Lentzgibbs0320

Food packaging faces the negative impact of synthetic materials on the environment, and edible coatings offer one alternative from filmogenic suspensions (FS). In this work, an active edible FS based on chitosan (C) and quinoa protein (QP) cross-linked with transglutaminase was produced. Thyme (T) and rosemary (R) essential oils (EOs) were incorporated as antimicrobial agents. Particle size, Z potential, and rheological parameters were evaluated. The antimicrobial activity against Micrococcus luteus (NCIB 8166) and Salmonella sp. (Lignieres 1900) was monitored using atomic force microscopy and image analysis. Results indicate that EOs incorporation into CQP suspensions did not affect the Z potential, ranging from -46.69 ± 3.19 mV to -46.21 ± 3.83 mV. However, the polydispersity index increased from 0.51 ± 0.07 to 0.80 ± 0.04 in suspensions with EO. The minimum inhibitory concentration of active suspensions against Salmonella sp. was 0.5% (v/v) for thyme and 1% (v/v) for rosemary. Entropy and fractal dimension of the images were used to confirm the antimicrobial effect of EOs, which modified the surface roughness.Epidural electrical stimulation (ES) of the lumbar spinal cord combined with daily locomotor training has been demonstrated to enhance stepping ability after complete spinal transection in rodents and clinically complete spinal injuries in humans. Although functional gain is observed, plasticity mechanisms associated with such recovery remain mostly unclear. Here, we investigated how ES and locomotor training affected expression of chondroitin sulfate proteoglycans (CSPG), perineuronal nets (PNN), and synaptic plasticity on spinal motoneurons. To test this, adult rats received a complete spinal transection (T9-T10) followed by daily locomotor training performed under ES with administration of quipazine (a serotonin (5-HT) agonist) starting 7 days post-injury (dpi). Excitatory and inhibitory synaptic changes were examined at 7, 21, and 67 dpi in addition to PNN and CSPG expression. The total amount of CSPG expression significantly increased with time after injury, with no effect of training. An interesting finding was that γ-motoneurons did not express PNNs, whereas α-motoneurons demonstrated well-defined PNNs. This remarkable difference is reflected in the greater extent of synaptic changes observed in γ-motoneurons compared to α-motoneurons. 2Aminoethanethiol A medium negative correlation between CSPG expression and changes in putative synapses around α-motoneurons was found, but no correlation was identified for γ-motoneurons. These results suggest that modulation of γ-motoneuron activity is an important mechanism associated with functional recovery induced by locomotor training under ES after a complete spinal transection.Experimental insights into the synergistic effect of 1-acetyl-3-thiosemicarbazide (AST) and iodide ions on the corrosion of C1018 carbon steel in 1 M HCl solution were investigated using open-circuit potential (OCP), linear polarization resistance (LPR), electrochemical frequency modulation (EFM), potentiodynamic polarization (PDP) measurements and electrochemical impedance spectroscopy (EIS). Theoretical studies were further undertaken using ACD/LABS Percepta software, density functional theory (DFT) calculations and Monte Carlo simulation to understand the mechanism of the corrosion inhibition process and interpret the experimental results at the atomic and molecular levels. The electrochemical results obtained showed that AST alone inhibited the acid-induced corrosion of C1018 carbon steel. The inhibition efficiency increases with a concentration reaching up to 72.27% at 750 ppm of AST. The addition of 5 mM KI to 250 ppm of AST improved the inhibition efficiency to 81.64%. The solubility and protonated state results predicted using the ACD/LABS Percepta software showed that AST was highly soluble in the aqueous acidic medium and approximately 95% of AST exists in the neutral form in 1 M HCl (pH = 0). DFT calculations and a Monte Carlo simulation were utilized to predict the active reactivity sites of AST and calculate the lowest adsorption energy and configuration of AST alone and AST + iodide on/Fe (110)/water interface.Synthetic anion transporters that facilitate chloride transport are promising candidates for channelopathy treatments. However, most anion transporters exhibit an undesired side effect of facilitating proton transport via interacting with fatty acids present in the membrane. To address the limitation, we here report the use of a new tetrapodal scaffold to maximize the selective interaction with spherical chloride over binding the carboxylate headgroup of fatty acids. One of the new transporters demonstrated a high selectivity for chloride uniport over fatty acid-induced proton transport while being >10 times more active in chloride uniport than strapped calixpyrroles that were previously the only class of compounds known to possess similar selectivity properties.This paper presents a method for low data rate transmission for devices implanted in the body using backscattered Long Range (LoRa) signals. The method uses an antenna loaded with a switch that changes between two load impedances at the rate of a modulating oscillator. Consequently, the LoRa signal transmitted by a LoRa node is reflected in the adjacent channels and can be detected with a LoRa gateway tuned to the shifted channels. A prototype developed to operate at Medical Implant Communication Service (MICS) and the Industrial Scientific and Medical (ISM) 433 MHz band is presented. The prototype uses a commercial ceramic antenna with a matched network tuned to the frequency band with high radiation efficiency. The effect of the coating material covering the antenna was studied. Simulated and experimental results using a phantom show that it is feasible to read data from deep implanted devices placed a few meters from the body because of the high sensitivity of commercial LoRa receivers.This study aims to describe parents' and infant's interactive styles after assisted reproduction treatments (ART), to compare them with parent-infant interactions after spontaneous conception (SC), and to assess the effect of specific ART variables (cause of infertility, treatment type, and previous ART attempts) on interaction quality. The sample included 25 ART conceiving couples and 31 SC couples with their 3-months-old babies. Free parent-infant interactions (3-5 min) were coded using the CARE-Index, a video-based assessment scale that gives both dimensional (e.g., sensitivity, control, passivity) and categorical scores (sensitive, inept, at-risk) for parents and infants. Results showed a global similarity between groups in CARE-Index dimensions. Nevertheless, differences emerged in categorical scores, as the interactive patterns of ART parents were more frequently classified as "inept" and "at-risk" compared to SC parents. With regards to ART dyads only, infants conceived through intracytoplasmic sperm injection scored significantly lower to the dimension compulsivity and higher to passivity, compared to infants conceived through in vitro fertilization.