Pruitthardin9744

Recently, multivalued logic (MVL) circuits have attracted tremendous interest due to their ability to process more data by increasing the number of logic states rather than the integration density. Here, we fabricate logic circuits based on molybdenum telluride (MoTe2)/black phosphorus (BP) van der Waals heterojunctions with different structural phases of MoTe2. Owing to the different electrical properties of the 2H and mixed 2H +1T' phases of MoTe2, tunable logic devices have been realized. A logic circuit based on a BP field-effect transistor (FET) and a BP/MoTe2 (2H + 1T') heterojunction FET displays the characteristics of binary logic. However, a drain voltage-controlled transition from binary to ternary logic has been observed in BP FET- and BP/ MoTe2 (2H) heterojunction FET-based logic circuits. https://www.selleckchem.com/products/MK-1775.html Also, a change from binary to ternary characteristics has been observed in BP/MoTe2 (2H)-based inverters at low temperature below 240 K. We believe that this work will stimulate the assessment of the structural phase transition in metal dichalcogenides toward advanced logic circuits and offer a pathway to substantialize the circuit standards for future MVL systems.Rechargeable aqueous zinc-ion batteries (ZIBs) are receiving increased attention because of their high safety and low cost. However, their practical application is plagued by their low energy density as a result of low output voltage and a narrow voltage window of aqueous electrolytes. Here, we explored a ZIB with a wider potential window using bication (1 M Al(CF3SO3)3/1 M Zn(CF3SO3)2) as the electrolyte and α-MnO2 as the cathode, obtaining a discharge voltage of 1.7 V, ∼0.3 V higher than the value reported earlier. The resultant cell delivers a record high energy density of 448 W h kg-1 (based on MnO2 mass) and retains 100% capacity over 1000 cycles. The ion-storage mechanism and the role of Al3+ in enlarging the output voltage were elucidated. This research indicates the important role of using bications in improving the electrochemical performance of aqueous ZIBs, opening a new way to increase the energy density of aqueous energy storage devices.Herein, the novel application of FeS2/C nanocomposite as a highly active, stable, and recyclable catalyst for heterogeneous electro-Fenton (EF) treatment of organic water pollutants is discussed. The simultaneous carbonization and sulfidation of an iron-based metal-organic framework (MOF) yielded well-dispersed pyrite FeS2 nanoparticles of ∼100 nm diameter linked to porous carbon. XPS analysis revealed the presence of doping N atoms. EF treatment with an IrO2/air-diffusion cell ensured the complete removal of the antidepressant fluoxetine spiked into urban wastewater at near-neutral pH after 60 min at 50 mA with 0.4 g L-1 catalyst as optimum dose. The clear enhancement of catalytic activity and stability of the material as compared to natural pyrite was evidenced, as deduced from its characterization before and after use. The final solutions contained less then 1.5 mg L-1 dissolved iron and became progressively acidified. Fluorescence excitation-emission spectroscopy with parallel factor analysis demonstrated the large mineralization of all wastewater components at 6 h, which was accompanied by a substantial decrease of toxicity. A mechanism with •OH as the dominant oxidant was proposed FeS2 core-shell nanoparticles served as Fe2+ shuttles for homogeneous Fenton's reaction and provided active sites for the heterogeneous Fenton process, whereas nanoporous carbon allowed minimizing the mass transport limitations.We develop a method to prepare hollow FeP/Fe3O4 hybrid nanoparticles supported on carbon nanotubes (CNTs), which could be used as highly active and efficient electrocatalysts. The Fe@Fe3O4/CNT hybrids were first synthesized by annealing the CNTs adsorbed with Fe(NO3)3, followed by controlled phosphorization treatment. They exhibit an outstanding catalytic activity for oxygen evolution reaction (OER) with a low overpotential of 229 mV at a current density of 10 mA cm-2, a high turnover frequency value of 0.35 s-1 at an overpotential of 300 mV, and an ultralow Tafel slope of 27.6 mV dec-1, which is much better than that of FeP/Fe3O4, FeP/CNTs, Fe3O4/CNTs, and the commercial RuO2 electrocatalyst. More importantly, the Tafel slope is much lower than most non-noble metal-based OER electrocatalysts reported in the previous literature studies as far as we know. The excellent OER performance benefits from the electron transfer from Fe3O4 to FeP confirmed by X-ray photoelectron spectroscopy, together with good conductivity of CNTs. This hybrid structure supported on conductive CNTs may offer an efficient method to design earth-abundant and low-cost electrocatalysts for OER in practical applications.Graphene oxide (GO) nanosheets are promising noble-metal-free catalysts. However, the catalytic activity and selectivity of GO are still very low. Herein, GO is first functionalized via noncovalent interactions by an aspartic acid modified anhydride having COOH groups to form A-GO. A-GO is more conductive and hydrophilic than GO and P-GO synthesized via functionalizing GO by a COOH-free anhydride. Then, we load CdS nanoparticles, which are responsible for absorbing light to produce charge carriers, on A-GO to fabricate a CdS/A-GO photocatalyst without noble metals for the photoreduction of CO2 by H2O. CdS/A-GO exhibits a higher photoreduction efficiency than that of CdS/GO and CdS/P-GO. The main carbon-based photoreduction product of CdS/A-GO is CH3OH, whereas that of CdS/GO and CdS/P-GO is CO. The more