Kroghbalslev5552

Recently, combined materials and techniques have been innovatively investigated. However, the challenge remains as low purity, not only impurities in CFA but also different types of zeolites formed in one process.Structure, reactivity and physico-chemical properties of polyhalogenated compounds determine their up-take, transport, bio-accumulation, transformation and toxicity and their environmental fate. In technical mixtures of chlorinated paraffins (CPs), these properties are distributed due to the presence of thousands of homologues. We hypothesized that roles of CP dehalogenation reactions, catalyzed by the haloalkane dehalogenase LinB, depend on structural properties of the substrates, e.g. chlorination degree and carbon-chain length. We exposed mixtures of chlorinated undecanes, dodecanes and tridecanes in-vitro to LinB from Sphingobium Indicum bacteria. These single-chain CP-materials also contain small amounts of chlorinated olefins (COs), which can be distinct by mathematical deconvolution of respective mass-spectra. With this procedure, we obtained homologue-specific transformation kinetics of substrates differing in saturation degree, chlorination degree and carbon chain-length. For all homologues, two-stage first-order kinetic models were established, which described the faster conversion of reactive material and the slower transformation of more persistent material. Half-lifes of 0.5-3.2 h and 56-162 h were determined for more reactive and more persistent CP-material. Proportions of persistent material increased steadily from 18 to 67% for lower (Cl6) to higher (Cl11) chlorinated paraffins and olefins. Conversion efficiencies decreased with increasing chlorination degree from 97 to 70%. Carbon-chain length had only minor effects on transformation rates. Hence, the conversion was faster and more efficient for lower-chlorinated material, and slower for higher-chlorinated and longer-chained CPs and COs. Current legislation has banned short-chain chlorinated paraffins (SCCPs) and forced a transition to longer-chain CPs. This may be counterproductive with regard to enzymatic transformation with LinB.The potential application of silage fermentation on abandoned fresh tea leaves (AFTL) was investigated. Dynamic profiles of fermentation-related components, characteristic components and the bacterial community of AFTL during ensiling were analysed. The results showed that after ensiling for 60 days, the concentrations of lactic, acetic and propionic acid increased, whereas a high pH value (4.80) and NH3-N content (106 g/kg TN) were detected. Characteristic components, including caffeine, polyphenols, theanine and catechins, were well preserved. The microbial community changed significantly, and Lactobacillus (63.6%) became the dominant phylum. Spearman rank correlation revealed a positive correlation between lactic acid concentration and the abundance of Lactobacillus (63.6%) and Klebsiella (25.0%), whereas the abundance of Klebsiella was negatively correlated with catechin concentration. In conclusion, ensiling could be an effective utilization for AFTL and provides a new idea for utilizing idle resources on tea plantations.Compared with the Z-scheme and type-II heterojunctions, p-n type heterojunctions are more favorable for the migration of photo-induced carriers owing to the advantage of built-in electric fields. In addition, it is still of great significance to understand the carrier migration properties of the p-n heterojunction. Therefore, the development of new p-n heterojunctions and the development of high-efficiency catalysts with effective modulation of light responsiveness and rapid transfer of charge to achieve photocatalytic inactivation have attracted much attention. In this study, we synthesized a Ag2S/g-C3N4 heterojunction via the in situ deposition of Ag2S onto the g-C3N4 substrate. The prepared Ag2S/g-C3N4 composite facilitated photo-generated charge carrier transfer and exhibited outstanding photocatalytic inactivation of bacteria compared to that of a single catalyst under visible light irradiation. In addition, the ACN-2 composites fully deactivated 7 log10 CFU/mL E. coli and 7 log10 CFU/mL S. aureus cells in 90 min under visible light. The quenching experiments confirmed that photo-generated active species (O2-, OH, and h+) were the major reactive oxygen species that contributed to the inactivation of bacteria. Energy band alignment analysis indicated that a type-II band alignment was formed in the p-n heterostructure, thereby providing strong support for the photocatalytic mechanism. This study not only provides insights into the design of p-n heterostructures, but also presents a promising strategy to enhance the photocatalytic capacities of g-C3N4 based materials for pathogen inactivation.Hydrofluorocarbons (HFCs) are widespread alternatives for the ozone-depleting substances chlorofluorocarbons and hydrochlorofluorocarbons. They are used mainly as refrigerants or as foam-blowing agents. HFCs do not deplete the ozone layer, but they are very potent greenhouse gases, already contributing to global warming. Since 2019 HFCs are regulated under the Kigali Amendment to the Montreal Protocol, which demands reliable emission estimates to monitor the phase-down. Quantification of emissions is performed with two methods bottom-up from product inventories or data on chemical sales; or top-down, inferred from atmospheric measurements by inverse modelling or interspecies correlation. Here, we review and compare the two methods and give an overview of HFC emissions from different parts of the world. Emission estimates reported by the different methods vary considerably. HFC