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Furthermore, the limitations of current spectroscopic approaches for the exploration of NOM-related environmental processesand how these weaknesses/drawbacks can be addressed are explored. Finally, suggestions and directions are proposed to advance the development of spectroscopic methods in analyzing and elucidating the properties and behaviors of NOM in natural and engineered environments.Interests in the kinetics of radical-induced reactions in aqueous solution have grown remarkably due to their water engineering significance (e.g., advanced oxidation processes). Although compilations of the rate constants (k) for various radicals have been documented, surprisingly a systematic review has yet to be reported on the development of reliable methods for determining k values. A knowledge gap exists to critically evaluate and screen the various methods to measure them. In this review, we summarize the direct and indirect methods under steady-state and non-steady-state conditions, followed by critical evaluations on their advantages and disadvantages. The radicals of ·OH, [Formula see text] , [Formula see text] , and Cl· were chosen based on their significant aquatic environmental relevance. MS excel spreadsheets that demonstrate the determination processes were provided allowing one to reproduce the data and/or to analyze the unprocessed raw data as a "template". We formulated a standard operation procedure for the k determination, although there is simply no "versatile" method fitting for all radical reactions. Finally, existing challenges and future research focus are discussed. This is the first review covering methodological approaches and considerations, aiming to provide a holistic and fundamental basis to choose an appropriate method for determining the k values for bimolecular reactions between target compounds and radicals in the aqueous phase.The application of granular biomass has enabled energy efficient, high-rate wastewater treatment systems. While initially designed for high-strength wastewater treatment, granular systems can also play a major role in resource recovery. This study focused on the formation of purple phototrophic bacteria (PPB) granular biomass during synthetic wastewater treatment. selleck chemicals llc Liquid upflow velocity was applied as the driving force for granulation. Separate reactors were operated at either low (2-5m h-1) or high (6-9m h-1) upflow velocities, with sludge retention times (SRTs) ranging from 5-15d. Reactors produced anaerobic, photo-granules within ~50d. The sludge volume index (SVI30) of the granules was 10mL g-1 and average settling rates were greater than 30m h-1, both metrics being similar to existing granular technologies. Granule sizes of 2-3mm were recorded, however the particle size distribution was bimodal with a large floc fraction (70-80% volume fraction). The extracellular polymeric substance (EPS) and alginate-lr biomass on synthetic wastewater suggests methods for resource recovery using PPB can be diversified to also include granular biomass.Anaerobic digestion of organic waste and wastewater represents an attractive sustainable bio-technology to produce methane as an alternative to fossil energy. In response to improvement of methane production via enhancing methanogenesis, current strategies of the addition of external biological/non-biological materials have to confront either the loss of materials, high cost and/or possible destruction of the microbial community. Here, we report the first case of using immobilized fungi Aspergillus sydowii 8L-9-F02 to optimize the microbial community, achieving remarkable improvement of the methane production in both batch test (1.5 times) and continuous flow operation (1.13-1.31 times). The crucial role of fungi is associated with the stimulation of enrichment of Methanosaeta and Methanobacterium for methanogenesis from 28.2 to 67.4% as well as the improved activity of enzyme F420. Moreover, fungi also increase the content of extracellular polymeric substances, facilitating the formation of bio-aggregates. This work provides a new pathway to enhance methanogenesis during anaerobic digestion of wastewater by using fungi as bio-enhancer.Polydopamine has high adsorption capacities for pollutants such as pesticides in food and environmental matrices. Consequently, it has found applications in some sorbent-based micro-extraction techniques such as solid phase micro-extraction and magnetic solid phase extraction. This paper gives a detailed review of the application of polydopamine-based adsorbents for the extraction of pesticides in food and environmental matrices using these techniques. The adhesive properties of polydopamine have made it to be a suitable material for the immobilisation of the components of electrochemical sensors used to detect pesticides in food and environmental matrices. This paper also gives a comprehensive review on the application of polydopamine in electrochemical sensors such as acetylcholinesterase sensors, molecularly imprinted sensors and aptasensors. The use of polydopamine-based adsorbents during the extraction and electrochemical sensing of pesticides in food and environmental matrices is not free of challenges. In this review, the challenges encountered during the use of polydopamine-based adsorbents are also discussed.Hyperemesis gravidarum (HG) is characterised by extreme nausea and vomiting of pregnancy, which can lead to dehydration, weight loss and electrolyte disturbances. Historically research has been challenging due to a lack of diagnostic criteria and objective outcome measures. Most studies in this population group have focused on medical management of symptoms, with little known about the effect of HG on nutritional intake and how this relates to perinatal outcomes. The aim of this study was to synthesise current knowledge of the dietary intake of women with HG. A systematic search of search engines was conducted in April 2020 using the following databases MEDLINE, Embase, CINAHL, Cochrane database, Scopus, NHS Evidence, BNI, Emcare, ClinicalTrials.gov, PROSPERO, Ethos and Open Grey. Titles and abstracts were screened independently by two reviewers against predefined inclusion and exclusion criteria. Studies were included where the authors described severe pregnancy nausea and vomiting as HG, regardless of how HG was defined.