Mcgowankenney7974

The results of hydraulic conductivity tests over the same time period indicated an abrupt reduction of SRS hydraulic conductivity within several months after the fire owing to ash clogging and the formation of a hydrophobic layer. After more time had elapsed, however, hydraulic conductivity had increased unexpectedly by a factor of 2.2-3.2 greater than that of unburned soil. We attribute this observation to the formation of macropore flow pathways from decayed roots, which was observed by scanning electron microscopy. The findings presented here provide important insight into the temporal changes of the hydro-mechanical characteristics of SRS in burned areas and their associated mechanisms and could be a useful reference to better evaluate post-wildfire stability of subalpine conifer forest in similar environmental conditions.Water-soluble organic matter (WSOM) is a complex mixture of organic compounds affecting global climate change and carbon cycle. Herein, Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) was used for identification of WSOM molecular compositions in annual atmospheric particulate matter with diameters ≤10 μm (PM10). Totally 6538 unambiguous monoisotopic molecular formulas were assigned to WSOM with m/z values concentrating in 150-600 Da. The CHO compounds with high unsaturation degrees contributed most (51.7-52.1%) to WSOM in spring and summer. However, the S-containing compounds (CHOS and CHNOS) with higher O/C and H/C ratios accounted for 56.8-63.2% of WSOM in autumn and winter. Temperature (r = 0.82) and O3 (r = 0.89) showed higher correlation with CHO compounds, which were mainly aliphatics and highly unsaturated structures with high oxygen compounds (80.7-90.8%). The concentrations of SO42- (r = 0.33) and NO3- (r = 0.46) in PM10 both showed a positive correlation with the abundances of the S-containing compounds due to their direct participation in atmospheric reactions. Among them, 96-100% and 78-96% of the CHOS and CHNOS compounds were confirmed to be organosulfates (OSs) and nitrooxy-organosulfates (NOSs) by MS/MS analysis, respectively. These findings illustrate the strong association of atmospheric conditions with molecular chemodiversity of WSOM.Convective mixing, mesoscale eddies and regenerated production sustain an above-average biological productivity in the North East Arabian Sea (NEAS) during the winter-spring transition period. Satellite-derived long-term data sets on Chlorophyll-a (Chl-a), Sea Surface Height Anomaly (SSHA), Sea Surface Temperature (SST) and Okubo-Weiss parameterization show existence of number of mesoscale eddies, propagating and non-propagating, that contribute to the regional production. The dominance of Eddy Kinetic Energy (EKE) over the Available Potential Energy (APE) in the core depth and the diameter (120 km) of the observed eddy being wider than the Rossby Radius of Deformation (RRD, 55 km), it is suggested that the baroclinic instability is a possible mechanism for the eddy formation. Spatial variation in APE and its influences on the regional dynamics, including chemical and biological response are explained. In the non-eddy areas, where convective mixing is active, diatoms (96.74%) dominated than dinoflagellates (3n and hence altered production patterns in the NEAS.In this work a novel nano-formulation is proposed to control leaching and volatilization of a broadly used herbicide, dicamba. Dicamba is subject to significant leaching in soils, due to its marked solubility, and to significant volatilization and vapor drift, with consequent risks for operators and neighbouring crops. Natural, biocompatible, low-cost materials were employed to control its dispersion in the environment among four tested candidate carriers, a nanosized natural clay (namely, K10 montmorillonite) was selected to adsorb the pesticide, and carboxymethyl cellulose (CMC), a food-grade biodegradable polymer, was employed as a coating agent. The synthesis approach is based on direct adsorption at ambient temperature and pressure, with a subsequent particle coating to increase suspension stability and control pesticide release. The nano-formulation showed a controlled release when diluted to field-relevant concentrations in tap water, the uncoated K10 released approximately 45% of the total loaded dicarget species.Land-use and land-cover change (LULCC) is the main cause of mangrove deforestation and degradation. However, the effect of LULCC on mangrove soil organic carbon (SOC) fractions and metal pollution risks, and the difference between the effects of those two soil evolutions are largely unknown. Here, we collected soil samples from natural systems (mangroves and mudflat), land-cover changes (Spartina alterniflora invasion), and anthropogenic land-use changes (cropland and culture pond) in Zhangjiang Estuary. We determined the soil aggregate fractions (macro-aggregate, micro-aggregate, and silt-clay fraction) and the associated carbon, and heavy metal dynamics. Our findings suggested that LULCC did not remarkably affect SOC contents, but changed the soil aggregate structures. LULCC significantly increased aggregate-associated carbon fractions, especially macro-aggregate carbon fraction. The large proportion of silt-clay fraction in natural systems was corresponding to a high percentage of mineral organic carbon, ion risk, and are of great significance for designing the long-term management and conservation policies for mangrove managers.In this study, a two-stage combined process of partial nitrification-Anammox (PNA) and partial denitrification-Anammox (PDA) was established achieving advanced nitrogen removal from landfill leachate. The PNA sludge used to treat reject water adapted to the leachate in 37 