Sanforderichsen4707

The spills of crude oil and other organic chemicals are common around the world, resulting in severe damage to the environment and ecosystem. Therefore, developing low-cost and eco-friendly absorption material is in urgent need. In this study, we report a superhydrophobic and oleophilic porous material using biomass cuttlebone as the scaffold. A layer of polydopamine is grafted on the cuttlebone as the adhesion layer between the cuttlebone and the superhydrophobic coating. The in situ grown silica micro/nanoparticles on top of the adhesion layer provide the anchoring spots for grafting the fluorinated hydrocarbon and a rough topography for realizing superhydrophobicity. The static water contact angle of the superhydrophobic cuttlebone reaches 152°, and its oil contact angle is ~0°. The excellent oil-water separation efficiency of the prepared superhydrophobic cuttlebone is demonstrated using high-density oil/water mixtures and low-density oil/water mixtures.This paper presents research on the application of magnetic shape memory alloys (MSMAs) in actuator design. MSMAs are a relatively new group of so-called smart materials that are distinguished by repeatable strains up to 6% and dynamics much better than that of thermally activated shape memory alloys (SMAs). The shape change mechanism in MSMAs is based on the rearrangement of martensite cells in the presence of an external magnetic field. In the first part of the article a review of the current state of MSMA actuator design is presented, followed by a description of the design, modelling and control of a newly proposed actuator. The developed actuator works with MSMA samples of 3 × 10 × 32 mm3, guaranteeing an available operating range of up to 1 mm, despite its great deformation range and dynamics. In the paper its dynamics model is proposed and its transfer function is derived. Moreover, the generalised Prandtl-Ishlinskii model of MSMA-actuator hysteresis is proposed. This model is then inverted and used in the control system for hysteresis compensation. A special test stand was designed and built to test the MSMA actuator with compensation. The step responses are recorded, showing that the compensated MSMA actuator exhibits the positioning accuracy as ±2 µm. As a result, the authors decided to apply a control system based on an inverse hysteresis model. The paper concludes with a summary of the research results, with theoretical analysis compared with the registered actuator characteristics.Silk fibroin (SF) is a natural protein polymer and promising biomaterial. Chemical modifications have attracted growing interest in expanding SF applications. However, the majority of amino acid residues in SF are non-reactive and most of the reactive ones are in the crystalline region. Herein, a modification was conducted to investigate the possibility of direct modification on the surface of natural SF by a reagent with a mild reactivity, the type and quantity of the residues involved in the reactions, and the structural changes upon modification. Infrared spectrum, 1H NMR, titration and amino acid analyses, X-ray diffraction, and hemolysis test were used to analyze the materials. The results showed that sulfonic acid groups were grafted onto SF and the reaction occurred mainly at serine residues through hydroxyl groups. In total, 0.0958 mmol/g of residues participated in the modification with a modification efficiency of 7.6%. Moreover, the crystallinity and the content of β-sheet structure in SF increased upon modification. The modified material had good blood-compatibility. In conclusion, surface modification on native SF through serine residues was practicable and had the advantage of increased β-sheet structure. This will provide an alternative way for the modification of fibroin for the desired application in the biomedical field.Dental remineralization represents the process of depositing calcium and phosphate ions into crystal voids in demineralized enamel, producing net mineral gain and preventing early enamel lesions progression. The aim of the present study was to qualitatively and quantitatively compare the remineralizing effectiveness of four commercially available agents on enamel artificial lesions using Scanning Electron Microscopy (SEM) combined with Energy Dispersive Spectroscopy (EDS) techniques. Thirty-six extracted third molars were collected and randomly assigned to six groups (n = 6), five of which were suspended in demineralizing solution for 72 h to create enamel artificial lesions, and one serving as control G1, treated with a mousse of casein phosphopeptide and amorphous calcium-phosphate (CPP-ACP); G2, treated with a gel containing nano-hydroxyapatite; G3, treated with a 5% SF varnish; G4, treated with a toothpaste containing ACP functionalized with fluoride and carbonate-coated with citrate; G5, not-treated artificial enamel lesions; G6, not demineralized and not treated sound enamel. selleckchem G1-G4 were subjected to pH cycling over a period of seven days. Analyses of the specimens' enamel surfaces morphology were performed by SEM and EDS. Data were statistically analyzed for multiple group comparison by one-way ANOVA/Tukey's test (p < 0.05). The results show that the Ca/P ratio of the G5 (2.00 ± 0.07) was statistically different (p < 0.05) from G1 (1.73 ± 0.05), G2 (1.76 ± 0.01), G3 (1.88 ± 0.06) and G6 (1.74 ± 0.04), while there were no differences (p > 0.05) between G1, G2 and G6 and between G4 (2.01 ± 0.06) and G5. We concluded that G1 and G2 showed better surface remineralization than G3 and G4, after 7 days of treatment.Since the successful separation of graphene from its bulk counterpart, two-dimensional (2D) layered materials have become the focus of research for their exceptional properties. The layered hexagonal boron nitride (h-BN), for instance, offers good lubricity, electrical insulation, corrosion resistance, and chemical stability. In recent years, the wide-band-gap layered h-BN has been recognized for its broad application prospects in neutron