Rodriguezrao1656

Additionally, the specific surface area of the formed BWOZ system was also improved in comparison with the flower-shaped Bi2WO6, and thus more active sites could be provided to contact with methylene blue molecules, thereby achieving better removal capacity. Moreover, trapping experiments and electron spin resonance results further illustrated that the coexistence of multiple free radicals realized efficient degradation of methylene blue. More importantly, the photocatalytic property of the 7%-BWOZ composite remained even after three cycles. Furthermore, a feasible photodegradation mechanism was also explored in depth.Covalently-bound organic silicate-aluminum hybrid coagulants (CBHyC) have been shown to efficiently remove low molecular weight organic contaminants from wastewater. However, the interaction dynamics and motivations during the coagulation of contaminant molecules by CBHyC are limited. In this study, a molecular dynamics (MD) simulation showed that CBHyC forms core-shell structure with the aliphatic carbon chains gather inside as a core and the hydrophilic quaternary ammonium-Si-Al complexes disperse outside as a shell. This wrapped structure allowed the coagulant to diffuse into solutions easily and capture target contaminants. The adsorption of anionic organic contaminants (e.g., diclofenac) onto the CBHyC aggregates was driven equally by van der Waals forces and electrostatic interactions. Cationic organic contaminants (e.g., tetracycline) were seldom bound to CBHyC because of substantial repulsive forces between cationic molecules and CBHyC. Neutrally-charged organic molecules were generally bound through hydrophobic interactions. For adenine and thymine deoxynucleotide, representatives of antibiotic resistance genes, van der Waals forces and electrostatic interaction became the dominant driving force with further movement for adenine and thymine, respectively. Driving forces between target contaminant and coagulant directly affect the size and stability of formed aggregate, following the coagulation efficiency of wastewater treatment. The findings of this study enrich the database of aggregation behavior between low molecular weight contaminants and CBHyC and contribute to further and efficient application of CBHyC in wastewater treatment.The degradation of ammonia is a key rate-limiting step during the supercritical water oxidation of nitrogen-containing organics. This paper studied the co-oxidation behavior between different ammonia-alcohol environments, including the influence of reaction parameters and the co-oxidation mechanism. The results showed that increasing temperature, oxidation coefficient, residence time, and alcohol concentration significantly promoted the degradation of NH3-N and TOC, while rising the ammonia concentration enhanced the NH3-N destruction but inhibited the TOC degradation. Alcohols were oxidized first in the co-oxidation system to produce more OH* and HO2* radicals. Ethanol generated the highest concentration of HO2* in the shortest time, leading to more significant ammonia removal than isopropanol and methanol; however, the produced intermediate products like aldehydes and ketones reacted with residual ammonia to generate a small amount of organics at lower temperatures, inhibiting the degradation of alcohols slightly, and combined catalyst or nitrate in the batch reactor or used continuous supercritical water oxidation or supercritical hydrothermal combustion system without controlling the exotherm of fuels could improve this.

As a group of environmental pollutants, polycyclic aromatic hydrocarbons (PAHs) may be neurotoxic，especially in high-exposure occupational populations. SAR405838 However, the effect of PAHs on mild cognitive impairment (MCI) is still unclear.

We aimed to investigate the relationship between PAH metabolites and MCI and to explore whether plasma p-tau231 can be used as a potential biomarker to reflect MCI in coke oven workers.

A total of 330 workers were recruited from a coke oven plant as the exposure group, and 234 workers were recruited from a water treatment plant as the control group. The concentrations of eleven PAH metabolites and plasma p-tau231 were determined by high-performance liquid chromatography-mass spectrometry (HPLC-MS/MS) and ELISA. Cognitive function was measured by the Montreal Cognitive Assessment (MoCA) questionnaire. A multivariate logistic regression model and multiple linear regression model were used to analyze the associations of urinary PAH metabolites with the detection rate of MCI, MoCA scores and plasma p-tau231. The dose-response relationships were evaluated using restricted cubic spline models.

We found 146 MCI-positive workers in coke oven plant (44.24%), and 69 MCI-positive workers in water treatment plant (29.49%). In addition, the urinary sum of PAH metabolites (Ʃ-OH PAHs) was significantly associated with MCI (OR, 1.371; 95% CI1.102-1.705). Each one-unit increase in ln-transformed Ʃ-OH PAHs was associated with a 0.429 decrease in the sum of MoCA, a 0.281 reduction in the visuospatial/executive function and a 9.416 increase in the level of plasma P-Tau231. We found a negative association between plasma P-Tau231 and visuospatial/executive function (β=-0.007, 95% CI -0.011, -0.003).

Our data indicated that urinary Ʃ-OH PAHs levels of workers were positively associated with MCI and the level of plasma P-Tau231.

