Mclaughlinyildiz9162

05) showed that PFOS and PFOA in European countries were significantly different from those in African and Latin American countries and between high-income and low-income countries. PFOA tends to have higher concentrations in wealthier countries. No correlation was found for population density.Bisphenol A is a phenolic plasticizer used in the production of various plastic products. Its endocrine-disrupting effects on ecological and human health lead to replacement with its structural analogs. The occurrence of these analogs in the soil environment, which is an important sink for bisphenols, has been rarely reported. In this study, a robust method was developed to determine bisphenol A and 13 analogs in soil using accelerated solvent extraction combined with in-line purification for fast and efficient extraction and ultra-performance liquid chromatography-tandem mass spectrometry for simultaneous and accurate quantification. The method detection limits of 14 bisphenols were between 0.01 and 0.39 ng g-1, and the recoveries were in the range of 80%-120%. The developed method was applied to 29 agricultural and urban soil samples from 21 provinces in China, and 12 bisphenols were detected. Among them, the contents of bisphenol A, F, and P were up to 166.0, 212.9, and 78.2 ng g-1 dry weight, respectively. The maximum concentration of bisphenol P was at least ten times higher than literature values in food and other environmental matrices. The results of this study showed that "hot spots" existed for bisphenol pollution in soil and that further investigations were necessary to avoid regrettable substitutions.Wastewater remediation is one of the special issues that have been discussed in recent years and one of the main pollutants was dyes which totally changes the water behavior. To eradicate the organic compounds from the wastewater and reuse it, there are numerous steps have been taken into consideration. Dye degradation via photocatalysis is one of the promising technique with good efficiency. Pure and tin (Sn) doped Co3O4 was prepared employing co-precipitation technique. The structural, vibrational, optical and morphological analysis was done employing X-ray diffraction studies, Photoluminescence, Raman analysis and Scanning Electron Microscopic (SEM) studies. The well-defined nanoparticles were grown with 1 M Sn doped Co3O4. The photocatalytic activities of methylene blue dye under visible light were investigated by adding the samples (CS-1, CS-2, CS-3). Sivelestat research buy 1 M Sn doped Co3O4 sample showed 75% efficiency towards dye degradation. The prepared 1 M Sn doped Co3O4 sample will be the best for photocatalytic activity. By doping Sn atoms the efficiency of the host is increased which will be the most promising candidate for the photocatalytic dye degradation applications.Persistent fungicides, which are widely applied to agricultural soils to protect crops, are frequently detected in freshwaters because of hydraulic transfer, possibly resulting in unintentional adverse effects on wildlife. However, the ecotoxicity of fungicides in aquatic species remains scarcely assessed at environmentally relevant concentrations, and there is scant information available on their combined effects. This study aims at investigating multi-level changes elicited by two currently used fungicides, boscalid and tebuconazole, in the amphipod Gammarus fossarum. In microcosms, gammarids were exposed for 72 h to fungicides tested individually or in binary mixture at 0.01, 0.1 and 1.0 μg/L to monitor individual performances (locomotion, respiration and amplexus formation) and biochemical parameters (involved in energy metabolism, growth, moulting and cell stress). This range of exposure concentrations was field-realistic and largely lower than local environmental quality standards for the protection of aquatic wildlife. Overall, results showed that single and combined exposures altered the mobility and respiratory activity of individuals. At the cellular level, boscalid inhibited energy-based biomarkers whereas tebuconazole led to cytotoxicity associated with reduced antioxidant defences. In binary mixtures, the biochemical responses were mainly driven by the presence of boscalid. Multi-variable analyses, integrating individual alterations and cellular impairments alike, confirmed the relevance of the multi-level approach in forecasting the toxicity of fungicides and their mixtures towards other aquatic species. This study demonstrates dose-related sublethal effects of fungicides on multiple functional traits in an ecosystem engineer under realistic exposure scenarios, highlighting the harmful signs of these toxicants. Such sublethal alterations could thus constitute reliable tools for the early diagnosis of the organisms' health and the ecological status of agriculturally impacted hydrosystems.Multiresidual pesticide analysis in hair can provide useful perspectives on the relationship between pesticides and human health. To establish a rapid and simultaneous analytical method using LC-MS/MS and GC-MS/MS, optimization of hair pulverization, extraction solvent and purification with dispersive SPE was performed for 300 pesticides. Hair pulverization was standardized with a ball mill, at 30 Hz for 20 min (10 min twice), using 3-mm diameter beads. For extraction, 0.1% formic acid in acetonitrile was selected, and PSA d-SPE was chosen for clean-up among three different types of solid phase extraction. The limits of quantitation (LOQs) in this method were between 2.5 and 7.5 pg mg-1. In recovery test, fifty milligrams of hair powder were extracted with 0.1% formic acid in acetonitrile, and incubated for three h at 40 ℃. The crude extract was treated using PSA-dSPE, dried under nitrogen gas, and reconstructed with acetonitrile. An aliquot was analyzed with LC- and GC-MS/MS. Recovery ranges were 22.7-131.1%, in LC-MS/MS analysis, and 81.1-151.8% in GC-MS/MS analysis. The validated analysis systems were applied to biomonitoring of ten agricultural workers, and residues of 28 target pesticides were detected in their hair.Volatile Organic Compounds (VOCs) are a large group of chemicals mostly found in indoor environments such as homes and workplaces. Long term exposure to certain VOCs can cause symptoms in some individuals and therefore, monitoring and controlling air quality can help better manage chronic respiratory diseases. In this study, we aimed to develop an easy-to-use, economical, in house needle trap-based methodology to detect certain VOCs to be used for public and occupational health. For this purpose, a multi-bed (packed with PDMS/Carbopack-X/Carboxen-1000) needle trap device (NTD) was utilized for sampling, enrichment, and injection of the VOCs into the gas chromatography. The performance of the developed method was investigated for the analysis of the group known as BTEX (benzene, toluene, ethylbenzene and xylene). Operational and instrumental parameters such as sampling flow rate and relative humidity, desorption time and temperature were optimized, and the analytical figures of merit of the proposed method have indicated that very low levels of BTEX in air samples can be easily determined by this new method.