Kamppage9298

Spatio-temporal distributions and bioaccumulation characteristics of freshwater cyanobacterial toxins, such as microcystins (MCs) in the Geum River Estuary, South Korea, were investigated during summer. Environmental multimedia samples (water, suspended particulate matter (SPM), and sediments) and tidal flat organisms (polychaetes, decapods, amphipods, and bivalves) were collected from regions inside and outside of the estuary dam for MCs analysis. Phytoplankton communities in the Geum River (freshwater) and estuarine area (brackish water) were also analyzed in order to understand the relationship with MCs concentrations. Seasonal variation in the structure of phytoplankton communities was detected in the Geum River, with a relatively high density of Cyanophyta in summer. MC concentrations were strongly correlated to water temperature, chlorophyll a, and cyanobacterial density. MC-LR was the most abundant MC variants in environmental samples. Dissolved MCs remained for longer periods and were more widely distributed in the coastal environments compared to particulate MCs. The distribution coefficients between water and SPM (Kd-SPM) and between water and sediments (Kd-sediment) of MCs showed that the phase shift of MCs in the environmental samples occurred in the estuary. Kd-SPM declined from the inside to outside regions of the estuary dam, and was mainly attributed to differences in the half-lives of MCs in dissolved (4.7 d for MC-LR) and particulate phases (0.44-0.52 d for MC-LR). Species-specific bioaccumulation of MCs occurred in tidal flat organisms, with relatively high bioaccumulation factors of MCs being detected in polychaetes and decapods compared to amphipods and bivalves. Overall, this study advances our understanding on the distribution, transport, fate, and bioaccumulation of MCs in estuarine and coastal environments.Yellow River Delta (YRD) is one of the youngest delta with complex hydrological and biological connectivity in the world, where offers habitats to the famous waterfowls in the Eastern Asia. Meanwhile, one specific ecological restoration project named as the "Wuwanmu" and followed by the "Shiwanmu" within the National Nature Reserve of the Yellow River Delta (NNRYRD) complicated the hydrological and biological connectivity. How to quantitatively evaluate the extent of coastal wetland affected by the project will be a difficult problem. Hence the authors presented three innovative models of the Marine Connectivity Change Index (MCCI), the Coupling Index of Hydro-biological Connectivity (CIHBC), and the Assessment Index of Suitability on Bird Habitats (AISBH). After the project, the habitat of Phragmites australis has been restored effectively with the increased area of 24.59%, while the habitat of Suaeda salsa as the native species lost largely with decreased area of 84.62%. And the tidal channel having been cut off by the project resulted in isolating the buildup restoration area from seawater, and reshaping completely the plant habitat environment. So the hydrological and biological connectivity has been changed largely with the 47.79% decreased MCCI area and the 16.3% decreased zero-valued CIHBC area. However the AISBH non-zero-valued area increased 10.7%, and with the hidden worry of the decreased Grallatores number. From the connectivity prospective, three models presented a significant methodology to evaluate the complex impact on the estuary wetland habitat caused by the restoration project. In the long run, the ecological impacts should be highlighted to the change of tidal channel and the corresponding tidal issues, and the continuous and big loss of native plant spices such as S. salsa. The further study needs to explore the longer-term assessment of the ecological restoration project and its multiple effect in the future.While the importance of extreme conditions is recognised, patterns in species' abundances are often interpreted through average environmental conditions within their distributional range. For marine species with pelagic larvae, temperature and phytoplankton concentration are key variables. Along the south coast of South Africa, conspicuous spatial patterns in recruitment rates and the abundances of different mussel species exist, with focal areas characterized by large populations. We studied 15 years of sea surface temperature (SST) and chlorophyll-a (chl-a) satellite data, using spectral analyses to partition their temporal variability over ecologically relevant time periods, including seasonal (101 to 365 days) and intra-seasonal cycles (20 to 100 days). Adult cover and mussel recruitment were measured at 10 sites along the south coast and regression models showed that about 70% of the variability in recruitment and adult cover was explained by seasonal variability in chl-a, while mean annual chl-a and SSTropogenic forcing.Microorganisms were observed to facilitate cathodic oxygen reduction and enhance cathode performance of microbial fuel cells (MFCs). However, the long-term activity and stability of bio-catalyzed cathode needs to be explored. This study evaluated the long-term performance of bio-catalyzed cathode and iron(II) phthalocyanine (FePc)-catalyzed cathode MFCs through effluent water quality, electricity production and electrochemical impedance spectroscopy (EIS) analysis under different scenarios, including conventional wastewater treatment and energy harvesting using a power management system (PMS). During the continuous operation, both systems demonstrated high chemical oxygen demand and ammonium removal, but bio-catalyzed cathode MFCs could achieve significantly better total nitrogen removal than FePc-catalyzed cathode MFCs. The FePc-coated cathode showed constant cathode potential during the entire operation period, but the biocathode showed varied but step-wise increased cathode potential to achieve more than 500 mV versus the standard hydrogen electrode, likely due to the gradual enrichment of biocathode