days, resulting in fast start-up of the PNA process with a nitrogen removal rate (NRR) of 0.22 kgN/(m3·d). Partial denitrification (PD) was induced using sodium acetate and proceeded in a stepwise manner using sludge fermentation liquid (SFL), achieving a NO3--N to NO2--N transformation ratio (NTR) of 52.1 ± 1.1% within 16 days. PDA was established via the addition of mature Anammox biofilms. find more The nitrogen removal efficiency (NRE) of this system was 97.6 ± 1.5%, of which PNA and PDA contributed 74.8 ± 4.0% and 18.7 ± 4.1%, respectively. Nitrosomonas (2.6% in PNA), Thauera (16.0% in PDA) and Candidatus Brocadia (23.0% in PNA, 1.4% in PDA) were dominant in the two-stage system. This study provides valuable and novel insights, supporting the practical application of PNA-PDA processes in landfill sites.Wastewater surveillance for SARS-CoV-2 RNA has been a successful indicator of COVID-19 outbreaks in populations prior to clinical testing. However, this has been mostly conducted in high-income countries, which means there is a dearth of performance investigations in low- and middle-income countries with different socio-economic settings. This study evaluated the applicability of SARS-CoV-2 RNA monitoring in wastewater (n = 132) to inform COVID-19 infection in the city of Bangkok, Thailand using CDC N1 and N2 RT-qPCR assays. Wastewater influents (n = 112) and effluents (n = 20) were collected from 19 centralized wastewater treatment plants (WWTPs) comprising four large, four medium, and 11 small WWTPs during seven sampling events from January to April 2021 prior to the third COVID-19 resurgence that was officially declared in April 2021. The CDC N1 assay showed higher detection rates and lower Ct values than the CDC N2. SARS-CoV-2 RNA was first detected at the first event when new reported cases were low. Increased positive detection rates preceded an increase in the number of newly reported cases and increased over time with the reported infection incidence. Wastewater surveillance (both positive rates and viral loads) showed strongest correlation with daily new COVID-19 cases at 22-24 days lag (Spearman's Rho = 0.74-1.00). Large WWTPs (serving 400,000-580,000 of the population) exhibited similar trends of viral loads and new cases to those from all 19 WWTPs, emphasizing that routine monitoring of the four large WWTPs could provide sufficient information for the city-scale dynamics. Higher sampling frequency at fewer sites, i.e., at the four representative WWTPs, is therefore suggested especially during the subsiding period of the outbreak to indicate the prevalence of COVID-19 infection, acting as an early warning of COVID-19 resurgence.The continuous growth of population and the steady improvement of people's living standards have accelerated the generation of massive food waste. Untreated food waste has great potential to harm the environment and human health due to bad odor release, bacterial leaching, and virus transmission. However, the application of traditional disposal techniques like composting, landfilling, animal feeding, and anaerobic digestion are difficult to ease the environmental burdens because of problems such as large land occupation, virus transmission, hazardous gas emissions, and poor efficiency. Pyrolysis is a practical and promising route to reduce the environmental burden by converting food waste into bioenergy. This paper aims to analyze the characteristics of food waste, introduce the production of biofuels from conventional and advanced pyrolysis of food waste, and provide a basis for scientific disposal and sustainable management of food waste. The review shows that co-pyrolysis and catalytic pyrolysis significantly impact the pyrolysis process and product characteristics. The addition of tire waste promotes the synthesis of hydrocarbons and inhibits the formation of oxygenated compounds efficiently. The application of calcium oxide (CaO) exhibits good performance in the increment of bio-oil yield and hydrocarbon content. Based on this literature review, pyrolysis can be considered as the optimal technique for dealing with food waste and producing valuable products.Epidemiological evidence linking metals bound to ambient particulate matters with aerodynamic diameter less than 2.5 μm (PM2.5) and maternal thyroid function is limited. In this study, we investigated the association of PM2.5-bound metals with maternal thyroid hormones (TH) during the first trimester. We retrospectively reviewed data for 2528 pregnant women attending prenatal care in Jinhua Maternal and Child Health Care Hospital, Jinhua, China, from January to December 2018. Information including thyroid hormone levels and demographics was retrieved from existing medical records. We analyzed the concentration of 10 metals for collected particulate samples, and estimated their exposure levels during the first trimester for each woman. We employed multivariate linear regression models to estimate the association of exposure to individual PM2.5-bound metals with serum levels of maternal TH, and weighted quantile sum (WQS) to estimate the overall association of exposure to PM2.5-bound metals within a mixture. Higher exposures to most of the PM2.5-bound metals were associated with lower levels of maternal free thyroxine (FT4) and free triiodothyronine (FT3). The thyroid peroxidase antibody (TPOAb) or thyroglobulin antibody (TgAb) status had no effect modification on the observed associations. WQS analyses further suggested that Be, Ni, Tl and Ba contributed the most to the associations. These findings highlight the associations of exposure to PM2.5-bound metals with maternal thyroid function, and emphasize the public health significance of commitments to improve air quality.