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The DFT simulation of the XRD pattern provides significant information on the stage index and the charge capacity of the GIC electrode.The photodissociation of the allyl radical (CH2[double bond, length as m-dash]CH-CH2˙) following excitation between 216 and 243 nm has been investigated employing velocity map imaging in conjunction with resonance enhanced multiphoton ionization to detect the hydrogen atom and CH3(ν = 0) produced. The translational energy distributions for the two fragments are reported and analyzed along with the corresponding fragment ion angular distributions. The results are discussed in terms of the different reactions pathways characterizing the hydrogen atom elimination and the minor methyl formation. On one hand, the angular analysis provides evidence of an additional mechanism, not reported before, leading to prompt dissociation and fast hydrogen atoms. On the other hand, the methyl elimination channel has been characterized as a function of the excitation energy and the contribution of three reaction pathways single 1,3-hydrogen shift, double 1,2-hydrogen shift and through the formation of vinylidene have been discussed. Contrary to previous predictions, the vinylidene channel, which plays a significant role at lower energies, seems to vanish following excitation on the E[combining tilde]2B1(3px) excited state at λ≤ 230 nm.Double perovskite-based silver and bismuth Cs2AgBiX6 (X = Cl, Br, I) have shown a bright future for the development of low-risk photovoltaic devices due to their high stability and non-toxicity of their elements, unlike Pb-based perovskites. Despite the great focus on the optoelectronic properties of Cs2AgBiX6 double perovskites, there are limited studies on the behavior of their structural properties. Herein, we carefully examined the cubic structure of Cs2AgBiX6 double perovskites, identifying a pseudo-cubic (ps-cubic) phase, which is similar to the initial cubic phase. The observed pseudo-cubic phase is more consistent with previous experimental results demonstrating higher elastic properties, which are useful for designing optoelectronic devices.Correction for 'Predictable spectroscopic properties of type-II ZnTe/CdSe nanocrystals and electron/hole quenching' by Tongqing Long et al., Phys. Chem. Chem. Phys., 2019, 21, 5824-5833.A self-assembled DNA nanostructure based on a DNA nanocreeper and multiplexed fluorescence supersandwich was designed for the sensitive and specific detection of tumour cells. This nanostructure could improve the binding affinity of current aptamers and trigger signal amplification, which provide potential for the discrimination of low abundant target cells in liquid biopsy.Abundant hydration, diffusivity, and volatile phase composition render the surface of calcium phosphates (CPs) a complex dynamic region. Three CP powders were analyzed using X-ray photoelectron spectroscopy (XPS) and ion scattering spectroscopy (ISS) with regard to their surface compositions and fine structures hydroxyapatite (HAp), amorphous CP (ACP), and a CP formed under the same conditions as ACP but allowed to ripen into HAp (ACP → HAp). XPS analyses revealed that the Ca/P atomic ratio in the 2-10 nm-thick layers of the nanoparticle surface was somewhat lower than the stoichiometric ratio for all the three CPs. However, it was still lower for ACP and ACP → HAp than that for HAp, indicating the incongruent dissolution of all the surfaces and also greater instability and higher solubility of ACP and ACP → HAp as compared to those of HAp. Consequently, as indicated by both XPS and ISS, the amount of adventitious carbon bound to HAp was higher than that on ACP or ACP → HAp. The binding energies of the most ien the surfaces of the two different forms of HAp as compared to that for ACP, but also a definite impression of the traces of their formation history on them.Induction of premalignant lesions in animal models is of high value for research purposes. This study aimed to induce dysplasia in hamster mucosal pouch for investigation of dysplastic lesions using dimethylbenz(a)anthracene. The buccal pouch of 10 hamsters was painted with dimethylbenz(a)anthracene for 10 weeks every other day. At 5 and 10 weeks, they underwent histopathological analysis. Clinically, there was no change until week 7; after which mucosal thickening occurred. Hamsters scarified at 5 weeks and 10 weeks demonstrated mild and moderate dysplasia, respectively. dimethylbenz(a)anthracene is a useful tool for inducing dysplastic lesions in the buccal pouch mucosa of hamsters. Copyright© Dental Research Center, Tehran University of Medical Sciences.Objectives Color change of cements over time can be detected through translucent ceramic veneers, compromising the aesthetic appearance of restorations in the long-term. This study aimed to assess the color stability of ceramic laminate veneers cemented with self-adhesive resin cements after accelerated aging. Materials and Methods In this study, 21 IPS e.max ceramic discs, measuring 8mm in diameter and 0.7 mm in thickness, were fabricated and divided into three groups (n=7) for the application of Choice 2 total-etch light-cure resin cement, RelyX U200 dual-cure self-adhesive resin cement, and SpeedCEM self-cure self-adhesive resin cement. The ceramic discs in each group were cemented on the prepared facial surface of bovine teeth. The color parameters were assessed using a spectrophotometer. Subsequently, the samples were subjected to accelerated aging for 100 hours, and the color parameters were measured again. The data were analyzed using two-way repeated-measures analysis of variance (ANOVA) and Tamhane's post-hoc test (P3.5). The color change of the other two groups was clinically acceptable (1 less then ΔE less then 3.5). Conclusion The self-adhesive dual-cure cement showed color stability comparable to that of the total-etch light-cure cement for cementation of IPS e.max ceramic laminates. The color