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Cadmium (Cd) contamination arising from industrialization has attracted increasing attention in recent years. Reductive soil disinfestation (RSD) as an effective agricultural practice has been widely applied for soil sterilization. However, there is little research regarding RSD affecting Cd immobilization. Here, five treatments, namely untreated soil (CK), flooding-treated soil (FL), RSD with 2% ethyl alcohol (EA), 2% sugarcane bagasse (SB), and 2% bean dregs (BD) were designed to detect their performance for Cd immobilization in contaminated soils, and the change of soil properties and microbial communities were monitored. The results revealed that pH significantly increased in FL and RSD-treated soils, but was negatively correlated with the exchangeable fraction of Cd (EX-Cd), while Oxidation-Reduction Potential (Eh) significantly decreased in FL and RSD-treated soils, and was positively correlated with EX-Cd. BD treatment might contribute to the increase of CaCO3 as shown by X-Ray Diffractomer analysis anposition of the microbial community.Tea polyphenols are the most widely distributed class of secondary metabolites (Camellia sinensis) and account for a considerable proportion of the pruning residues of tea. A large amount of tea polyphenols have fallen down over soil with prunning residues every year. However, the effect of tea polyphenols on soil nitrogen cycle, especially the denitrification process and its related microbial communities, remains unclear. Epigallocatechin gallate (EGCG), the most abundant component of tea polyphenols, was selected to simulate the effects of tea polyphenols on soil nitrification, denitrification, related functional genes and microbial community. The results indicated that addition of EGCG can significantly (p less then 0.05) inhibit soil nitrification. Copy numbers of bacterial and archaeal ammonia monooxygenase genes (amoA) decreased as EGCG concentration increased. Further, the ammonia oxidisers exhibited a significantly (p less then 0.05) greater niche differentiation under the effect of EGCG compared vironmental risks caused by unreasonable nitrogen fertiliser adaptation.On December 13, 2019, the Yale School of Public Health hosted a symposium titled "Per- and Polyfluoroalkyl Substances (PFAS) Challenges and Opportunities" in New Haven, Connecticut. The meeting focused on the current state of the science on these chemicals, highlighted the challenges unique to PFAS, and explored promising opportunities for addressing them. It brought together participants from Yale University, the National Institute of Environmental Health Sciences, the University of Massachusetts Amherst, the University of Connecticut, the Connecticut Agricultural Experiment Station, the Connecticut Departments of Public Health and Energy and Environmental Protection, and the public and private sectors. Presentations during the symposium centered around several primary themes. The first reviewed the current state of the science on the health effects associated with PFAS exposure and noted key areas that warranted future research. As research in this field relies on specialized laboratory analyses, the seconds. In doing so, it bolstered the State of Connecticut's efforts to implement the ambitious initiatives that its PFAS Action Plan recommends.Urban wastewater treatment plants (WWTP) are a major vector of highly ecotoxic contaminants of emerging concern (CECs) for urban and sub-urban streams. Ecotoxicological risk assessments (ERAs) provide essential information to public environmental authorities. Nevertheless, ERAs are mainly performed at very local scale (one or few WWTPs) and on pre-selected list of CECs. To cope with these limits, the present study aims to develop a territorial-scale ERA on CECs previously identified by a "suspect screening" analytical approach (LC-QToF-MS) and quantified in the effluents of 10 WWTPs of a highly urbanized territory during three periods of the year. Among CECs, this work focused on pharmaceutical residue and pesticides. ERA was conducted following two complementary methods (1) a single substance approach, based on the calculation for each CEC of risk quotients (RQs) by the ratio of Predicted Environmental Concentration (PEC) and Predicted No Effect Concentration (PNEC), and (2) mixture risk assessment ("cocktail effect") based on a concentration addition model (CA), summing individual RQs. Chemical results led to an ERA for 41 CEC (37 pharmaceuticals and 4 pesticides) detected in treated effluents. Single substance ERA identified 19 CECs implicated in at least one significant risk for streams, with significant risks for DEET, diclofenac, lidocaine, atenolol, terbutryn, atorvastatin, methocarbamol, and venlafaxine (RQs reaching 39.84, 62.10, 125.58, 179.11, 348.24, 509.27, 1509.71 and 3097.37, respectively). Mixture ERA allowed the identification of a risk (RQmix > 1) for 9 of the 10 WWTPs studied. SANT-1 price It was also remarked that CECs leading individually to a negligible risk could imply a significant risk in a mixture. Finally, the territorial ERA showed a diversity of risk situations, with the highest concerns for 3 WWTPs the 2 biggest of the territory discharging into a large French river, the Rhône, and for the smallest WWTP that releases into a small intermittent stream.Fine particulate matter with aerodynamic diameters less than 2.5 μm (PM2.5) poses adverse impacts on public health and the environment. It is still a great challenge to estimate high-resolution PM2.5 concentrations at moderate scales. The current study calibrated PM2.5 concentrations at a 1 km resolution scale using ground-level monitoring data, Aerosol