Rasmussenpace5763

The prepared catalysts show good repeatability (a slightly decrease ca.3% after 5 cycles) and applicability, providing a reasonable design for water remediation.Spent resins generated from the nuclear industrial processes are still difficult to be treated and disposed. Fenton-like processes have great application potential in the treatment of spent resins, but the Fenton reaction mechanisms and resin degradation pathways remain challenging. In this study, nanoscale Fe0/Cu0 bimetallic catalysts were prepared and characterized for the Fenton-like degradation of the mixture of cationic and anionic resins. High catalytic property of Fe0/Cu0 bimetallic nanoparticles activated by H2O2 was evaluated, according to the effects of various nanoparticles, temperature, catalyst amount, H2O2 concentration and the mixing ratio of cationic and anionic resins. Combined the shape and color changes of mixed resins with the experimental and calculated characterization results, different degradation difficulty of cationic and anionic resins and their degradation mechanisms were studied. According to the density functional theory calculations of the optimized resin molecules with the Fe0/Cu0 catalyst, the mechanisms of Fenton-like reactions and the degradation of mixed resins through the synergistic effect of Fe and Cu species were proposed. The comprehensive Fenton-like reactions and degradation mechanisms provide new insights to advance the treatment of spent resins and organic polymers by Fenton-like processes.In this study, a single-stage ceramic membrane moving bed biofilm reactor (CMMBBR) was developed for simultaneous COD and nitrogen removal, while its effluent was further reclaimed to ultra-clean water by a coupled reverse osmosis (RO) unit. Results showed that approximately 97% of COD and 93% of total nitrogen (TN) removal were obtained in CMMBBR, with the effluent COD and TN concentrations being 8.15 mg/L and 2.31 mg/L, respectively. The excellent performance of CMMBBR was achieved at a constant permeate flux of 30 L/m2/h (LMH), with the average dTMP/dt of 0.05 bar/d due to the low suspended sludge concentration (i.e. 75 mg VSS/L) and the effective membrane scouring by fluidized biocarriers. The excellent permeate quality of CMMBBR could lead to a very low RO fouling rate of 0.029 bar/d, with the product water quality meeting typical NEWater standards in major ions concerned. In addition, the energy and cost analyses further indicated that the proposed CMMBBR-RO process could reduce 43.8% of energy consumption and 23.5% of operating cost compared to the current NEWater production process. It is expected that the integrated CMMBBR-RO process could provide a promising alternative for municipal wastewater reclamation to high-grade product water towards minimized sludge production and energy-efficient operation.The widespread use of silver nanoparticles (AgNPs) in consumer products that release Ag throughout their life cycle has raised potential environmental concerns. AgNPs primarily accumulate in soil through the spreading of sewage sludge (SS). In this study, the effects of direct exposure to AgNPs or indirect exposure via SS contaminated with AgNPs on the earthworm Eisenia fetida and soil microbial communities were compared, through 3 scenarios offering increasing exposure concentrations. The effects of Ag speciation were analyzed by spiking SS with AgNPs or AgNO3 before application to soil. SS treatment strongly impacted Ag speciation due to the formation of Ag2S species that remained sulfided after mixing in the soil. The life traits and expression of lysenin, superoxide dismutase, cd-metallothionein genes in earthworms were not impacted by Ag after 5 weeks of exposure, but direct exposure to Ag without SS led to bioaccumulation of Ag, suggesting transfer in the food chain. Ag exposure led to a decrease in potential carbon respiration only when directly added to the soil. The addition of SS had a greater effect on soil microbial diversity than the form of Ag, and the formation of Ag sulfides in SS reduced the impact of AgNPs on E. fetida and soil microorganisms compared with direct addition.Energy recovery from sewage sludge was carried out by using microwave and conventional torrefaction. The microwave torrefaction was carried out by using a laboratory-scale microwave oven that provides single-mode microwave irradiation at 2.45 GHz, and the amount of sewage sludge for each experiment was approximately 20 g. The efficiency of microwave heating can be substantially promoted at higher power level, resulting in higher heating rate and maximum temperature. According to higher energy yield and heating value of torrefied sewage sludge, the optimum power level for bioenergy produced by microwave torrefaction of sewage sludge should be 200 W. Because of lower mass yield and temperature required to obtain the same yield, microwave heating can be more effective than conventional heating for sewage sludge torrefaction. The elemental composition of torrefied sewage sludge at 400 W was similar to that of anthracite, and its low hydrogen and oxygen contents could prevent excessive formation of smoke. Two correlations were obtained to predict the HHV of SS based on proximate and elemental compositions. With the recovery of liquid and gas products as bioenergy, the energy return on investment for microwave torrefaction of sewage sludge can be up to 16.4, much higher than the minimum value required for a sustainable society. Because of lower activation energy but higher pre-exponential factor, microwave heating can be approximately five times faster than conventional heating.A magnetic Ag3PO4/rGO/CoFe2O4 ternary catalyst was firstly prepared