Iqbaljakobsen5233

Brownian dynamics simulation results confirm the experimental observations and also illustrate helical structures formed by squares packing on cylinders. Our results demonstrate a way towards control over the self-assembly of anisotropic particles through curvature and depletion-attraction-induced orientational confinement.

10.9L, but a tetratic phase is seen instead for the 10.9L tube at the corresponding platelet area fractions. We show that this transition is caused by the curvature-induced orientation-dependence of the depletion attraction between the squares and the underlying cylindrical surface. Brownian dynamics simulation results confirm the experimental observations and also illustrate helical structures formed by squares packing on cylinders. Our results demonstrate a way towards control over the self-assembly of anisotropic particles through curvature and depletion-attraction-induced orientational confinement.Photodynamic therapy (PDT) of tumor has achieved good results, but the treatment efficiency is not high due to the lack of effective photosensitizers and tumor hypoxia. In this study, iridium dioxide nanoparticles (IrO2 NPs) with excellent photothermal/photodynamic effects and catalase like activity were synthesized by a simple method. The combination of glucose oxidase (GOx) and IrO2 NPs is formed by hyaluronic acid (HA), which have the activities of glucose oxidase and catalase, can target tumor sites and form in situ amplifiers in tumor microenvironment (IrO2-GOx@HA NPs). Firstly, GOx convert the high levels of glucose in the tumor to hydrogen peroxide (H2O2), and then IrO2 NPs convert H2O2 to oxygen (O2), which can enhance the type II of PDT. IrO2 NPs also can be used as a thermosensitive agent for photothermal therapy (PTT). In cancer cells, IrO2-GOx@HA NPs-mediated amplifier enhances the effect of type II of PDT, aggravating the apoptosis of breast cancer (4T1) cells and cooperating with its own PTT to further improve the overall treatment effect. Under simulated hypoxic conditions of tumor tissue, it was found that IrO2-GOx@HA NPs treatment can effectively relieve hypoxia inside tumor tissue. Epacadostat In addition, the results in vivo further proved that, IrO2-GOx@HA NPs can enhance the role of II PDT and cooperate with PTT to treat breast cancer effectively. The results highlight the prospect of IrO2-GOx@HA NPs in controlling and regulating tumor hypoxia to overcome the limitations of current cancer therapy.Although lithium-ion batteries (LIBs) have many advantages, they cannot satisfy the demands of numerous large energy storage industries owing to their high cost, low security, and low resource richness. Aqueous zinc-ion batteries (ZIBs) with low cost, high safety, and high synergistic efficiency have attracted an increasing amount of attention and are considered a promising choice to replace LIBs. However, the existing cathode materials for ZIBs have many shortcomings, such as poor electron and zinc ion conductivity and complex energy storage mechanisms. Thus, it is crucial to identify a cathode material with a stable structure, substantial limit, and suitability for ZIBs. In this review, several typical cathode materials for ZIBs employed in recent years and their detailed energy storage mechanisms are summarized, and various methods to enhance the electrochemical properties of ZIBs are briefly introduced. Finally, the existing problems and expected development directions of ZIBs are discussed.The rapid evolution of antimicrobial resistant genes (AMRs) in water resources is well correlated to the persistent occurrence of ciprofloxacin in water. For the first time, encapsulated nanoscale zerovalent iron (nZVI) with a shell of magnesium hydroxide (Mg/Fe0) was used to adsorb ciprofloxacin from water. Optimization of the removal conditions exhibited that 5% was the optimum mass ratio between magnesium hydroxide and nZVI [Mg(OH)2/nZVI)] as more than 96% of 100 mg L-1 of ciprofloxacin was removed. In addition, 0.5 g L-1 of Mg/Fe0 showed an extraordinary performance in removing ciprofloxacin over a wide range of pH (3-11) with removal efficiencies exceeded 90%. Kinetic analysis displayed that the kinetic data was well described by both Pseudo first-order and second-order models. Also, the equilibrium data was well fitted by Freundlich isotherm model. In addition, thermodynamic analysis evidenced that the removal of ciprofloxacin by Mg/Fe0 was exothermic, and spontaneous. The experiments also revealed that physisorption and chemisorption were the responsible mechanisms for ciprofloxacin removal. The proposed treatment system remediated 10 litters of 100 mg L-1 of ciprofloxacin solution with 100% overall removal efficiency. This treatment system could be a promising and practical solution to decrease ciprofloxacin concentration in different water bodies.Responsive photonic crystals have attracted much attention due to their strong capability to manipulate the propagation of light in the visible region, but it is still a big challenge to invisibility and mechanical stability. Here, the novel Poly(ether sulfone)/Poly(acrylic acid) inverse opal photonic crystals, which have high mechanical stability and can release visible patterns after wetting with water, are discussed. The Poly(ether sulfone)/Poly(acrylic acid) inverse opal photonic crystals are also responsive to the concentration of ethanol, and the structural color response times increase with increasing ethanol concentration. This design uses the selective infiltration, hydrogen bonding and capillary action of solvent to realize the spectral diversity of reflectance. Owing to the high polarity and hydrogen bonding ability of carboxyl groups, water molecules are adsorbed easily by the poly(acrylic acid) gel. Subsequently, the encrypted information is decrypted due to the redshift of the structural color. Because of its