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The proposed procedure estimates the interface bond strength based on the geostatistical methods applied to the numerical surface model and can be used in practical and theoretical applications.Completed area coverage planning (CACP) plays an essential role in various fields of robotics, such as area exploration, search, rescue, security, cleaning, and maintenance. Tiling robots with the ability to change their shape is a feasible solution to enhance the ability to cover predefined map areas with flexible sizes and to access the narrow space constraints. By dividing the map into sub-areas with the same size as the changeable robot shapes, the robot can plan the optimal movement to predetermined locations, transform its morphologies to cover the specific area, and ensure that the map is completely covered. The optimal navigation planning problem, including the least changing shape, shortest travel distance, and the lowest travel time while ensuring complete coverage of the map area, are solved in this paper. To this end, we propose the CACP framework for a tiling robot called hTrihex with three honeycomb shape modules. The robot can shift its shape into three different morphologies ensuring coverage of the map with a predetermined size. However, the ability to change shape also raises the complexity issues of the moving mechanisms. Therefore, the process of optimizing trajectories of the complete coverage is modeled according to the Traveling Salesman Problem (TSP) problem and solved by evolutionary approaches Genetic Algorithm (GA) and Ant Colony Optimization (ACO). Hence, the costweight to clear a pair of waypoints in the TSP is defined as the required energy shift the robot between the two locations. This energy corresponds to the three operating processes of the hTrihex robot transformation, translation, and orientation correction. The CACP framework is verified both in the simulation environment and in the real environment. From the experimental results, proposed CACP capable of generating the Pareto-optimal outcome that navigates the robot from the goal to destination in various workspaces, and the algorithm could be adopted to other tiling robot platforms with multiple configurations.In addition to their high nutritional value, some chicken egg proteins and derivatives such as protein hydrolysates, peptides and amino acids show antioxidant properties which make them prominent candidates for the development of functional foods, drawing attention to both the food and biopharmaceutical industries. This review summarizes current knowledge on antioxidant activity of chicken egg proteins and their derived peptides. Some egg proteins such as ovalbumin, ovotransferrin and lysozyme from egg white or phosvitin from yolk have shown antioxidant properties, although derived peptides have higher bioactive potential. selleck compound The main process for obtaining egg bioactive peptides is enzymatic hydrolysis of its proteins using enzymes and/or processing technologies such as heating, sonication or high-intensity-pulsed electric field. Different in vitro assays such as determination of reducing power, DPPH and ABTS radical-scavenging activity tests or oxygen radical absorbance capacity assay have been used to evaluate the diverse antioxidant mechanisms of proteins and peptides. Similarly, different cell lines and animal models including zebrafish, mice and rats have also been used. In summary, this review collects all the knowledge described so far regarding egg proteins and derived peptides with antioxidant functions.Functionalized graphene derivatives including graphene oxide (GO), reduced graphene oxide (rGO), and heteroatom (nitrogen/sulphur (N/S) or boron (B))-doped graphene were used to synthesize composites with TiO2 (T). The photocatalytic performance of composites was assessed for the degradation of Orange G dye (OG) under simulated solar light. All the prepared graphene derivatives-TiO2 composites showed better photocatalytic performance than bare TiO2. A higher photocatalytic activity was found for the composites containing GO and N/S co-doped rGO (kapp = 109.2 × 10-3 and 48.4 × 10-3 min-1, for GO-T and rGONS-T, respectively). The influence of both initial solution pH and the reactive species involved in the OG degradation pathway were studied. The photocatalytic activity of the samples decreased with the increase of the initial pH (from 3.0 to 10.0) due to the occurrence of electrostatic repulsive forces between the photocatalysts surface and the molecules of OG, both negatively charged. The use of selective scavengers showed that although the photogenerated holes dominate the degradation mechanism, radicals and singlet oxygen also participate in the OG degradation pathway. In addition, reutilization experiments indicated that the samples were stable under the reaction conditions used.The purpose of this study was to apply the Kano model and revised importance-performance analysis (RIPA) to explore the teaching quality of physical education programs at Taiwanese universities. Random sampling was used to select universities from the north, south, central, and east areas of Taiwan. The questionnaire developed by the researcher included 20 items within four subscales. A total of 970 students participated in this study. A combination of the Kano model and RIPA was used for analysis. The results indicate that the item "physical education teachers have cordial attitudes toward instructions" fell into the "keep up the good work" designation of RIPA and the fourth quadrant of the Kano model. A patient and cordial attitude towards students can, therefore, be considered an important quality factor for physical education programs. Teacher-student relationships should, therefore, form a priority for physical education teachers looking to increase student satisfaction and optimize their programs.Thymus zygis subsp. zygis is an endemic Portuguese plant belonging to the Thymus zygis species. Although T. zygis is commonly used as a condiment and as a medicinal herb, a detailed description of the polyphenol composition of hydroethanolic (HE) and aqueous decoction (AD) extracts is not available. In this work, we describe for the first time a detailed phenolic composition of Thymus zygis subsp. zygis HE and AD extracts, together with their antioxidant, anti-proliferative and anti-inflammatory activities. Unlike other Thymus species, T. zygis subsp. zygis extracts contain higher amounts of luteolin-(?)-O-hexoside. However, the major phenolic compound is rosmarinic acid, and high amounts of salvianolic acids K and I were also detected. T. zygis subsp. zygis extracts exhibited significant scavenging activity of ABTS+, hydroxyl (•OH), and nitric oxide (NO) radicals. Regarding the anti-proliferative/cytotoxic effect, tested against Caco-2 and HepG2 cells, the AD extract only slightly reduced cell viability at higher concentrations (IC50 > 600 µg/mL, 48 h exposure), denoting very low toxicity, while the HE extract showed a high anti-proliferative effect, especially at 48 h exposure (IC50 of 85.