emissions of developed countries (Annex I) are reported to the United Nations Framework Convention on Climate Change. These bottom-up estimates add up to only half of global emissions estimated from atmospheric data. Several studies with regional top-down estimates have shown that this gap is not owed to large-scale underreporting of emissions from developed countries, but mostly due to emissions from developing countries (non-Annex I). China accounts for a large fraction of the emissions causing the gap, but not entirely. Bottom-up and top-down estimations of emissions from other developing countries that could identify other large emitters are largely unavailable. Telotristat Etiprate inhibitor Especially South America, West-, Central- and East-Africa, India, the Arabian Peninsula and Northern Australia are not well covered by measurement stations that could provide atmospheric data for top-down estimates.The Stoppani factory manufactured chromium for more than one century, dumping millions of tons of Chromite Ore Processing Residues (COPRs) over decades. The massive presence of COPRs resulted in an intense CrVI leaching and consequent contamination of percolating groundwater. link2 The site offers a unique opportunity to follow COPRs evolution from the primary roasting process to the aged Cr-bearing mineral phases. link3 Herein, new insights on COPRs mineralogy evolution and their role in CrVI release are provided by a dry sample preparation protocol, coupled with in-depth multi-technique characterization. Besides typical COPRs mineral assemblages, highly soluble Na2CrO4 and the first evidence of crocoite (PbCrO4) in a COPR contaminated site are revealed. Selective extraction experiments confirmed a strong reactivity for Cr-bearing minerals as confirmed by concentrations as high as 375 mg L-1 of leached CrVI. The mineralogical approach was combined with a nanotechnological solution for CrVI wastewater remediation. The application of naked colloidal maghemite (γ-Fe2O3) nanoparticles (SAMNs) on the complex industrial wastewater, led to > 90% CrVI removal, either under acidic or in-situ conditions. The present case study of a highly polluted site, ranging from mineral characterization to wastewater remediation, highlights the use of multidisciplinary approaches to cope with complex environmental issues.Aerosol (PM10), bulk deposition, sea surface microlayer (SML) and underlying water (ULW) samples were collected simultaneously during a field campaign at the middle Adriatic coastal site between February and July 2019, to assess the impact of atmospheric deposition (AD) of biologically relevant trace metals (TM) (Zn, Cu, Co, Ni, Cd and Pb) on the sea surface responses in an oligotrophic coastal region. Anthropogenic emissions from continental Europe, alongside local/regional domestic heating, likely affected the concentrations of Zn, Cd and Pb in aerosols during winter-early spring, while traffic emissions during the tourist season impacted Ni, Co and Cu aerosol concentrations. Additionally, open-fire biomass burning (BB) episodes caused considerable TM concentration increases, while Saharan dust intrusion in spring led to a 10-fold increase in Co concentrations in PM10 samples. These intensive episodes significantly affected the bulk deposition fluxes of TMs, showing that a small number of such extreme events, common to Mediterranean coastal areas, could be responsible for most of the AD. Enrichments and concentrations of total TMs in SML samples collected following BB events indicated that such events, along with high precipitation, influenced TM partitioning in surface water layers. We estimated that AD represents a significant source of TM to the shallow middle Adriatic coastal area, highlighting the need to further explore the atmosphere-sea surface links, to expand our understanding of the biogeochemistry of these important micronutrients and pollutants, including their impact on the aquatic community.The aquatic environment may represent an essential route for transmission of antibiotic resistance to opportunistic human pathogens. Since industrial wastewater is discharged into the river after treatment, understanding the distribution of antibiotic resistance genes (ARGs) in river systems and the possibility of pathogens acquiring antibiotic resistance are challenges with far-reaching significance. This work mainly studied distribution profiles of pathogens and ARGs, and compared their health risk in various industrial wastewater with that of river water. Results showed that 166 pathogens were concurrently shared by the six water samples, with Salmonella enterica and Pseudomonas aeruginosa being the most abundant, followed by Fusarium graminearum and Magnaporthe oryzae. The similar composition of the pathogens suggests that pathogens in river water may mainly come from sewage discharge of slaughterhouses and that changes in water quality contribute significantly to the prevalence of these pathogens. Of the 57 ARG types detected, bacitracin was the most abundant, followed by sulfonamide, chloramphenicol, tetracycline, and aminoglycoside. Strikingly, the wastewater from a pharmaceutical factory producing Chinese medicine was also rich in bacA, sul1, mexW, mexB, mexF and oprn. It can be seen from the co-occurrence patterns that pathogens and the main ARGs have strong co-occurrence. Higher abundance of offensive virulence factors in industrial wastewater and their strong correlation with pathogens containing ARGs suggest higher microbiological risk. These findings highlight the need to assess ARG acquisition by pathogens in the surface water of human-impacted environments where pathogens and ARGs may co-thrive.