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0% and 11.8%, respectively, and Cd accumulation within those grains reduced by 14.3% and 48.9%, respectively. During the winter non-growth period, freeze-thaw aging facilitated Cd mobilization, with DTPA-extractable Cd increasing by 16.9% in the control soil, relative to the initial period. However, this reduced to 10.9%, 14.4%, 7.6% and 5.0%, for the sepiolite, superphosphate, biochar and joint application treatments, respectively. Overall, the joint application of biochar and superphosphate provided the best performance in terms of both long-term Cd immobilization and rice production enhancement, offering a green remediation option for risk management at Cd contaminated rice paddies in seasonally frozen regions.Droughts are among the costliest natural hazards that occur annually worldwide. Their socioeconomic impacts are significant and widespread, affecting the sustainable development of human societies. This study investigates the influence of different forcing precipitation data in driving Land Surface Models (LSMs) and characterizing drought conditions. Here, we utilize our recently developed LSM data assimilation system for probabilistically monitoring drought over the Contiguous United States (CONUS). The Noah-MP LSM model is forced with two widely used precipitation data including IMERG (Integrated Multi-satellitE Retrievals for GPM) and NLDAS (North American Land Data Assimilation System). Soil moisture and evapotranspiration are known to have a strong relationship in the land-atmospheric interaction processes. C1632 Unlike other studies that attempted the individual assimilation of these variables, here we propose a multivariate data assimilation framework. Therefore, in both modeling scenarios, the data assimilaion forcings.China is under rapid urbanization and consequently facing increasing carbon emissions (CE). Economic growth (EG) and innovation performance (IP), as two critical indicators of urbanization, are considered the driving forces of CE. Although economy and innovation are entangled and can jointly affect CE in reality, the measured effects of economy and innovation on CE are often treated separately in traditional studies. We adopted a three-part research framework including the total, interaction and mediation effect tests to elucidate how EG and IP affected CE in China from 2005 to 2015 based on insights from 282 Chinese cities. The empirical results showed that both economy and innovation contributed to CE, although the contribution has reduced over the 11 years. In particular, the interaction effect between economy and innovation for North China, Northeast China, and Southwest China was -4.201, -8.442, and - 3.897, respectively, in 2015, meaning that these regions adversely affect CE. In addition, we found that the economy helps reduce CE via innovation. When considering the changes of economy and innovation, their mediation effect on CE changes varied in different regions, attributable to the level of economy and innovation as well as the stocks of energy resources. Therefore, future planning for low-carbon transition should regard the economy and innovation together. Based on this principle, we propose five detailed policies. Overall, this study is valuable not only for further understanding the triangle relationship among economy, innovation, and CE, but also for reaching low-carbon goals.Subterranean ecosystems play an active role in the global carbon cycle, yet only a few studies using indirect methods have focused on the role of the cave microbiota in this critical cycle. Here we present pioneering research based on in situ real-time monitoring of CO2 and CH4 diffusive fluxes and concurrent δ13C geochemical tracing in caves, combined with 16S microbiome analysis. Our findings show that cave sediments are promoting continuous CH4 consumption from cave atmosphere, resulting in a significant removal of 65% to 90%. This research reveals the most effective taxa and metabolic pathways in consumption and uptake of greenhouse gases. Methanotrophic bacteria were the most effective group involved in CH4 consumption, namely within the families Methylomonaceae, Methylomirabilaceae and Methylacidiphilaceae. In addition, Crossiella and Nitrosococcaceae wb1-P19 could be one of the main responsible of CO2 uptake, which occurs via the Calvin-Benson-Bassham cycle and reversible hydration of CO2. Thus, syntrophic relationships exist between Crossiella and nitrifying bacteria that capture CO2, consume inorganic N produced by heterotrophic ammonification in the surface of sediments, and induce moonmilk formation. Moonmilk is found as the most evolved phase of the microbial processes in cave sediments that fixes CO2 as calcite and intensifies CH4 oxidation. From an ecological perspective, cave sediments act qualitatively as soils, providing fundamental ecosystem