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Hypersaline environments are underappreciated and are frequently exposed to pollution from petroleum hydrocarbons. Unlike other environs, the high salinity conditions present are a deterrent to various remediation techniques. There is also production of hypersaline waters from oil-polluted ecosystems which contain toxic hydrophobic pollutants that are threat to public health, environmental protection, and sustainability. Currently, innovative advances are being proposed for the remediation of oil-contaminated hypersaline regions. Such advancements include the exploration and stimulation of native microbial communities capable of utilizing and degrading petroleum hydrocarbons. However, prevailing salinity in these environments is unfavourable for the growth of non-halophylic microorganisms, thus limiting effective bioremediation options. An in-depth understanding of the potentials of various remediation technologies of hydrocarbon-polluted hypersaline environments is lacking. Thus, we present an overview of petroleum hydrocarbon pollution in hypersaline ecosystems and discuss the challenges and prospects associated with several technologies that may be employed in remediation of hydrocarbon pollution in the presence of delimiting high salinities. The application of biological remediation technologies including the utilization of halophilic and halotolerant microorganisms is also discussed.The baseline data of radioactivity levels in food is one of the main factors for the assessment of resident's health risk. Gross beta and alpha activity was identified for selected commercial freshwater fish species, including 29 types of fish species by a gas-flow proportional detector. The samples were collected from wholesale markets in Hanoi city, Vietnam. The highest gross alpha activity was recorded in blotched snakehead, a pelagic and carnivorous species, and the lowest one was recorded in common carp, a demersal and omnivorous species. Meanwhile, the gross beta activity was much higher than the gross alpha activity with the highest value of gross beta, observed in Wels catfish, a demersal and carnivorous species, and the lowest one found in Mudskipper a demersal, herbivores species. Regarding feeding types, the gross alpha activity was observed in the order of Alcarnivores > Alomnivores > Alherbivores whereas the gross beta was non-distinction. In terms of living behavior, the gross alpha activity in pelagic species was much higher than that in demersal species (Alpelagic >  > Aldemersal) and indifferent for gross beta. There was an insignificant relationship between the trophic level with gross beta and alpha activities in freshwater fish species. The calculated annual effective dose ranged from 0.19 to 1.88 and 0.78 mSv.y-1 on average, being within the limited dose for the public as reported by UNSCEAR in which gross beta activity has a strong correlation with the total annual effective dose.Urban water pollution has been well controlled by strict management in the past few decades in China. Thus, the central government started to place emphasis on rural water pollution, and increasing number of sewage treatment facilities have been constructed, and currently, they are operating in China. Therefore, thoroughly assessing the operating conditions and the performance of these facilities is important. This article analyzes life cycle assessment and life cycle cost to evaluate the environmental and economic performance of four common technologies to determine how the emerging rural sewage treatment facilities in China are running. The results showed that the plant-adopted anaerobic-anoxic-oxic process was an optimal scheme for lower environmental impact that was also cost-effective. All technologies had similar impacts on eleven environmental categories. Due to cement consumption during the construction phase and electricity consumption during the operation phase, the marine aquatic ecotoxicity potential was the greatest contributor, accounting for approximately 90% of the total potential impact. In addition, this research revealed that electricity consumption during the operation phase was responsible for almost all environmental impact categories, except for eutrophication potential and ozone layer depletion potential categories. Lastly, scenario analysis indicated that reusing treated water and adjusting power structure could be useful measures to promote the sustainable development of rural water environments.This paper presents a theoretical investigation of structural, optical, and phosphorescence properties of four cyclometalated Pt(II) complexes containing substituted 2-(2-thienyl)pyridine ligands using DFT and TD-DFT methods. Geometrical parameters of ground states were calculated and compared with available experimental data. Electronic absorptions were studied and assigned in terms of natural transition orbitals. Phosphorescence spectra have been simulated with adiabatic Hessian and adiabatic shift approaches according to the Franck-Condon approximation. selleck chemicals llc Theoretical and experimental results agree and show that the four complexes exhibit two intense bands in orange region. Main normal modes involved in phosphorescence bands were analyzed and assigned.In molecular photochemistry, charge-transfer emission is well understood and widely exploited. In contrast, luminescent metal-centered transitions only came into focus in recent years. This gave rise to strongly phosphorescent CrIII complexes with a d3 electronic configuration featuring luminescent metal-centered excited states which are characterized by the flip of a single spin. These so-called spin-flip emitters possess unique properties and require different design strategies than traditional charge-transfer phosphors. In this review, we give a brief introduction to ligand field theory as a framework to understand this phenomenon and outline prerequisites for efficient spin-flip emission including ligand field strength, symmetry, intersystem crossing and common deactivation pathways using CrIII complexes as instructive examples. The recent progress and associated challenges of tuning the energies of emissive excited states and of emerging applications of the unique photophysical properties of spin-flip emitters are discussed. Finally, we summarize the current state-of-the-art and challenges of spin-flip emitters beyond CrIII with d2, d3, d4 and d8 electronic configuration, where we mainly cover pseudooctahedral molecular complexes of V, Mo, W, Mn, Re and Ni, and highlight possible future research opportunities.Plants of the genus Hevea present a great diversity of endophytic fungal species, which can provide bioactive compounds and enzymes for biotechnological use, and antagonist agents for plant disease biological control. The diversity of endophytic fungi associated with leaves of Hevea spp. clones in western Amazonia was explored using cultivation-based techniques, combined with the sequencing of the ITS rRNA-region. A total of 269 isolates were obtained, and phylogenetic analysis showed that they belong to 47 putative species, of which 24 species were unambiguous. The phylum Ascomycota was the most abundant (95.4%), with predominance of the genera Colletotrichum and Diaporthe, followed by the phylum Basidiomycota (4.6%), with abundance of the genera Trametes and Phanerochaete. Endophytic composition was influenced by the clones, with few species shared among them, and the greatest diversity was found in clone C44 (richness 26, Shannon 14,15, Simpson 9.11). The potential for biocontrol and enzymatic production of endophytes has been investigated. In dual culture tests, 95% of the isolates showed inhibitory activity against C. gloeosporioides, and 84% against C. cassiicola. Efficient inhibition was obtained with isolates HEV158C and HEV255M (Cophinforma atrovirens and Polyporales sp. 2) for C. gloeosporioides, and HEV1A and HEV8B (Phanerochaete sp. 3 and Diaporthe sp. 4) for C. cassiicola. The endophytic isolates were positive for lipase (69.6%), amylase (67.6%), cellulase (33.3%), and protease (20.6%). The enzyme index ≥ 2 was found for amylase and lipase. The isolates obtained from rubber trees showed good antimicrobial and enzymatic potential, which can be tested in the future for use in the industry, and in the control of plant pathogens.Chronic ankle instability (CAI) is associated with recurring symptoms that inhibit daily activity. Stability-based rehabilitative training is recommended for CAI. Visualisation (VIS) produces real-time feedback using motion capture and virtual reality. This pilot study aimed to determine the feasibility, adherence, safety, and efficacy of incorporating VIS into stability training for people with CAI. Efficacy was examined through effect of VIS training on dynamic stability, perception of stability, and rehabilitative experience. Individuals with CAI completed a 4-week stability-based training programme with VIS, or without visualisation (NO-VIS). Participants completed the Star Excursion Balance Test (SEBT) and Cumberland Ankle Instability Tool (CAIT) prior to, and after training. Enjoyment of training was recorded using the Physical Activity Enjoyment Scale (PACES-8). Of 17 participants (VIS = 10, NO-VIS = 7), there were 2 drop outs (VIS = 1, NO-VIS = 1). No adverse events were reported, and participant drop-out was due to injury unrelated to the study. The VIS group showed a significantly greater increase in average SEBT reach distance (d = 1.7, p = 0.02). No significant differences were reported for the CAIT or PACES-8. This study supports the feasibility and safety of stability-based training with VIS in those with CAI. The enhanced performance outcome on the SEBT suggests VIS may enhance stability-based training.

