Leachbenjamin6549

The generated ·O2--, ·OH and h+ by ternary composites could promote the dechlorination reaction of 2,4-DCP effectively and decompose it into smaller organic molecules. This work extends the design of g-C3N4-based 2D/2D heterojunction or Z-scheme photocatalysts to remediate the environment.Despite showing serious health consequences and widespread exposure, the toxicokinetic information required to evaluate the health risks of BPS is insufficient. Thus, we aim to describe the comprehensive toxicokinetics of BPS and its glucuronide (BPS-G) and sulfate (BPS-S) metabolites in rats. Simultaneous quantification of BPS and its metabolites (authentic standards) was accomplished using UPLC-MS/MS method. BPS displayed rapid absorption, extensive metabolism and fast elimination after oral administration. Following intravenous administration, BPS exhibited CL (8.8 L/h/kg) higher than the rat hepatic blood flow rate suggesting the likelihood of extrahepatic clearance. The CL value differed from those reported previously (sheep and piglets) and the probable reason could be attributed to dose- and/or interspecies differences. BPS was extensively metabolized and excreted primarily through urine as BPS-G (∼56%). BPS and BPS-S exhibited a high protein binding capacity in comparison to BPS-G. In in vitro metabolic stability study, BPS was predominantly metabolized through glucuronidation. The predicted in vivo hepatic clearance of BPS suggested it to be a high and intermediate clearance chemical in rats and humans, respectively. The significant interspecies difference observed in the clearance of BPS between rats and humans indicated that toxicokinetics of BPS should be considered for health risk assessment in humans.Streptomyces pactum (Act12), an agent of a gentle in situ remediation approach, has been recently used in few works in phytoextraction trials; however, the impact of Act12 on soil quality and metal phytoavailability has not been assessed in multi-metal contaminated soils. Consequently, here we assessed the potential impact of Act12 on the wheat (Triticum aestivum L.) growth, antioxidants activity, and the metal bioavailability in three industrial and mining soils collected from China and contained up to 118, 141, 339, and 6625 mg Cd, Cu, Pb, and Zn kg-1 soil, respectively. The Act12 was applied at 0 (control), 0.75 (Act-0.75), 1.50 (Act-1.5), and 2.25 (Act-2.25) g kg-1 (dry weight base) to the three soils; thereafter, the soils were cultivated with wheat (bio-indicator plant) in a pot experiment. The addition of Act12 (at Act-1.5 and Act-2.25) promoted wheat growth in the three soils and significantly increased the content of Cd, Cu, and Zn in the roots and shoots and Pb only in the roots (up to 121%). Immunology chemical The Act12-induced increase in metals uptake by wheat might be attributed to the associated decrease in soil pH and/or the increase of metal chelation and production of indole acetic acid and siderophores. The Act12 significantly decreased the antioxidant activities and lipid peroxidation in wheat, which indicates that Act12 may mitigate metals stress in contaminated soils. Enhancing metals phytoextraction using Act12 is a promising ecofriendly approach for phytoremediation of metal-contaminated mining soils that can be safely utilized with non-edible plants and/or bioenergy crops.Electrostatic and complexation effects have been considered as the primary adsorption mechanisms for defluorination using aluminum based materials, while the effect of ion exchange between anions and fluorine ion has been mostly ignored, although synthesized alumina materials usually contain a large amount of anions, such as SO42-, NO3-, and Cl-. In this study, the effect of anions exchanges and its key role on defluorination were systematically investigated for adsorption by aluminas loaded with various typical anions (SO42-, NO3- and Cl-). Experimental results showed that SO42-- loading alumina had the best defluorination performance (94.5 mg/g), much higher than NO3- (45.0 mg/g) and Cl- (19.1 mg/g). The contribution ratio of ion exchange between SO42- and F- was as high as 20-60% in all potential defluorination mechanisms. By using Density Functional Theory calculation, the detailed mechanism revealed that the ion exchange process was mainly driven by the tridentate chelation of SO42- which reduced the exchange energy ( [Formula see text] 4.8 eV). Our study clearly demonstrated that ion exchange between SO42- and F- is a critical mechanism in defluorination using aluminum-based materials and provides a potential alternative method to enhance the adsorption performance of modified alumina.Neonicotinoid insecticides are the most widely used insecticides in the world. However, some experiments in vivo and vitro have shown association between neonicotinoids exposure and adverse effects in non-target mammals. The aims of this study were to 1) develop a robust method for simultaneous quantification of urinary neonicotinoids with a wide water solubility range by modified solid-phase extraction-ultrahigh performance liquid chromatography- tandem mass spectrometry and 2) quantify the concentrations of ten neonicotinoids in 386 adolescents in Chongqing of Southwest China by using the developed method and assess health risks of exposure to neonicotinoids. The introduction of extractive crystallization effectively removed interfering inorganic salts and improved the sensitivity of the method. The mean recoveries of all the analytes were satisfactory in the range of 89.1-104.8% and the limits of detection ranged from 0.001 to 0.02 ng/mL. The developed method was sensitive, accurate and suitable for trace detection and batch analysis in biomonitoring-based studies. Of the ten examined neonicotinoids, acetamiprid had the highest geometric mean concentration (49.43 μg/g creatinine), followed by clothianidin (5.01), imidacloprid (3.80), thiamethoxam (3.24), thiacloprid (2.25), nitenpyram (1.79), dinotefuran (1.76), sulfoxaflor (1.65), imidaclothiz (1.28) and flonicamid (1.01). High detection rates of neonicotinoids (79.3-100.0%) indicated a ubiquitous adolescents' exposure to neonicotinoids in urban areas of Chongqing. Nevertheless, hazard quotient and hazard index data exhibited a low health risk caused by the individual and cumulative exposure to neonicotinoids on the basis of the reference limit values recommended by the U.S. Environmental Protection Agency and the National Food Safety Standard of China.