine sediments in Luqiao District was 829, 787, 363, 85, and 61 kg, respectively. The ecological risk assessment revealed that BDE-99 posed an unacceptable risk to aquatic life at 86% of the locations. The hazard quotients for penta-BDE, BDE-209, and HBB exceeded one for 30%, 28%, and 2.3% of the sediment samples, respectively.There is public and scientific concern about air, soil and water contamination and possible adverse environmental and human health effects as a result of hydraulic fracturing activities. The use of greener chemicals in fracturing fluid aims to mitigate these effects. This study compares fracturing fluids marketed as either 'conventional' or 'green', as assessed by their chemical composition and their toxicity in bioassays. Chemical composition was analysed via non-target screening using liquid chromatography - high resolution mass spectrometry, while toxicity was evaluated by the Ames fluctuation test to assess mutagenicity and CALUX reporter gene assays to determine specific toxicity. Overall, the results do not indicate that the 'green' fluids are less harmful than the 'conventional' ones. First, there is no clear indication that the selected green fluids contain chemicals present at lower concentrations than the selected conventional fluids. Second, the predicted environmental fate of the identified compounds does not seem to be clearly distinct between the 'green' and 'conventional' fluids, based on the available data for the top five chemicals based on signal intensity that were tentatively identified. read more Furthermore, Ames fluctuation test results indicate that the green fluids have a similar genotoxic potential than the conventional fluids. Results of the CALUX reporter gene assays add to the evidence that there is no clear difference between the green and conventional fluids. These results do not support the claim that currently available and tested green-labeled fracturing fluids are environmentally more friendly alternatives to conventional fracturing fluids.The dual isotope fractionation of nitrogen (N) and oxygen (O) is an effective way to track the transformation of NO3--N in biological denitrification process. The Sulfur autotrophic denitrification combined with the different concentrations of S2O32- was investigated using the dual isotope fractionation of nitrogen (N) and oxygen (O) to reveal the nitrogen removal mechanism of the activated sludge. Based on successful autotrophic denitrification incubation, the modified Logistic model responded to the short-term effects of S2O32- addition on NO3--N removal and SO42- generation. Under the S2O32- addition of 0.5, 1, 2 and 4 times of the incubation stage (49.29 mg/L-394.32 mg/L), the fractionation effect of N in NO3--N (15εNO3) decreased from 8.74 ± 1.81‰ to 2.08 ± 0.06‰, and the fractionation effect of O in NO3--N (18εNO3) declined from 11.34 ± 0.46‰ to 5.48 ± 0.46‰. The 15εNO3/18εNO3 was maintained at 0.46-0.94, indicating a negative correlation between addition amount and isotope effect, and the addition of high concentrations of S2O32- was not suitable for system stabilization. Moreover, the 18O-labeled H2O (δ18OH2O) tests significantly proved the presence of O exchange between NO2--N/NO3--N and H2O (67%/97%) during the nitrogen removal process, while the reoxidation of NO2--N was explored in the autotrophic denitrification. The kinetic models coupled with isotope fractionation effectively revealed the nitrogen removal characteristics in the autotrophic denitrification systems, and verified the difference between the activated sludge-based wastewater treatment process and the natural ecosystem.In this study, we investigated a fractured karst aquifer polluted by chlorinated hydrocarbons to determine the contamination characteristics of the main hydrocarbon components. The natural attenuation processes of representative components were simulated and forecasted using TMVOC and hydro-chemical components (NO3-, SO42-, HCO3- Cl- and δ13CDIC). The impact of hydrocarbon compounds on the hydro-chemical ions were estimated, and their historical contamination characteristics were also reconstructed. Results showed that the dynamic characteristics of Trichloromethane and 1,1,2-Trichlorethane can indicate those of chlorinated hydrocarbons, where the rate of natural attenuation was observed to decrease with decreasing