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Furthermore, the composition of the resin cement was determinant for the correlation's coefficients of these physical properties with depth. β-Glycerophosphate order The μCT technique showed to be useful to probe physical properties of dental restorative materials that influence in the clinical outcomes, revealing that, for thin specimens, when light cured the RU cement presented mechanical behavior more favorable for clinical applications. © 2020 Wiley Periodicals, Inc.Amphiphilic donor/acceptor dyes were synthesized from unsymmetrically substituted perylene bisimide dyes, which were obtained by three synthetic methods. The optical behaviors and aggregation behaviors of these functional dyes were studied by UV/vis absorption and fluorescence spectroscopy, dynamic light scattering and transmission electron microscopy. The donor/acceptor dye displays high efficient intramolecular fluorescence resonance energy transfer (96.4%) from pyrene to peylene bisimide chromophores, which leads to a high fluorescence color sensitivity to environment polarity. Under 365nm UV lamp, the light-emitting colors of donor/acceptor dye change from green to yellow with increasing solvent polarity, which demonstrates application potentials as a new class of fluorescence resonance energy transfer probes. The donor/acceptor dye in water was assembled into hollow vesicles with narrow size distribution as revealed by transmission electron microscopy and dynamic light scattering measurements. The bilayer structure of vesicular wall was directly observed by transmission electron microscopy. These vesicular aggregates in water are fluorescent at 650-850 nm within near-infrared region. © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.Dehydropolymerisation of methylamine borane (H 3 B ∙ NMeH 2 ) using the well-known iron amido complex [(PNP)Fe(H)(CO)] (PNP = N(CH 2 CH 2 P i -Pr 2 ) 2 ) ( 1 ) gives poly(aminoborane)s by a chain growth mechanism. In toluene, rapid dehydrogenation of H 3 B ∙ NMeH 2 following a borderline case of first-order/Michaelis-Menten kinetics is observed, forming aminoborane H 2 B=NMeH which selectively couples to give high-molecular weight poly(aminoborane)s (H 2 BNMeH) n and only traces of borazine (HBNMe) 3 by depolymerisation after full conversion. Based on a series of comparative experiments using structurally related Fe catalysts and dimethylamine borane (H 3 B ∙ NMe 2 H) polymer formation is proposed to occur by nucleophilic chain growth as reported earlier computationally and experimentally. A silyl functionalised primary borane H 3 B ∙ N(CH 2 SiMe 3 )H 2 was studied in homo- and co-dehydropolymerisation reactions to give the first examples for Si containing poly(aminoborane)s. © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.Non-planar conjugated organic molecules (NPCOMs) contain pi -conjugation across their length and also exhibit asymmetry in their conformation. In other words, certain molecular fragments in NPCOMs are either twisted or curved out of planarity. This conformational asymmetry in NPCOMs leads to non-uniform charge-distribution across the molecule, with important photophysical and electronic consequences such as altered thermodynamic stability, chemical reactivity, as well as materials properties. Majorly, NPCOMs can be classified as having either fused or rotatable architectures. NPCOMs have been the focus of significant scientific attention in the recent past due to their exciting photophysical behavior that includes intramolecular charge-transfer (ICT), thermally activated delayed fluorescence (TADF) and long-lived charge-separated states. In addition, they also have many useful materials characteristics such as biradical character, semi- conductivity, dynamic conformations, and mechanochromism. As a result, rational design of NPCOMs and mapping their structure-property correlations has become imperative. Researchers have executed conformational changes in NPCOMs through a variety of external stimuli such as pH, temperature, anions-cations, solvent, electric potential, and mechanical force in order to tailor their photophysical, optoelectronic and magnetic properties. Converging to these points, this review highlights the lucrative electronic features, photophysical traits and upcoming applications of NPCOMs by a selective survey of the recent scientific literature. © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.NEW FINDINGS What is the central question of this study? Are fitness-related improvements in thermoregulatory responses during uncompensable heat stress mediated by aerobic capacity V ̇ O 2 max or is it the partial heat acclimation associated with training? What is the main finding and its importance? During uncompensable heat stress, individuals with high and low V ̇ O 2 max displayed similar sweating and core temperature responses whereas exercise training in previously untrained individuals resulted in a greater sweat rate and a smaller rise in core temperature. These observations suggest that it is training, not V ̇ O 2 max per se, that mediates thermoregulatory improvements during uncompensable heat stress. ABSTRACT It remains unclear whether aerobic fitness, as defined by the maximum rate of oxygen consumption V ̇ O 2 max , independently improves heat dissipation in uncompensable environments, or whether the thermoregulatory adaptations associated with heat acclimation are due to repeated bouts of exercing. During exercise, mean local sweat rate (forearm and upper-back) was greater post- (1.24 ± 0.20 mg cm-2  min-1 ) compared to pre- (1.04 ± 0.25 mg cm-2  min-1 , P  less then  0.01) training, but similar between UF (0.94 ± 0.31 mg cm-2  min-1 , P = 0.90) and F (1.02 ± 0.30 mg cm-2  min-1 ). The ΔTre at 60 min of exercise was greater pre- (1.13 ± 0.16°C, P  less then  0.01) compared to post- (0.96 ± 0.14°C) training, but similar between UF (0.85 ± 0.29°C, P = 0.22) and F (0.95 ± 0.22°C). Taken together, aerobic training, not V ̇ O 2 max per se, confers an increased ωmax , greater sweat rate, and smaller rise in core temperature during uncompensable heat stress in fit individuals. © 2020 The Authors. Experimental Physiology © 2020 The Physiological Society.