Our data indicated that urinary Ʃ-OH PAHs levels of workers were positively associated with MCI and the level of plasma P-Tau231.Abandoned mines with untreated waste cause environmental pollution. The complex mixture of mining waste includes high metal content, anthropogenic chemicals and sterile rocks. Adverse effects of contaminated soils have been widely assessed by the use of plants. The aim of this study was to assess the chronic toxicity of a contaminated soil by waste from an abandoned gold mine on Lactuca sativa and its relationship with the bioavailability and bioaccumulation of Zn, Cu and Pb. Soil samples were taken from the site of mining waste stacking and a reference site in La Planta (Argentina). Contamination indices were calculated and acute and chronic exposures on L. sativa were carried out. Phytotoxicity indices, morphological and biochemical parameters, and concentrations of Zn, Cu and Pb in pseudo total and bioavailable soil fractions and in plant tissue were determined. Concentration- and time-dependent toxicity effects were observed, especially on plant width, fresh aerial biomass, leaf area and percentage of plants with completely necrotic aerial biomass. High levels of Zn (1453.3 ± 220.3 μg g-1) were found in plant tissue compared to Pb (277.2 ± 18.0 μg g-1) and Cu (255.3 ± 25.6 μg g-1). Toxicological endpoints correlated with metal uptake and mining waste concentration. In addition, bioaccumulation factors correlated with mobilisable and water soluble fractions. The concentration of Pb in aerial biomass surpassed the permissible concentrations in leaf vegetables, even at the reference site, indicating that lettuce crop consumption could be risky for the local population's health. This study demonstrated a strong relationship between metal bioavailability, toxicity endpoints and bioaccumulation, contributing with novel information to future ecotoxicological risk assessments and remediation plans.In modern agricultural practice, the land use pattern has been changing due to economic reasons and related policies, which significantly affects the basic physical and chemical properties of soils, thereby influencing the speciation and distribution of heavy metals (HMs) in soils. In this study, we selected three typical types of land use patterns (vegetable field, paddy field and forest field) in Shaoguan City, Guangdong Province, to analyze the content and distribution of HMs, screen the sensitive physicochemical properties, and predict the phytoavailability of HMs under different land use patterns with the multi-surface model (MSM). The forest field had relatively lower levels of labile and free HM ions than both paddy and vegetable fields, which may be attributed to the lower HM content in forest field. The modeling results revealed that organic matter (OM) is the primary carrier of HMs, accounting for 0.19%-97.92% of labile HMs. The sensitivity of soil physicochemical properties to free HM ions followed the order of pH > SOM > goethite > clay. Besides, the conversion of paddy field into vegetable or forest field increased the environmental risk of HMs. Our results may help better decision making in agricultural restructuring to reduce the risk of HM-contaminated soils, as well as give a demonstration for the application of the MSM in predicting the phytoavailability of HMs as a powerful technique.A heterotrophic sulfur autotrophic integrated fluidized bed reactor was established for simultaneous and efficient removal of ClO4- and NO3- from water. The optimum operating conditions forecasted through the response surface method (RSM) were the hydraulic retention time (HRT) of 0.50 h, the influent acetate (CH3COO-) concentration of 55 mg/L and the reflux ratio of 14, contributing to ClO4- and NO3- removal of 98.99% and 99.96%, respectively, without secondary pollution caused by residual carbon (NPOC less then 3.89 mg/L). Meanwhile, the effluent pH fluctuated in a range of 6.70-8.02 and sulfur-containing by-products (i.e., SO42- and S2-) could be controlled by adjusting operation conditions throughout the experimental stage. The increase of the influent CH3COO- concentration reduced the load borne by autotrophic reduction process and further reduced SO42- production. Shortening HRT, increasing the influent CH3COO- concentration and decreasing the reflux ratio could all reduce alkalinity consumption. Shortening HRT and decreasing the reflux ratio could shorten contact time between sulfur and water and thus inhibit S0 disproportionation. High-throughput sequencing result showed that Proteobacteria and Chlorobi were the dominant bacteria. Sulfurovum, Sulfuricurvum and Ignavibacterium were the major heterotrophic denitrifying bacteria (DB)/perchlorate reducing bacteria (PRB), Ferritrophicum and Geothrix were DB, and Chlorobaculum was S0 disproportionation bacteria.Thiram has been widely used in agriculture and may invades the food chain, posing a threat to human health. In this research, a label-free electrochemical cell-based biosensor was presented for in vitro toxicity assessment of thiram. HepG2 cells were cultured on poly-l-lysine@gold nano-flowers functionalized indium tin oxide coated glass electrode (PLL@AuNFs/ITO) to serve as biorecognition elements. AuNFs were electrodeposited on ITO to provide an enlarged specific surface area and benefited the output signal amplification. PLL was selected as an effective biocompatible coating material to facilitate cell adhesion and proliferation, thereby realizing one-step recording of electrochemical signals from thiram-treated cells. With the aid of the differential pulse voltammetry method, the fabricated biosensor was applied to assess the cytotoxicity of thiram. Results showed that the cytotoxicity measured by the fabricated biosensor exhibited a linear relationship related to thiram concentration ranging from 5 to 50 μM with a detection limit of 2.