Richardsrankin6196

The unexpected linear group 13 E[triple bond, length as m-dash]E triple bonds were herein uncovered with the D3h-symmetry E2M5+ (M = Li, Na, and K) clusters, where the linear M-E[triple bond, length as m-dash]E-M form is perfectly surrounded by M3 motifs. The increasing nonbonded electron density of the heavier main-group elements is the key issue for the trans-bent geometry, and yet it is strongly suppressed in E2M5+, creating two degenerate π bonds and one multi-center σ bond.We report a filamentous chaperone-based protein hydrogel capable of stabilizing enzymes against thermal inactivation. The hydrogel backbone consists of a thermostable chaperone protein, the gamma-prefoldin (γPFD) from Methanocaldococcus jannaschii, which self-assembles into a fibrous structure. Specific coiled-coil interactions engineered into the wildtype γPFD trigger the formation of a cross-linked network of protein filaments. The structure of the filamentous chaperone is preserved through the designed coiled-coil interactions. The resulting hydrogel enables entrapped enzymes to retain greater activity after exposure to high temperatures, presumably by virtue of the inherent chaperone activity of the γPFD.We analyze the emergence of wiggling temporal localized states in a passively mode-locked vertical external-cavity surface-emitting laser composed by a gain chip and a resonant saturable absorber mirror. We show that the wiggling instability stems from the interplay between the third-order dispersion induced by the micro-cavities and their frequency mismatch. The latter is identified as an experimentally crucial parameter defining the range of existence of stable emission. We reveal the homoclinic scenario underlying the wiggling phenomenon, and we show how it allows us to control the oscillation parameters.We report on an ytterbium-free, erbium-doped single-mode all-fiber laser reaching a record output power of 107 W at 1598 nm, with a slope efficiency of 38.6% according to the absorbed pump power at 981 nm. The erbium-doped gain fiber, co-doped with cerium, aluminum, and phosphorus, was fabricated in-house with adjusted doping concentrations to reduce erbium ions clustering, thereby increasing efficiency while keeping the numerical aperture low to ensure a single-mode laser operation. The addition of cerium co-dopant in the core glass of an erbium system is used for the first time, to the best of our knowledge, in order to adjust the fiber's numerical aperture without increasing the erbium concentration. Numerical modeling, validated by the experimental results, demonstrates that adding aluminum and phosphorus at high concentration mitigates erbium ions clustering, with an estimated erbium paired ions of only 5.0% in the reported gain fiber.In this Letter, we experimentally demonstrate liquid crystal-based moiré lenses with a wide and tunable focal length by direct-writing photoalignment. Our moiré lenses, which consist of two cascaded diffractive optical elements, have a large range of refractive power between $\pm 0.85\;\rm m^- 1$ at 532 nm and a mutual rotation between $\pm 90^\circ$ with high diffraction efficiency ($\gt\!75\%$). 3',3'-cGAMP order Based on the as-designed moiré lenses, we propose high-dynamic-resolution optical edge detection without any axial shift or substitution of components. The minimum edge width is 13.2 µm and can be adjusted within 100 µm by mutual rotation of this device, which has great potential to be used in adaptive and compact optical systems.We show that anisotropic planar anti-guiding waveguide structures with two radiation channels toward the surrounding cladding materials can support unidirectional guided resonances (UGRs), where radiation is canceled in one of the radiation channels and redirected into the other. Their formation is subtle as it requires breaking the so-called polar anisotropy-symmetry of the structures. Then, UGRs appear at specific wavelengths and light propagation directions, are robust, and are characterized by phase singularities in the channel in which radiation is canceled. The mechanism we describe allows for ready selection of the radiation direction, as well as tuning of the wavelength and the propagation angle at which UGRs occur.We propose a reliable scheme for one-step synthesizing of a quantum fan-out gate in a system of neutral atoms. By introducing the off-resonant driving fields with Gaussian temporal modulation, the dynamics of the system is strictly restricted to the ground-state subspace on the basis of unconventional Rydberg pumping, which exhibits more robustness than the constant driving method against the fluctuation of system parameters, such as operating time and environment noise. As a direct application of this quantum fan-out gate, we discuss in detail the preparation of multipartite Greenberger-Horne-Zeilinger (GHZ) state for neutral atoms. The result shows that a high fidelity better than 99% can be obtained within the state-of-the-art experiments.In this Letter, we report the significant enhancement of the photonic spin Hall effect (SHE) in a plasmonic metasurface with $\rm S_4$ symmetry. We find that an enhanced SHE of reflected light can occur in both horizontally and vertically polarized incident beams, and the maximum transverse displacement can approach half of the beam waist. Such a large displacement is caused by the non-resonant and near-zero pseudo-Brewster angles in the plasmonic metasurface. Owing to $\rm S_4$ symmetry, a unidirectional SHE is obtained in the metasurface, i.e., large and tiny transverse displacements are realized for a linearly polarized beam incident from the opposite side. This Letter provides a new, to the best of our knowledge, way to achieve an enhanced photonic SHE and offers more opportunities for designing spin-based nanophotonic devices.A hybrid optical fiber comprising metal electrodes, high performance polymers, and a highly nonlinear glass core is presented in this work as a novel, to the best of our knowledge, platform for mid-infrared nonlinear devices. The fiber allows for electrical tuning of the temperature by joule heating using a set of embedded tungsten wires. Unlike temperature tuning by an external heater, this results in a strong modulation, which introduces alternating signs of its dispersion. Enhanced spectral broadening through supercontinuum generation in the mid-infrared due to this modulation is investigated numerically.