detection and quantum information processing. In addition, it has become very important in the field of 2D crystals and van der Waals heterostructures due to its versatility as a substrate, encapsulation layer, and a tunneling barrier layer for various device applications. However, due to the poor adhesion between h-BN and substrate and its high preparation temperature, it is very difficult to prepare large-area and denseh-BN films. Therefore, the controllable synthesis of h-BN films has been the focus of research in recent years. In this paper, the preparation methods and applications of h-BN films on III-V compounds are systematically summarized, and the prospects are discussed.At present, the research on rice hull ash and cement-based materials as cementitious materials continues to deepen. Low-cost rice hull ash replaces part of Portland cement, which plays a dual role in saving material costs and improving environmental benefits. In this study, alkali-activated rice husk ash (RHA) and ground granulated blast furnace slag (GGBS) were used to prepare cementitious material. The influence of RHA dosage on the strength, slump degree, and coagulation time of cementitious material was studied. On this basis, tailing was used as an aggregate based on the orthogonal design method and the bone-gel ratio, modulus, and alkali content were taken as variable factors, with strength and slump degree taken as the targets. A new cemented paste backfill (CPB) was prepared and mix ratio optimization was carried out. The strength formation mechanism of cementitious material and CPB was explored by combining scanning electron microscopy (SEM), energy dispersive spectrometry (EDS) and X-ray diffraction (XRD). The results of this study show that with the increase in RHA mixing, the unconfined compressive strength (UCS) of the gelling material purification slurry showed a tendency first to increase and then decrease. When the amount of RHA was about 10%, the internal structure became denser, more C-S-H gel was generated, and greater strength could be obtained. The specific surface area of RHA is high, and a small amount of RHA can fill the internal pores, making the internal structure of concrete more dense. The active silica content in RHA is relatively high. The addition of RHA can appropriately improve the strength of the material, which is of certain significance to our material research. Finally, the micro-analysis of RHA-GGBS clean slurry, the analysis of influencing factors of fluidity and strength, and the optimal mix proportion of alkali-activated RHA-GGBS-based backfill are put forward.The machined-surface integrity plays a critical role in corrosion resistance and fatigue properties of ultra-high-strength steels. This work develops a multiphysics model for predicting the microstructure changes and microhardness of machined AerMet100 steel. The variations of stress, strain and temperature of the machined workpiece are evaluated by constructing a finite-element model of the orthogonal cutting process. Based on the multiphysics fields, the analytical models of phase transformation and dislocation density evolution are built up. The white layer is modeled according to the phase-transformation mechanism and the effects of stress and plastic strain on real phase-transformation temperature are taken into consideration. The microhardness changes are predicted by a model that accounts for both dislocation density and phase-transformation evolution processes. Experimental tests are carried out for model validation. The predicted results of cutting force, white-layer thickness and microhardness are in good agreement with the measured data. Additionally, from the proposed model, the correlation between the machined-surface characteristics and processing parameters is established.In this study, we analyzed the quaternary Fe-C-Mn-B system to create new eutectic cast alloys for coating deposition and additive manufacturing. Experimental samples were fabricated via the wire arc manufacturing method with argon shielding using Kemppi Pro 5200 Evolution equipment. Annealing was performed in a vacuum electric furnace at 1273 K for 350 h. For phase analyses, Jeol Superprobe 733 equipment was used. Metallographic and differential thermal analyses were used to reveal the eutectic structure of the samples. Examinations of the quaternary Fe-C-Mn-B system demonstrated that several eutectic alloys existed in the system. Four isothermal pseudo-ternary sections of the Fe-C-Mn-B system were studied "Fe3B"-Fe3C-"Fe3Mn"; Fe2B-"Fe2C"-"Fe2Mn"; "Fe3B"-Fe3C-"Fe1.2Mn"; "Fe23B6"-"Fe23C6"-"Fe23Mn". Broad eutectic concentrations enabled us to overcome parameter fluctuations during additive manufacturing. In each isothermal section, two dissimilar phase regions were determined one with a ternary Fe-C-B composition and the other with a ternary Fe-C-Mn composition. Depending on the manganese content, two types of solid solutions could be formed (Fe, Mn)α or (Fe, Mn)γ.In this paper, supplementary cementitious materials are used as a substitute for cement to decrease carbon dioxide emissions. A by-product of the iron manufacturing industry, ground granulated blast-furnace slag (GGBS), known to improve some performance characteristics of concrete, is used as an effective cement replacement to manufacture mortar samples. Here, the influence of curing conditions on the durability of samples including various amounts of GGBS is investigated experimentally and numerically. Twelve high-strength Portland cement CEM I 52.5 N samples were prepared, in which 0%, 45%, 60%, and 80% of cement were substituted by GGBS. In addition, three curing conditions (standard, dry, and cold curing) were applied to the samples. Durability aspects were studied through porosity, permeability, and water absorption. Experimental results indicate that samples cured in standard conditions gave the best performance in comparison to other curing conditions. Furthermore, samples incorporating 45% of GGBS have superior durability properties.