biofilm. EIS analysis revealed that biocathode had higher ohmic resistance than bare carbon felt cathode but the microbial biofilm could largely decrease polarization resistance of cathode material. Microbial community analysis has shown the presence of nitrifying and denitrifying bacteria in the bio-catalyzed cathode biofilm. When connecting PMS, both bio-catalyzed cathode and FePc-catalyzed cathode MFCs successfully charged a capacitor, but the bio-catalyzed cathode MFC voltage significantly dropped to less than 100 mV after charging for 91 h, and gradually recovered when disconnecting PMS. This study has demonstrated the potential application of oxygen reduction bio-catalyzed cathode MFCs for continuous wastewater treatment and energy harvesting for long period of time.Halimione portulacoides plants were exposed to dissolved cerium (Ce) in a hydroponic medium for five days. Ce accumulation in plants followed the metal's increase in the medium although with a very low translocation factor (TF less then 0.01) between roots and shoots. Ce median concentrations in roots were 586, 988 and 1103 μg/g (dry wt.), while in shoots the median values reached 1.9, 3.5 and 10.0 μg/g (dry wt.), for plants exposed to 300, 600 and 1200 μg/L of Ce, respectively. No significant differences occurred in the length of roots and shoots among treatment groups, albeit plants exposed to the highest Ce concentration showed a clear loss of turgor pressure on the fifth day. An increase of hydrogen peroxide and malondialdehyde levels were observed in the plant shoots at 1200 μg/L of Ce. The highest concentration also triggered an answer by the shoots' antioxidant enzymes with a decrease in the activity of superoxide dismutase and an increase in peroxidase. However, no significant change in catalase activity was observed, compared to the control group, which may indicate that peroxidase played a more crucial role against the oxidative stress than catalase. Combined results indicate that H. portulacoides was actively responding to a toxic effect imposed by this higher Ce concentration. Nevertheless, changes in normal environmental conditions, may increase the bioavailability of Ce, while in areas where acid mine drainage may occur, the highest Ce concentration tested in this study may be largely exceeded, placing the sustainability of halophytes and estuarine marshes at risk.The modified Al-MCM-41 solid acids with turning Si/Al molar ratio were successfully fabricated through a hydrothermal route and utilized as a suitable catalyst in the cellulose conversion into 5-hydroxylmethylfurfural (5-HMF). The crystal structure, composition, morphologies and porosity of as-synthesized acids were characterized by XRD, FT-IR, N2 adsorption-desorption, TEM and EDS. The 27Al MAS NMR and 29Si-MAS NMR results revealed the existence of both Al framework and Al extra framework. Besides, the existence of medium-weak and strong acid sites, according to Brønsted and Lewis acidity, in Al-MCM-41 acids was confirmed by NH3-TPD and FTIR-pyridine adsorption. The 30Al-MCM-41 solid acid (Si/Al molar ratio = 30) exhibited excellent activity with the highest 5-HMF yield of 40.56% compared to other samples. We also discovered that 5-HMF production, as well as cellulose conversion, strongly depended on the total acid, strong/medium-weak acid ratio, as well as Brønsted/Lewis acid ratio. Therefore, these parameters have been considered as essential factors for the design of solid acid for 5-HMF production.The liver of anurans play an important role in metabolism, including detoxification, the biotransformation of molecules, and the storage of metabolites. Surfactants are part of domestic and industrial effluents. The effects of linear alkylbenzene sulfonate (LAS) on anuran liver remain unknown, however, some studies have evaluated the effects of LAS on the skin, gills, heart, testes, and liver of fishes. Here, we tested the hypothesis that LAS is hepatotoxic, promoting morphometric alterations in hepatocytes along with inflammation in the tissue, altering hepatic catabolism. We evaluated the effects of a LAS concentration that is considered environmentally safe in Brazilian inland waters on the liver of Lithobates catesbeianus tadpoles, including studies on morphology, morphometry, immunology, and metabolism. find more LAS exposure promoted enlargement of liver sinusoids and vacuolization of hepatocytes. Exposure to LAS also increased the area of mast cells and melanomacrophages (MMs). Additionally, LAS exposure increased hemosiderin inside MMs, suggesting alterations in the catabolism and storage of iron. Hepatocyte size increased after exposure to LAS, suggesting cytotoxic effects. Integrative analyses (i.e., morphometric, metabolic, and immunological) demonstrated hepatotoxic effects of LAS. These types of studies are key to understanding the negative effects of these substances on tadpole health, as these liver alterations impair anuran homeostasis.This study analyzes the 137Cs behavior in the ponds of Okuma Town from 2015 to 2019 in the Fukushima Dai-ichi nuclear power plant (FDNPP) exclusion zone. A decline in both particulate and dissolved 137Cs activity concentrations was revealed. The decline rate constants for the particulate 137Cs activity concentration were found to be higher than for the dissolved 137Cs activity concentration. In terms of seasonality the dissolved 137Cs concentrations were higher from June to October, depending on the specific pond and year, most likely due to temperature dependence of 137Cs desorption from frayed edge sites of micaceous clay minerals. The apparent Kd(137Cs) in the studied ponds, in absolute value, appeared to be much higher than that for closed and semi-closed lakes of the Chernobyl contaminated area; however, these were comparable to the values characteristic of the rivers and reservoirs of the FDNPP contaminated area. The apparent Kd(137Cs) in the suspended sediment-water system was observed to decrease over time.