conductive and hydrophilic A-GO triggers a more efficient electron transfer, CO2 adsorption, and production of hydrogen atoms from H2O dissociation, thus leading to the higher photoreduction efficiency and product change on CdS/A-GO. Besides, the COOH groups of the aspartic acid modified anhydride supply their hydrogen atoms to promote the conversion from CO2 to CH3OH on CdS/A-GO. Therefore, noncovalently functionalizing GO with different active species can efficiently improve the catalytic performance of GO. This opens a new way to design and construct noble-metal-free catalysts with enhanced activity and selectivity.A systematic review of the current literature on retreatment with omalizumab of patients with relapsing chronic spontaneous urticaria was performed. Published evidence shows that retreatment is safe and clinically effective, and that time to complete clinical response reduces as the number of retreatments increases.Severe uncontrolled asthma in children is a complex and heterogeneous disease and is considered a challenge for the pediatricians. Although nearly 5% of children with asthma present with a severe uncontrolled disease, these patients and their caregivers face a significant burden, including troublesome persistent symptoms, life-threatening acute attacks, medication side effects, impaired school performance, neuropsychological problems, and lower quality of life (QoL). link2 Moreover, these patients also account for substantially higher healthcare resource use and costs than average patients with asthma. Thus, it is essential to accurately define and diagnose severe asthma in children as they potentially need close monitoring and additional treatment with advanced therapies. This review aims to update knowledge on diagnosis and management of severe uncontrolled asthma in childhood. We describe a practical approach to differentiate children with difficult-to-treat asthma from those with true severe therapy-resistant asthma. Moreover, the recent advances in the understanding of the pathogenetic mechanisms and inflammatory mediators involved in asthma have paved the way for the development of a precision medicine approach. link3 In this context, we analyze approved personalized therapies for severe uncontrolled asthma, focusing on the pediatric indications.PURPOSE There was limited study available on successful intervention for central-line-associated bloodstream infection (CLABSI) done at nonintensive care unit (ICU) and resources-limited setting. The objective of this study was to design, implement and evaluate a strategy to reduce CLABSI rate in non-ICU settings at general medical wards of Hospital Tuanku Ja'afar Seremban. DESIGN/METHODOLOGY/APPROACH Preinterventional study was conducted in one-month period of January 2019, followed by intervention period from February to March 2019. Postintervention study was conducted from April to July 2019. The CLABSI rates were compared between pre and postintervention periods. A multifaceted intervention bundle was implemented, which comprised (1) educational program for healthcare workers, (2) weekly audit and feedback and (3) implementation of central line bundle of care. FINDINGS There was a significant overall reduction of CLABSI rate between preintervention and postintervention period [incidence rate ratio (IRR) of 0.06 (95 percent CI, 0.01-0.33; P = 0.001)]. PRACTICAL IMPLICATIONS CLABSI rates were reduced by a multifaceted intervention bundle, even in non-ICU and resource-limited setting. This includes a preinterventional study to identify the risk factors followed by a local adaption of the recommended care bundles. This study recommends resources-limited hospitals to design a strategy that is suitable for their own local setting to reduce CLABSI. ORIGINALITY/VALUE This study demonstrated the feasibility of a multifaceted intervention bundle that was locally adapted with an evidence-based approach to reduce CLABSI rate in non-ICU and resource-limited setting. © Emerald Publishing Limited.Chanhua (Isaria cicadae) was known as a rare entomogenous fungus with various pharmacological activities since a long time ago in China, which has attracted considerable attention. However, less knowledge was maintained about its products as potential bioflocculants. In this work, a bioflocculant IC-1 produced by Isaria cicadae GZU6722, consisted mainly of protein (4%) and polysaccharides including neutral sugars (52.75%) and galacturonic acid (38.14%), was characterized. It presented high efficiency in flocculating coal washing wastewater, and the flocculating efficiency could reach 91.81% by addition of 24 mg l-1 IC-1 compared to the addition of 60 mg l-1 APAM (anionic polyacrylamide) under the same treatment conditions. The highest flocculating efficiency reached 95.8% in the presence of 2% CaCl2. Compared to APAM, the flocculating efficiency of coal washing wastewater by IC-1 varied little with the increasing dosage. Although the flocs in the APAM-assisted sediment were larger than that in the IC-1-assisted sediment after 1 min of sedimentation, few flocs were still found in the supernatant of both treated samples after 10 min of sedimentation. More interestingly, it was observed under the microscope that the flocs in the IC-1-assisted sediments were more compact than that in the APAM-assisted sediments, suggesting that polymer bridging might take place after IC-1 was added into the coal washing wastewater. The evaluation of costs indicated that the use of IC-1 to treat the coal-washing wastewater may be an economical and feasible way to avoid the extra cost for post-treatment of conventional flocculants.