Human cardiac tissue engineering holds great promise for early detection of drug-related cardiac toxicity and arrhythmogenicity during drug discovery and development. We describe shortcomings of the current drug development pathway, recent advances in the development of cardiac tissue constructs as drug testing platforms, and the challenges remaining in their widespread adoption.

Human pluripotent stem cell-derived cardiomyocytes (hPSC-CMs) have been used to develop a variety of constructs including cardiac spheroids, microtissues, strips, rings, and chambers. Several ambitious studies have used these constructs to test a significant number of drugs, and while most have shown proper negative inotropic and arrhythmogenic responses, few have been able to demonstrate positive inotropy, indicative of relative hPSC-CM immaturity. Several engineered human cardiac tissue platforms have demonstrated native cardiac physiology and proper drug responses. Future studies addressing hPSC-CM immaturity and inclusion of patient-specific cell lines will further advance the utility of such models for in vitro drug development.

Human pluripotent stem cell-derived cardiomyocytes (hPSC-CMs) have been used to develop a variety of constructs including cardiac spheroids, microtissues, strips, rings, and chambers. Several ambitious studies have used these constructs to test a significant number of drugs, and while most have shown proper negative inotropic and arrhythmogenic responses, few have been able to demonstrate positive inotropy, indicative of relative hPSC-CM immaturity. Several engineered human cardiac tissue platforms have demonstrated native cardiac physiology and proper drug responses. Future studies addressing hPSC-CM immaturity and inclusion of patient-specific cell lines will further advance the utility of such models for in vitro drug development.