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Furthermore, the radical species produced in the Vis/Ag-Fe@BAB/PDS system were identified by electron spin resonance. Finally, we demonstrated the recyclability of the Ag-Fe@BAB photocatalyst through its excellent magnetic property.In this work, ZSM-5-(C@Fe), as a peroxymonosulfate (PMS) heterogeneous activator, was synthesized, characterized, and evaluated for activating PMS to degrade ciprofloxacin (CIP) in wastewater. Zeolite Socony Mobil-5 (ZSM-5) was utilized to enhance structural stability and provided a scaffold to graft Fe doping C nanocomposites activator. Pyrolytic metal-organic frameworks (MOFs) can use crystal structure to construct stable carbon-encapsulated Fe nanocomposites. The formation of C-O-Si, C-O-Al and C-Fe was the key to the stability of catalysts. Fe doping in ZSM-5-(C@Fe) formed non-radical degradation pathway was the key to improve the degradation efficiency. The experimental data indicated ZSM-5-(C@Fe) could completely remove 20 mg L-1 CIP within 15 min and achieve good results in the experiments of treating actual wastewater, which could reduce 40% COD of the paper mill aerobic pond effluent. The Fukui function calculation and UHPL C-H RMS/MS analysis elucidated that the 1O2-dominated electrophilic reaction and the ZSM-5-(C@Fe) complex PMS-dominated nucleophilic reaction were the main pathways for CIP degradation and the radical degradation pathway (·OH and SO4-˙) plays auxiliary role. In addition, two new degradation pathways of the N29 and C27 in quinolone ring and the N22 in piperazine ring were discovered. This finding had important implications for the removal of N from organic pollutants.The increasing demand of rising population leads to the escalation of industrial sectors such as agro-, food-, paper and pulp industries. These industries generated hazardous waste which is primarily organic in nature thus is being dumped or processed in the environment. These waste leads to increasing contamination leading to increased mortality, physical and morphological changes in the organisms/animals in contact. Although the generated waste is hazardous yet it predominantly contains macromolecules and bioactive compounds thus can be efficiently utilized for the extraction and production of value added products. This article reviews the effect of these waste streams on terrestrial and aquatic ecosystems. Since these wastes abundantly contain proteins, lipids, carbohydrates and lignocelluloses thus recycling, reuse and valorization offers an effective strategy for their reduction while comforting the environment. The policies laid down by national and international agencies that directs these industries for reducing the generation of waste and increasing the recyclability and reuse of the generated waste is discussed and the gaps and bottlenecks for these is identified. This study essentially provides the state-of-art information on above aspects by identifying the gaps for future research directions and may contribute in policy development for mitigation strategies.The intumescent flame retardant (IFR) with ammonium polyphosphate (APP) as the main component has many defects in practical applications, more than that, APP can be traced to non-renewable phosphate rock resources. For the foregoing reasons, the melamine phytate supramolecular nanosheet flame retardant incorporating manganese ion (PAMA-Mn) was successfully prepared with a facile and environmental friendly hydrothermal procedure based on renewable bio-based material phytic acid (PA). The flame retardant polypropylene composite (PPI) with 13.5 wt% APP and 4.5 wt% pentaerythritol (PER) failed to the UL-94 test, and its limiting oxygen index (LOI) value was only 26.5%. After 33 wt% of APP was replaced by PAMA-Mn, the PPMn33 incorporating only 18 wt% flame retardant additives passed the UL-94 V-0 rating, and its LOI value was increased to 31.9%. Compared with PP, pHRR and pSPR values of PPMn33 were reduced by 56% and 23%, respectively. The fire retardant mechanism of PPMn33 was thoroughly discussed via a variety of characterization methods. It was found that the peak of the Gram-Schmidt curve of PPMn33 was drastically reduced by 49% relative to that of PPI, indicating a remarkably decrease of combustible volatile products owing to the incorporation of PAMA-Mn, thereby rapidly reducing the fire hazard risk.Anaerobic digestion is a promising ecofriendly technology for the management of the continuous increasing food waste (FW). However, the large amount of resulting anaerobic digestate are very difficult to be purified due to high concentration of suspended colloids. Solid-liquid separation is a pivotal step for the subsequent biological treatment of the digestate by activated sludge process. The dewaterability of digestate could directly reflect the solid-liquid separation performance. Selleckchem Olaparib In this study, a thermally-activated persulfate (PDS) conditioning method was utilized to enhance the digestate dewaterability. Results revealed that PDS thermally conditioning significantly improved the dewaterability by decreasing digestate pH and decomposing organic substances in digestate. The decline of pH, which was resulted from PDS thermally activation reaction, facilitated filterability improvement via reducing the surface negative charges and prompting the oxidizing ability of PDS-relevant radicals. Protein, the main organic component in digestate, was most closely correlated with digestate dewaterability. Fortunately, they were also the most vulnerable constituent under the oxidation attack. PDS thermal conditioning at 80°C was proven to be the most suitable for improving the solid-liquid separation performance of anaerobic. For practical application in conditioning the anaerobic digestate from FW, the conditions should be further optimized according to the digestate characteristic.Despite growing concerns regarding plastic additives, their environmental fate coupled with leaching from source materials are not well known. Styrene oligomers (SOs), which are unintended additives in expanded polystyrene (EPS), are estrogenic micropollutants. Here, we identified the effects of their potential sources (i.e., EPS buoy and its leachate) and environmental dilution on SO distribution within coastal sediments. SO content in fresh EPS particles was 0.1% (w/w), dominated by 2,4,6-triphenyl-hexene (ST-1), while 2,4-diphenyl-1-butene (SD-2) accounted for most of the SOs in EPS leachate, indicating its faster leachability. In lake and offshore environments, the SO composition profiles from their terrestrial inputs and inner sites were similar to those of EPS leachate; meanwhile, the exponentially decreasing SO concentration and increasing styrene trimers (STs) fraction with distance from the inner to outer sites were evident. These profiles indicated continuous SO leaching from their potential sources in the inland, followed by a change in SOs due to environmental dilution.