concentrations of hydrocarbon compounds. Additionally, the long-term variation characteristics in groundwater levels showed that the relatively stable hydrodynamic field conditions enabled the simulation of the natural attenuation processes of chlorinated hydrocarbons. The simulation which also considered the biodegradation processes showed that the use of TMVOC and hydro-chemical parameters may better describe natural attenuation processes. Over 3 years (from 2017 to 2019), the average percentage of biodegradation in the total natural attenuation was estimated to be 88.35%. Similarly, Trichloromethane and 1,1,2-Trichlorethane are forecasted to have no health hazards in 10 and 15 years, respectively. The contribution rates of biodegradation to HCO3- and Cl- in the fractured karst aquifer varied with the concentrations of chlorinated hydrocarbons. Overall, the findings and methods in this work have significant contributions for advancing remediation developments of petroleum hydrocarbons, especially in karst environments that are highly susceptible to contamination.This paper describes the new concept of the mainstream partial nitritation (PN)-anaerobic ammonium oxidation (ANAMMOX) combined with a high-temperature shock strategy for the selective recovery of ammonia-oxidizing bacteria (AOB) activity. In the preliminary test, the temperature shock condition for PN was optimized (60 °C and > 20 min). Based on this, the implementation strategy in a continuous stirred tank reactor (CSTR) system was studied further, and the polyvinyl alcohol (PVA)/sodium alginate carrier exposure ratio (ER) and dissolved oxygen (DO) concentration were considered as primary variables. The AOB activity was recovered selectively when the ER of the carrier ranged from 20 to 40%, and the DO was higher than 2.3 mg O2/L. This was not the case for nitrite-oxidizing bacteria (NOB) (AOB 1.17±0.1 gNH4+-N/LCarrier/d, NOB 0.34±0.1 gNO3--N/LCarrier/d). As a result, the activity of AOB was recovered selectively with a decrease in Nitrospira spp., which was verified by kinetic and microbial analyses for the AOB (KS, DO = 3.89 mgO2/L) and NOB (KS, DO = 1.14 mgO2/L). Eventually, the mainstream PN-ANAMMOX was achieved with a nitrogen removal efficiency of 81.5±3.3% for 95 days. The findings provide insight to establishing a stable mainstream PN-ANAMMOX process using a high-temperature shock strategy.Understanding of biological responses of marine fauna to seawater acidification due to potential CO2 leakage from sub-seabed storage sites has improved recently, providing support to CCS environmental risk assessment. Physiological responses of benthic organisms to ambient hypercapnia have been previously investigated but rarely at the cellular level, particularly in areas of less common geochemical and ecological conditions such as brackish water and/or reduced oxygen levels. In this study, CO2-related responses of oxygen-dependent, antioxidant and detoxification systems as well as markers of neurotoxicity and acid-base balance in the Baltic clam Limecola balthica from the Baltic Sea were quantified in 50-day experiments. Experimental conditions included CO2 addition producing pH levels of 7.7, 7.0 and 6.3, respectively and hydrostatic pressure 900 kPa, simulating realistic seawater acidities following a CO2 seepage accident at the potential CO2-storage site in the Baltic. Reduced pH interfered with most biomarkers studied, and modifications to lactate dehydrogenase and malate dehydrogenase indicate that aerobiosis was a dominant energy production pathway. Hypercapnic stress was most evident in bivalves exposed to moderately acidic seawater environment (pH 7.0), showing a decrease of glutathione peroxidase activity, activation of catalase and suppression of glutathione S-transferase activity likely in response to enhanced free radical production. The clams subjected to pH 7.0 also demonstrated acetylcholinesterase activation that might be linked to prolonged impact of contaminants released from sediment. The most acidified conditions (pH 6.3) stimulated glutathione and malondialdehyde concentration in the bivalve tissue suggesting potential cell damage. Temporal variations of most biomarkers imply that after a 10-to-15-day initial phase of an acute disturbance, the metabolic and antioxidant defence systems recovered their capacities.