stability of both cements was superior to that of the self-adhesive self-cure cement. Copyright© Dental Research Center, Tehran University of Medical Sciences.Objectives Considering the emergence of resistant microbes and side effects of chemical drugs, in this study, the inhibitory effect of organic and hydro-alcoholic extracts of Boswellia serrata (B. serrata) on some oral microbiota was investigated. Materials and Methods In this experimental study, standard strains of Candida albicans (C. albicans; PTCC 5027), Candida glabrata (C. glabrata; PTCC 5295), Candida krusei (C. krusei; PTCC 5297), and Streptococcus mutans (S. mutans; PTCC 1688) were collected from the Iranian Research Organization for Science and Technology (IROST). Then, the minimum inhibitory concentration (MIC) of organic and hydro-alcoholic extracts of B. serrata was determined based on the CLSI protocol and using the micro-dilution method. The contents of each well were subcultured in Müller-Hinton agar (Candida species) and blood agar (S. mutans). The lowest concentration with no growth was considered as the minimum fungicidal concentration (MFC) or bactericidal concentration (MBC). Statistical analyses were performed using Mann-Whitney test. Results Hydro-alcoholic extract of B. serrata at the concentration of 50 mg/ml inhibited the growth of C. albicans and S. mutans. It also inhibited the growth of C. krusei and C. glabrata at the concentration of 100 mg/ml. Organic extract of B. serrata at the concentration of 200 mg/ml only inhibited the growth of C. glabrata. TTNPB Conclusion Hydro-alcoholic extract of B. serrata had a greater inhibitory effect on C. albicans and S. mutans compared to the organic extract. Copyright© Dental Research Center, Tehran University of Medical Sciences.Objectives We aimed to evaluate the knowledge and attitude of Iranian dentists towards cone-beam computed tomography (CBCT). Materials and Methods A 20-item questionnaire was distributed among 410 Iranian dentistry graduates attending the 56th Congress of Iranian Dental Association held in Tehran, Iran. The questionnaire included items on demographic characteristics, namely full name, age, gender, work experience, type of current activity (individual or group), and the highest educational level. In addition, the questionnaire contained items on the knowledge and attitude of dentists. The obtained data were analyzed using statistical tests. Results In this study, 49.3% and 22.4% of the subjects were male and female, respectively, 47.1% of whom used CBCT, while 49.8% did not. In detail, 72.2% of the dentists used the technique to evaluate the location of implants, whereas 19.7%, 3.2%, and 2.7% of the subjects applied it to localize the inferior alveolar nerve (IAN), evaluate the location of implants and localize the IAN, and perform cephalometric analysis, respectively. The main causes of lack of prescription of CBCT entailed high cost (80%), high rate of patient absorbed dose (27.6%), insufficient number of CBCT centers (46.3%), and the long duration of the process (15.6%). Conclusion CBCT is an advantageous imaging technique in dentistry. Considering the increased application of CBCT in dentistry, attending workshops could help train dentists to use the technique. Copyright© Dental Research Center, Tehran University of Medical Sciences.Objectives This study aimed to assess the shear bond strength (SBS) of molar tubes to the enamel surface of molar teeth using a resin-modified glass ionomer (RMGI) cement modified with amorphous calcium phosphate (ACP). Materials and Methods In this in-vitro study, 60 extracted human third molars were randomly divided into four groups for bonding of molar tubes to the enamel surface. Fuji Ortho LC and Fuji Ortho LC modified with ACP (1.55 wt%) were used in groups 1 and 2, respectively. In group 3, the enamel surface was sandblasted, and bonding was then performed using Fuji Ortho LC glass ionomer modified with ACP. In group 4, molar tubes were conventionally bonded using Transbond XT composite. The SBS was measured using a universal testing machine. Results The mean SBS of groups 1 to 4 was 10.22, 6.88, 9.4, and 13.68 MPa, respectively. Only the SBS of group 1 was not significantly different from that of groups 3 and 4 (P>0.05). Comparison of adhesive remnant index (ARI) scores of the groups revealed significant differences only between groups 1 and 4 (P less then 0.001) and between groups 1 and 2 (P=0.002). Conclusion The results revealed that the addition of ACP to Fuji Ortho LC significantly decreased the SBS of molar tubes bonded to enamel compared to the conventional resin bonding system. Sandblasting of the enamel surface significantly increased the bond strength. Fuji Ortho LC modified with ACP is recommended for bonding of molar tubes to posterior teeth considering its cariostatic property. Copyright© Dental Research Center, Tehran University of Medical Sciences.Objectives This study aimed to compare the optical properties of Zolid FX, Katana UTML, and lithium disilicate laminate veneers. Materials and Methods In this in-vitro experimental study, the maxillary left lateral incisor of a phantom received a laminate veneer preparation. An impression was made, and a die was fabricated using dental stone. The die was scanned using a computer-aided design/computer-aided manufacturing scanner. Ten dies were fabricated from each of the A1, A2, and A3 shades of composite resin. Laminate veneers were fabricated using A1 shade of Katana UTML, Zolid FX, and IPS e.max CAD ceramics (n=10) and placed on composite abutments using bleach and white colors of trial insertion paste (TIP). The optical properties were measured at the incisal, middle, and cervical thirds using a spectrophotometer. Data were analyzed using three-way analysis of variance and Tukey's test. Results The effect of laminate material on the L*, a*, and b* parameters was significant in all areas (P less then 0.001), except for the L* parameter in the middle and cervical thirds.