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For most species, models including heterospecifics explained occurrence frequency better than landscape features alone. Dominant predator (wolf) occurrence was best explained by prey, while prey species were explained by apparent competitors and subdominant predators. Evidence for interactions between landscape features and heterospecifics was strong for coyotes and wolves but variable for other species. Boreal mammals' spatial distribution is a function of heterospecific co-occurrence as well as landscape features, with synergistic effects observed for most species. Understanding species' responses to anthropogenic landscape change thus requires a multi-taxa approach that incorporates interspecific relationships, enabling better inference into underlying processes from observed patterns.The research on the mechanism of combined air pollution in the Yangtze-Huaihe region, which is characterized by unique meteorological and geographical conditions and pollution emission characteristics, is still insufficient. We performed an experiment on key pollutants and an ozone formation study in Hefei, which is a pivotal city in the Yangtze-Huaihe region, from September 1 to 20, 2020. The aerosols retrieved via two-dimensional Multi-axis Differential Optical Absorption Spectroscopy (2D-MAX-DOAS) with a Boltzmann-shaped a priori profile had the best agreement with the results of Light Detection and Ranging (LIDAR) and sun-photometer measurements among the three typical a priori profiles (Gaussian, Boltzmann, and exponential shapes). The correlation coefficients of the near-surface gas concentrations retrieved using both 2D-MAX-DOAS and in situ measurements were 0.86 (NO2) and 0.61 (HCHO). The high NO2 and HCHO concentrations were observed at azimuths of 180° and 315° at heights of 0.8-1.5 km, and they may have been emitted by aircrafts. Importantly, the ratio of HCHO to NO2 during a typical pollution episode revealed that the factors controlling the O3 formation changed with altitude VOCs (surface) to NOx (0.4 km) to transition (1.0 km) to VOCs (1.6 km). Moreover, the effect of VOCs on the O3 generation was stronger than that of NOx, especially in the downtown area of Hefei. When the ratio of HCHO to NO2 was 3.55-7.46, the ozone concentration in Hefei could be controlled well, especially at the optimal value of 5.50.This study compares select dust sampling apparatuses and monitoring methods by investigating fugitive tailings dust transport and deposition at an abandoned Zn-Pb-Cu mine located in eastern, Canada. The sampling apparatuses and monitoring methods are compared in terms of capturing seasonal trends and spatial extent, as well as the ability to evaluate impacts to aquatic ecosystems. Methods evaluated include satellite imagery, lichen tissue analysis, passive dry deposition collectors (Pas-DDs) with two different configurations, dust deposition gauges (DDGs) and a high volume total suspended particulate (Hi-Vol TSP) sampler. All methods utilized demonstrated benefits and challenges in relation to seasonal sampling and determining spatial extent of dust deposition. Results indicate that the polyurethane foam disk configuration of the Pas-DD sampler efficiently accumulates dust in comparison to the glass fiber filter configuration and DDGs which both likely underestimate dust deposition. Lichen and satellite imagery were shown to be effective tools for identifying areas of interest and extent of contamination. At the study site, it was observed that dust deposition was highest in the winter months and lowest in the summer months, likely due to increased erosion in winter weather conditions (higher wind speeds and/or freeze drying effect).High salinity organic wastewater (HSOW) contains both organic pollutants and high concentration of inorganic salts. If it is discharged into the environment without proper treatment, it will cause adverse consequences such as dehydration and death of aquatic organisms, and soil salinization. Bioelectrochemical systems (BESs) have been applied in various wastewater treatment processes. To assess the feasibility of using BESs to treat HSOW, the effect of applying potential on anaerobic digestion of HSOW was explored in an up-flow anaerobic sludge blanket (UASB) reactor poised at -0.6 V (vs. Ag/AgCl). When organic loading rate (OLR) was 2.16-2.88 kg chemical oxygen demand/(m3d) (kg COD/(m3d)), the applied potential had no significant effect on the UASB performance. After OLR was increased to 4.32 kg COD/(m3d), the applied potential decreased COD removal efficiency and methane production and resulted in VFAs accumulation. Epicatechin supplier Mesotoga was enriched on the electrode when potential was applied, causing decrease in relative abundances of acetoclastic methanogens. The abundance of Methanothrix on the electrode in the reactor with applied potential was much lower than in the control reactor (10% vs 28.9%), which might lead to decrease in performance of the reactor due to the depressed direct interspecies electron transfer (DIET) and less formation of granular sludge. These results suggest that applying external potentials has negative effect on the anaerobic treatment of HSOW, and should be taken into consideration in real HSOW treatment projects.Pollution from personal protective equipment (PPE), particularly face masks, has surfaced in the marine and terrestrial environments globally since the COVID-19 outbreak due to improper disposal practices and inadequate waste management, raising widespread alarm and attention. Our understanding of the prevalence and distribution of PPE in highly populated metropolitan areas is still emerging, and studies focusing specifically on developing countries in