and used for removing levofloxacin (LVF) from different water matrices via simultaneous adsorption and photocatalysis. Compared with Ag3PO4 and Ag3PO4/CoFe2O4, Ag3PO4/rGO/CoFe2O4 shows a superior adsorption-photocatalysis performance for LVF elimination since rGO component not only improves the adsorption ability but also enhances the charge separation efficiency of the catalyst. About 90.7% of LVF in distilled water (10 mg/L) was removed by the ternary catalyst after adsorption for 0.5 h and photocatalysis for 1.0 h, and the removal of LVF performed well in the pH range of 3.51-9.47. Singlet oxygen (1O2) was the major reactive oxygen species for LVF degradation in Ag3PO4/rGO/CoFe2O4 system under visible light, as confirmed by the quenching experiments and ESR study. Based on the detected intermediates in the photocatalytic process, the possible LVF degradation pathways were well-established. As-synthesized Ag3PO4/rGO/CoFe2O4 can also efficiently remove LVF from the different real water matrices (river water, lake water and secondary effluent) via simultaneous adsorption and photocatalysis. Moreover, magnetic Ag3PO4/rGO/CoFe2O4 can be easily recovered and effectively reused for the removal of LVF in actual water bodies.This work aimed to prepare surfactant modified-PBAT (poly(butylene adipate-co-terephthalate)) sheets with superior properties to increase the PBAT applicability and be a possible solution for plastic disposal environmental problems. Three different surfactant contents (0, 1, 5, and 10 wt%) were investigated, and their effects on PBAT chemical structure, mechanical and morphological properties, wettability, and water absorption were investigated. Modified-PBAT samples showed high hydrogen bond coefficients (0.57) than the pristine PBAT (0.54), indicating an excellent electrostatic interaction between both components and the formation of a rigid hydrogen-bonded network, as confirmed by mechanical tests, where the elastic modulus values for PBAT and PBAT+10% surfactant were 44 and 60 MPa. SEM images and roughness measurements showed changes in PBAT morphology after surfactant addition, improving the roughness and wettability by the voids and polar groups presence, altering the water absorption (WA) behavior. The higher water affinity resulted in high water absorption for PBAT-10%S (17%) compared to the pristine PBAT (2%), which improves hydrolysis tendency, which is the initial step to biodegradation. Biodegradation results indicated that the roughness and WA behavior influenced the biodegradation rate, facilitating hydrolysis and microbial attack, and accelerating modified samples weight loss. Our results suggested developing a material with superior mechanical properties, mainly for PBAT-10%S, that can be applied in several applications, such as packaging and furniture. After discharge, it is not an environmental problem, being a biodegradable material with a green character.Ivermectin is the most common antiparasitic drug used in livestock in many regions of the world. Its residues are excreted in dung, threatening non-target fauna such as dung beetles, fundamental for cleaning dung in pastures. However, it is unclear which are the physiological mechanisms used by dung beetles to cope with ivermectin. Here we evaluated experimentally the physiological responses of the dung beetle Euoniticellus intermedius to ivermectin-induced stress. We measured metabolic rates, heat shock protein 70 (Hsp70) expression, antioxidant capacity, and oxidative damage in lipids in both males and females exposed to a sublethal dose. Compared to control beetles, ivermectin-treated males and females had increased metabolic rates. Selleckchem Honokiol Moreover, ivermectin-treated females increased their expression of Hsp70 whereas males increased their antioxidant capacity. No changes in the levels of oxidative damage to lipids were detected for either sex, suggesting a process of hormesis, such that exposure to a moderate concentration of ivermectin could stimulate the action of a protective mechanism against oxidative stress, that differs between sexes. However, it does not exclude the possibility that damage to other biomolecules might have occurred. Sexual differences in physiological responses can be interpreted as the result of hormonal differences or life-history trade-offs that favor different mechanisms in females and males. Hsps and antioxidants are involved in the physiological response of beetles to ivermectin and may be key in providing resistance to this contaminant in target and non-target species, including dung beetles.In this study, a facile and effective route to prepare hybrid photocatalysts (paper-TiO2, paper-TiO2-AgBr and paper-AgBr-TiO2) has been reported. The preparation procedure consisted of the direct adsorption of the previously synthesized titania nanoparticles (TiO2 sol) to generate the TiO2 nanosphere and the immersion process in an aqueous suspension of AgBr to form the AgBr nanoclusters on paper fibers. The synthesis technology is economic, efficient, environmentally friendly and easy to implement even at industrial scale. A cellulose-based structure with well dispersed TiO2 particles of around 1 μm and a pseudo-liquid coating of Ag+ and AgBr species was obtained. All the prepared photocatalysts demonstrated effective photocatalytic performance in gaseous phase ethanol degradation with simulated sunlight illumination, through the direct mineralization to CO2 and the parallel reaction via acetaldehyde degradation. A relevant improvement in the photocatalytic activity was noticed when TiO2 was associated with AgBr nanocrystals, with a higher effect observed when AgBr was loaded onto the paper surface prior to TiO2.