Iveykryger1870

Soil adsorbed and inactivated approximately 99% of total Cu2+. Only 1% of total Cu2+ was the toxic exchangeable fraction, of which the concentrations were 0.73, 0.23, and 0.22 mg kg-1 in the surface (0-3 cm), middle (3-6 cm), and bottom (6-11 cm) layers, respectively. The abundance of 16S rRNA gene transcripts of exoelectrogenic bacteria-associated genera is the lowest in the surface layer (2.86 × 1011 copies g-1) and the highest in the bottom layer (7.99 × 1011 copies g-1). Geobacter, Clostridium, Anaeromyxobacter, and Bacillus are the most active exoelectrogenic bacteria-associated genera in the soil. This study suggests that the SMFC sensor could be applied in wetlands to monitor the repeated discharge of Cu2+ and other heavy metals.Drip irrigation is an effective water-saving strategy for crop production in arid regions. However, limited information is available on how fertilizer nitrogen (N) management affects soil nitrous oxide (N2O) emission under drip irrigation. A two-year (2017-2018) field experiment was conducted in arid northwestern China to test management options of fertilizer N to reduce N2O emission and improve NUE of cotton (Gossypium hirsutum L.) under drip irrigation. Treatment included a factorial design of rate (120, 240 kg N ha-1) and source of N fertilizer (Urea, polymer-coated urea-ESN, stabilized urea with nitrification and urease inhibitors-SuperU), and an unfertilized Control. Urea was split-applied with irrigation water (fertigation) whereas ESN and SuperU were all side-banded at pre-plant. Crop yield and N uptake, soil mineral N concentrations, soil temperature and moisture, and N2O fluxes were determined. Across the two growing seasons, a single pre-plant application with ESN or SuperU significantly increased growing season cumulative N2O emissions (ƩN2O) by 29-47% and applied N-scaled emission factor (EF) by 57-83% compared to urea fertigation, irrespectively of application rate. In contrast, cotton yield, agronomic NUE, apparent N recovery (ANR), and yield-based N2O emission intensity (EI) were not affected by N source. Reducing N rate from 240 to 120 kg N ha-1 significantly decreased ƩN2O by 35% in 2017 and 36% in 2018 while simultaneously reduced cotton yield in both years. Bcl-2 expression The increased N2O emissions with ESN and SuperU were attributed to greater availability of inorganic N resulted from one-time application at pre-plant and higher soil temperature. We concluded that fertigation with urea at the recommended rate is the best option to ensure agronomic productively and agronomic NUE with minimal risk of N2O emissions. In contrast, the benefit of enhanced efficiency N fertilizer is limited and recommendation on using of these products is challenging for arid croplands under drip irrigation.The dispersities of goethite nanoparticles (GTNPs) and ferrihydrite nanoparticles (FHNPs) affect the transport and retention of nanoparticle-associated contaminants. However, the effects of interaction on nanoparticle stability under varying environmental conditions have not been previously investigated. This study utilized settling experiments, a semi-empirical model, and the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory to study the homo-aggregation and hetero-aggregation of GTNPs and FHNPs. The pure system of GTNPs tended to aggregate more easily than that of FHNPs, especially under the conditions of high pH (7.0-9.0), high ionic strength (IS, 10 mM), and low concentrations of humic acid (HA) (2 mg L-1). This aggregation was attributed to the elongated morphology of GTNPs, which contributed to surface heterogeneity. The GTNPs and FHNPs mixtures rapidly coagulated, particularly under the surface-charge disequilibrium caused by an increase in negative charges or IS. Hetero-aggregation increased with increase in the GTNPs ratio, indicating that the elongated GTNPs dominated the coagulation of the Fe mineral nanoparticle mixture, which was attributed to the surface heterogeneity and high probability collisions between the GTNPs. Although DLVO neglects the influence of heterogeneity on the nanoparticle surfaces, SEM revealed that hetero-aggregation of GTNPs and FHNPs occurred. The results obtained in this study provide novel and valuable insights into the behaviors of GTNPs and FHNPs mixtures and suggest that during the gradual transformation of FHNPs to GTNPs in soil or aquatic environments, the hetero-aggregation of GTNPs and FHNPs may be enhanced, thus promoting contaminant immobilization.The objective of this work was to relate PM2.5 Oxidative Potential (OP) data to PM composition and PM local and distant source contributions. PM2.5 collected in Dunkerque, a coastal industrial city in North of France, was extensively characterized for major and minor chemical species. PM2.5 filters were extracted using a synthetic pulmonary fluid to achieve OP estimation based on Ascorbic Acid (AA) and dithiothreitol (DTT) depletion assays. In order to evidence relationships between OP values, chemical composition and local and distant source contributions, correlation coefficient, Principal Component Analysis (PCA), concentration roses, polar plots and concentration weighted trajectories were used. Heterogeneous conclusions were drawn using the three first methods as the bivariate polar plots lead to dismiss some of the correlations evidenced using correlation coefficient and PCA. Both AA and DTT tests appeared complementary as they were not sensitive to the same species/source contribution. The bivariate polar plot representation of OP values versus wind direction and wind speed revealed that PM2.5 concentration and combustion sources were linked to OP-AA, whereas emissions from integrated steelworks, electric steelworks, heavy fuel oil combustion and traffic non-exhaust significantly contribute to OP-DTT. Sea-salts, aged sea-salts, crustal, secondary sulfates and secondary nitrates sources were not found to contribute to OP values. Constant weighted trajectories evidenced several source regions responsible for high OP values with Belgium, Germany, Netherlands and France at the leader position. Contribution of inland regions appeared possibly related to the biomass and traffic related combustion while heavy fuel oil combustion could also be involved in the contribution of marine and coastal areas.