Latin America remain sparse. This study attempted to "kill two birds with one stone" by (1) addressing this knowledge gap by analyzing the degree of improper dispensing of PPE in Mexico City (Mexico) and (2) investigating the impact of massive public congregations on PPE contamination during the yearly pilgrimage to the Villa de Guadalupe on December 12th. Our survey findings revealed 731 PPE items within a 6-kilometer radius between December 5 and December 12, 2021, with daily densities ranging from 4.1 × 10-3-13.9 × 10-3 PPE items m-2. Face masks were the most disposed type of PPE (94%), with gloves and face shields accounting for just 6% of the total. The PPE disposal more than doubled as the pilgrim day approached, with an estimated disposal rate ranging from 151.52 to 506.06 items day-1, substantiating the surge in the disposal of used PPE to large public congregations that filled the surroundings during the pilgrimage. The observed average PPE density of 7.8 × 10-3 items m-2 was higher than in the metropolitan environments of Canada, Ghana, and Turkey. To our knowledge, this first study describes information showing the need to pay attention to the major impact of public events and mobility on COVID-19 PPE pollution, as well as emphasizes the necessity for adequate management facilities in improving PPE disposal.In this paper, we present the total column water vapour (TCWV) retrieval for the TROPOspheric Monitoring Instrument (TROPOMI) observations in the visible blue spectral band. The TROPOMI TCWV algorithm is being optimized and validated in the framework of the Sentinel 5 Precursor Product Algorithm Laboratory (S5P-PAL) project from the European Space Agency (ESA). The retrieval was first developed to retrieve TCWV from the Global Ozone Monitoring Experiment 2 (GOME-2). We have optimized the settings of the retrieval to adapt it for TROPOMI observations. The TROPOMI TCWV algorithm follows the typical two step approach, using spectral fit retrieval of slant columns, and conversion of the slant columns to vertical columns using air mass factors (AMFs). An iterative optimization algorithm is developed to dynamically find the optimal a priori water vapour profile for the AMF calculation. Further optimizations on the spectral retrieval, air mass factor calculations as well as a new surface albedo retrieval approach arl discrepancies found between TROPOMI and reference data sets are related to the differences in measurement technique, measurement time, surface albedo issue, as well as cloud and aerosol contamination. This study demonstrates that the algorithm can provide stable and consistent results on a global scale and can be applied to generate operational TCWV products from TROPOMI and the forthcoming Copernicus missions Sentinel-4 and Sentinel-5. We have also demonstrated the capability of retrieving fine scale water vapour structures in a case study over the Amazon. This indicates that the TROPOMI data set is also useful for local and regional climate studies.Mercury concentrations ([Hg]) in fish reflect complex biogeochemical and ecological interactions that occur at a range of spatial and biological scales. Elucidating these interactions is crucial to understanding and predicting fish [Hg], particularly at northern latitudes, where environmental perturbations are having profound effects on land-water-animal interactions, and where fish are a critical subsistence food source. Using data from eleven subarctic lakes that span an area of ~60,000 km2 in the Dehcho Region of Northwest Territories (Canada), we investigated how trophic ecology and growth rates of fish, lake water chemistry, and catchment characteristics interact to affect [Hg] in Northern Pike (Esox lucius), a predatory fish of widespread subsistence and commercial importance. Results from linear regression and piecewise structural equation models showed that 83% of among-lake variability in Northern Pike [Hg] was explained by fish growth rates (negative) and concentrations of methyl Hg ([MeHg]) in benthic invertebrates (positive). These variables were in turn influenced by concentrations of dissolved organic carbon, MeHg (water), and total Hg (sediment) in lakes, which were ultimately driven by catchment characteristics. Lakes in relatively larger catchments and with more temperate/subpolar needleleaf and mixed forests had higher [Hg] in Northern Pike. Our results provide a plausible mechanistic understanding of how interacting processes at scales ranging from whole catchments to individual organisms influence fish [Hg], and give insight into factors that could be considered for prioritizing lakes for monitoring in subarctic regions.Analyzing the carbon footprint of crop production and proposing low-carbon emission reduction production strategies can help China develop sustainable agriculture under the goal of 'carbon peak and carbon neutrality'. Cotton is an economically important crop in China, but few reports have systematically quantified the carbon footprint of China's cotton production and analyzed its spatiotemporal changes and driving factors. This study used a life cycle approach to analyze the spatiotemporal changes and identify the main components and driving factors of the carbon footprint of cotton production in China between 2004 and 2018 based on statistical data. The results showed that the carbon footprint per unit area of cotton in Northwest China, the Yellow River Basin and the Yangtze River Basin reached 6220.13 kg CO2eq·ha-1, 3528.14 kg CO2eq·ha-1 and 2958.56 kg CO2eq·ha-1, respectively. From 2004 to 2018, the CFa in the Yellow River Basin and Northwest China increased annually, with average increases of 59.87 kg CO2eq·ha-1 and 260.

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