Optical Depth (AOD), meteorological data, and auxiliary data via Random Forest (RF) model across China in 2017. The three ten-folded cross-validations (CV) methods including sample-based, time-based, and spatial-based validation combined with Coefficient Square (R2), Root-Mean-Square Error (RMSE), and Mean Predictive Error (MPE) have been used for validation at different temporal scales in terms of daily, monthly, heating seasonal, and non-heating seasonal. Finally, the distribution map of PM2.5 concentrations was illustrated based on the RF model. Some findings were achieved. The RF model performed well, with a relatively high sample-based cross-validation R2 of 0.74, a low RMSE of 16.29 μg × m-3, and a small MPE of -0.282 μg × m-3. Meanwhile, the performance of the RF model in inferring the PM2.5 concentrations was well at urban scales except for Chengyu (CY). North China, the CY urban agglomeration, and the northwest of China exhibited relatively high PM2.5 pollution features, especially in the heating season. The robustness of the RF model in the present study outperformed most statistical regression models for calibrating PM2.5 concentrations. The outcomes can supply an up-to-date scientific dataset for epidemiological and air pollutants exposure risk studies across China.Rivers are significant sources of CO2 to the atmosphere, and karstic watersheds are particularly important in this respect due to their large availability of inorganic carbon. This study examines characteristics of dissolved inorganic carbon (DIC) and excess partial pressures of CO2 (epCO2) in the source springs and headwaters of four watersheds in a Central European karstic region, via dissolved inorganic carbon concentration and stable carbon isotope measurements. Our results show the most 13C-depleted δ13CDIC values at the source springs, which become rapidly enriched downstream due to CO2 degassing. Concurrently, epCO2 values, while consistently in excess of atmospheric concentrations at the spring sources, show decreases of up to 92% within only 50 m downstream distance. In conjunction with the large observed flux estimates of up to 88 g C m-2 day-1, these findings suggest that karstic springs are major CO2 sources to the atmosphere. Because headwater streams constitute the bulk of the surface area of most watersheds, they may provide a disproportionately large contribution to CO2 effluxes in carbonate-dominated basins, in which source springs play a particularly important role.Bioretention systems are popular low impact development stormwater management features designed to remove pollutants, including phosphorus (P), from urban stormwater runoff. While the performance of bioretention systems in retaining P has been well studied, seasonal variability of P retention in field-scale systems installed in cold climates, including the influence of high road de-icing salt (sodium chloride) inputs, remains unclear. Two large field-scale bioretention systems installed in London, Ontario, Canada were monitored over their initial operational period to evaluate the seasonal trends in the retention of different forms of P in bioretention systems and the impact of high salt loading. Over the 12-month monitoring period, a net retention of total P and dissolved organic P, and a net release of soluble reactive P and total dissolved P mass were observed. Reduced hydrological performance and increased effluent P concentrations resulted in high P release from the bioretention systems in early to mid-spring (March and April), with most release occurring during a few individual large precipitation events. link2 Laboratory-scale column experiments were performed using the engineered soil media installed in the field-scale bioretention systems to isolate the effect of high salt loading on P release. Column experiments combined with field data indicate that prolonged high salt loads through winter and spring may have contributed to elevated spring P release, mostly in the form of soluble reactive P, from the field-scale bioretention systems. Findings from this study are needed to better understand the performance of bioretention systems with respect to P retention as required to improve urban stormwater management in cold climates. Results have implications for further investigations of the impact of road salt on P mobility in bioretention systems and more broadly in roadside soils and groundwater systems.The development of inexpensive and efficient heterogeneous catalyst for the conversion of biomass including food and winery processing waste to value-added products is crucial in biorefinery. Glucose could be obtained via the hydrolysis of waste cellulose or starch-rich material, and the isomerization of glucose to fructose using either Lewis acid or Brønsted base catalysts is an important route in biorefinery. link3 As a natural clay mineral, bentonite (Bt) is widely used as adsorption material and catalyst support, but how its intrinsic acid-base properties can impact the biomass conversion chemistry is still rarely reported. In this study, we investigated the influence of the textural and acid-base properties of Bt on the glucose isomerization reaction. The reaction kinetics and mechanism, and the effect of Al3+-exchange were explored. The results showed that the activation energy of Bt-catalyzed glucose conversion was 59.0 kJ mol-1, and the in-situ Fourier transform infrared spectrometer (FT-IR) characterization proved that Brønsted base was responsible for the isomerization. The highest fructose yield of 39.2% with 86.3% selectivity could be obtained at 110 °C for 60 min in water. Alkaline rinse and calcination can recover most of the catalytic activity of the spent catalyst.