lower polarity and hydrogen bonding ability relative to water, ethanol can impede the absorption of solvent by gel. Therefore, the ethanol concentration can be identified based on the structural color response time. Furthermore, reliable information decryption methods make Poly(ether sulfone)/Poly(acrylic acid) inverse opal photonic crystals potentially uesful as trusted encryption devices.Carbon aerogels are prepared by a thermal treating-freeze drying approach from chitosan, with glycine hydrochloride ionic liquid (IL) acting as solvent and nitrogen source. Different post-treatments such as ball milling and high temperature carbonization are employed to functionalize the obtained carbon aerogels with tuned properties, making it promising candidates as fluorescence material (NACs-Q), electrode material (FDC-800) and catalyst support (NACPd-C). NACs-Q is water-soluble quantum dot with average particle sizes of 3.8 nm, presenting excitation-/emission-independent and pH-sensitive properties, which could be used as sensor for testing acetone vapor or an "on-off-on" sensor for detections of Fe3+ and vitamin C in fruits. FDC-800 exhibits fluffy lamellar structure with developed micro-mesopores and nitrogen-containing groups on their surfaces, which is beneficial for building flexible solid-state supercapacitor with excellent performance, delivering a capacitance of 208F/g at 0.5 A/g, and achieving an energy density of 7.2 W h/kg at a power density of 50 W/kg. Moreover, NACPd-C can be used as catalyst for phenol hydrogenation, and phenol conversion of 100% with cyclohexanone selectivity of 98.3% is achieved, due to the synergetic effects of the Pd active-site, the N-containing groups, and the Lewis acid sites on the support.Urea electro-oxidation reaction (UOR) has been a promising strategy to replace oxygen evolution reaction (OER) by urea-mediated water splitting for hydrogen production. Naturally, rational design of high-efficiency and multifunctional electrocatalyst towards UOR and hydrogen evolution reaction (HER) is of vital significance, but still a grand challenge. Herein, an innovative 3D Ru-modified NiFe metal-organic framework (MOF) nanoflake array on Ni foam (Ru-NiFe-x/NF) was elaborately designed via spontaneous galvanic replacement reaction (GRR). Notably, the adsorption capability of intermediate species (H*) of catalyst is significantly optimized by Ru modification. Meanwhile, rich high-valence Ni active species can be acquired by self-driven electronic reconstruction in the interface, then dramatically accelerating the electrolysis of water and urea. Remarkably, the optimized Ru-NiFe-③/NF (1.6 at% of Ru) only requires the overpotential of 90 and 310 mV to attain 100 mA cm-2 toward HER and OER in alkaline electrolyte, respectively. Impressively, an ultralow voltage of 1.47 V is required for Ru-NiFe-③/NF to deliver a current density of 100 mA cm-2 in urea-assisted electrolysis cell with superior stability, which is 190 mV lower than that of Pt/C-NF||RuO2/NF couple. This work is desired to explore a facile way to exploit environmentally-friendly energy by coupling hydrogen evolution with urea-rich sewage disposal.The reasonable design of the structure and composition of catalysts was essential to improve the catalytic performance of advanced oxidation processes (AOPs). Herein, we reported a simple strategy to synthesize hierarchical Co3O4-C@CoSiOx yolk-shell nanoreactors with multiple active components by using metal-organic frameworks (MOFs). The novel nanoreactors are further used to activate peroxymonosulfate (PMS) for ciprofloxacin (CIP) degradation. The effects of reaction parameters (pH value, co-existing ions, reaction temperature, etc.) on CIP degradation were systematically investigated. Especially, ∼98.2% of CIP was degraded within 17 min under the optimal conditions, together with the low cobalt leaching and excellent reusability. The appreciable catalytic performance improvement might be due to the synergistic effect of the structure and component design (1) the hierarchical yolk-shell structure endowed the catalyst with high surface area (∼232.47 m2/g) and fully exposed active sites; (2) abundant highly active ≡Co-OH+ were formed on the surface of CoSiOx; (3) the presence of oxygen vacancies and nitrogen-doped carbon promoted the decomposition of PMS through a non-radical process. The results revealed both the radical (SO4∙-, ∙OH and O2∙-) and non-radical (1O2 and direct charge transfer) should be responsible for the CIP degradation. Moreover, the possible degradation pathways of CIP were proposed through the identification of intermediates using LC-MS/MS techniques and density functional theory (DFT) calculation. Our work highlights that multi-component catalysts derived from MOFs with novel structure have broad application prospects in AOPs.The interaction of proteins and peptides with inorganic surfaces is relevant in a wide array of technological applications. A rational approach to design peptides for specific surfaces would build on amino-acid and surface specific interaction models, which are difficult to characterize experimentally or by modeling. Even with such a model at hand, the large number of possible sequences and the large conformation space of peptides make comparative simulations challenging. Here we present a computational protocol, the effective implicit surface model (EISM), for efficient in silico evaluation of the binding affinity trends of peptides on parameterized surface, with a specific application to the widely studied gold surface. In EISM the peptide surface interactions are modeled with an amino-acid and surface specific implicit solvent model, which permits rapid exploration of the peptide conformational degrees of freedom. We demonstrate the parametrization of the model and compare the results with all-atom simulations and experimental results for specific peptides.