Newtonestrada1955

High hydraulic pressure in air-cathode microbial fuel cells (MFCs) can lead to severe cathodic water leakage and power reduction, thereby hindering the practical applications of MFCs. In this study, an alternative air cathode without a diffusion layer was developed using a cross-linked hydrogel, oxidized konjac glucomannan/2-hydroxypropytrimethyl ammonium chloride chitosan (OKH), for ion bridging. The cathode was placed horizontally to avoid hydraulic pressure on its surface. Ion transportation was sustained with a minimal OKH hydrogel loading of 10 mg/cm2. A maximum power density of 1.0 ± 0.04 W/m2 was achieved, which was only slightly lower than the 1.28 ± 0.02 W/m2 of common air cathodes. Moreover, the cost of the OKH hydrogel is only $0.12/m2, which can reduce ~85% of the cathode cost without using the advanced polyvinylidene fluoride diffusion layer. Therefore, the development of this new diffusion-layer-free air cathode using conductive ionic hydrogel provides a low-cost strategy for stable MFC operation, thereby demonstrating great potential for practical applications of MFC technology.The trends of enzyme activities and litter chemistry after abandonment of arable soil and succession of natural vegetation were studied in a deciduous forest zone (Moscow region, Russia). The Luvic Phaeozem chronosequence included an arable field, 3 fields with increasing abandonment periods (7, 11, 35 years), and the soil under natural forest as a reference site (never used for cropland). The activities of four hydrolytic enzymes (β-glucosidase, cellobiohydrolase, β-galactosidase, chitinase) in the topsoil (0-5 cm) were compared with chemical functional groups of plant litter identified by 13C NMR spectra. The total enzyme activity increased 5-fold during 35 years of postagricultural restoration of arable soil. The share of C-cycle enzymes with "narrower" substrate specificity (cellobiohydrolase and chitinase) increased during 35 years from 19% to 42% of the total enzyme pool. We explain this gain by the increase in the diversity and recalcitrance of organic compounds in the plant litter from cropland to natural forest. read more Aromaticity index of plant litter built up remarkably from 0.11 in the young abandoned land to 0.14-0.15 in the 35-year abandoned land and the reference site. The share of enzymes with a "narrower" substrate specificity correlated closely with the portions of aryl C, O-aryl C, and carbonyl C functional groups in plant litter. Accordingly, the succession of natural vegetation on abandoned cropland leads to strong diversification of the plant litter composition and a corresponding production of soil enzymes with "narrower" substrate specificity.The activation of peroxymonosulfate (PMS) for organic contaminant oxidation usually relies on the formation of reactive oxygen species (ROSs). However, the ubiquitous anions and natural organic matter can easily scavenge ROSs and/or PMS, resulting in lower efficiencies and/or the formation of toxic byproducts. Relying on the unique long-distance electron transfer property, the recently developed Galvanic Oxidation Process (GOP) successfully achieved bisphenol A (BPA) degradation when BPA and PMS were physically separated in two reactors. In this study, we systematically investigated the performance of GOP at different PMS or BPA concentrations, pH, and ionic strength (IS) in both PMS and BPA solutions. The kinetic modeling employing the Langmuir-Hinshelwood model at different BPA concentrations suggested that although BPA and PMS were physically separated, the oxidation of the adsorbed BPA and reduction of the adsorbed PMS still followed a similar mechanism to that in traditional heterogeneous catalytic processes. The anions in the target water showed little impact on BPA degradation; higher IS enhanced the solution conductivity but inhibited BPA and electrode interactions, resulting in increased and then decrease BPA degradation rate. The electrodes presented high stability with a rate increase of 12% after 13 times of uses, and their hydration significantly facilitated BPA degradation but reduced the current by decreasing the potential difference between the anode and cathode. The graphite sheet itself without catalyst coating was also capable of shuttling electrons, while the use of a graphite fiber anode increased the BPA degradation by near 100% because of the larger surface area. The developed continuous stirred-tank reactor coupled with GOP (CSTR-GOP) achieved stable BPA degradation in less than 35 min and its scaling up is promising for future applications.Hydrogen sulfide (H2S) represents one of the main pollutants originating from both geologic phenomena such as volcanoes, geysers, fumaroles and hot springs, and geothermal plants that produce heat and electricity. Many increasing data suggest that H2S retains a variety of biological properties, and modulates many pathways related to cardiovascular pathophysiology although its role as beneficial/adverse determinant on cardiovascular disease (CVD) is not clearly established. In this review, the current knowledge on the association between H2S exposure and risk of CVD in geothermal areas has been examined. The few epidemiological studies carried out in geothermal areas suggest, in some cases, a protective role of H2S towards CVD, while in others a positive association between exposure to H2S and increased incidence of CVD. Most of the studies have an ecological design that does not allow to produce evidence to support a causal relationship and also often lack for an adequate adjustment for individual CVD risk factors. The review has also considered the potential role of two other aspects not sufficiently explored in this relationship the production of endogenous H2S that is a gasotransmitter producing beneficial effects on cardiovascular function at low concentration and the intake of H2S-releasing drugs for the treatment of patients affected by hypertension, inflammatory diseases, and CVD. Thus, a threshold effect of H2S and the shift of action as beneficial/adverse determinant given by the synergy of exogenous exposure and endogenous production cannot be excluded. In this complex scenario, an effort is warranted in the future to include a more comprehensive evaluation of risk for CVD in relation to H2S emissions, especially in geothermal areas.