services (e.g. nutrient cycling and carbon sequestration) with direct influence on greenhouse gas emissions.Artificial light at night (ALAN) has become a profound form of global anthropogenic environmental change differing in from natural light regimes in intensity, duration, distribution and spectra. It is clear that ALAN impacts individual organisms, however, population level effects, particularly of spectral changes, remain poorly understood. Here we exposed experimental multigenerational aphid-parasitoid communities in the field to seven different light spectra at night ranging from 385 to 630 nm and compared responses to a natural day-night light regime. We found that while aphid population growth was initially unaffected by ALAN, parasitoid efficiency declined under most ALAN spectra, leading to reduced top-down control and higher aphid densities. These results differ from those previously found for white light, showing a strong impact on species' daytime performance. This highlights the importance of ALAN spectra when considering their environmental impact. ALAN can have large impacts on the wider ecological community by influencing diurnal species.The implementation of the European Union (EU) Carbon Border Adjustment Mechanism (CBAM) will affect the cost efficiency of Chinese exporters, and few studies have considered how to deal with its impact from the carbon market perspective. Based on this, this paper constructs two price-variable resource allocation (VPRA) models to investigate China's allowance allocation strategies to mitigate the impact of the EU CBAM from a carbon market perspective. This paper takes the steel and cement industries in each province of China for example for cost efficiency assessment and carbon allowance allocation, and finds that (1) The EU CBAM has a negative impact, and it is necessary to incorporate the CBAM into the top-level system design of allowance allocation to obtain an allowance allocation scheme that maintains the cost efficiency level of each industry. (2) A higher and more stable carbon price in China can effectively counteract the impact of the EU CBAM and ensure that the cost efficiency of each industry does not fluctuate significantly. (3) When the Chinese carbon price exceeds 60 RMB/ton, the impact of the EU CBAM on the cost efficiency of each industry will become significantly smaller. (4) Measures to reduce the number of products exported to the EU are not effective in mitigating the impact of the EU CBAM when the number of products exported to the EU exceeds a certain rate. The findings of this paper provide useful policy insights for China and other developing countries to actively address the challenges of the EU CBAM.This study investigates the ecotoxicological impacts of the Fundão dam rupture, one of the major environmental disaster that occurred in Brazil and in the world mining industry history, through multi-biomarkers responses and metals bioaccumulation in the fish community of different trophic levels. Specimens of the fishes (omnivorous/herbivorous and carnivorous) were collected along the Doce River channel and its affluent Guandú River, and in different lakes and coastal lagoons adjacent to the river channel, in the Espirito Santo State, Southeast of Brazil. Four sampling collections were carried out over two years (2018 to 2020, during dry and rainy seasons). For both trophic groups the biomarkers responses indicated physiological alterations related to metals exposure and showed strong seasonal variations. The principal component analysis and integrated biomarker response index showed that DNA damage and lipid peroxidation were more associated with dry season 2 (Sep/Oct 2019) and the oxidative damage in proteins, metallothioneins concentration and the activity of superoxide dismutase in the gills showed a greater association with rainy season 2 (Jan/Feb 2020). On the other hand, the enzymes of energy metabolism, catalase and histological damage in the liver and the gills, were more associated with the dry and rainy campaigns of the first year of monitoring. The multivariate approach also suggested a temporal intensification in the bioaccumulation of metals and biological effects in the lacustrine environments. Thus, these results demonstrate that the release of mineral residues from the rupture of the Fundão mine dam affects the health status of the fish from the Doce River basin, provoking metals bioaccumulation, hepatic and branchial damage in the fish besides inducing of enzyme activity related to metal contamination, even four years after the rupture.Animal manures are reported as good substitutes for chemical fertilizers to mobilize soil phosphorus (P). However, the mechanisms on how different types of manures regulate microbial biomass involved in P mobilization remain unclear. In this study, we conducted a two-year field experiment to investigate variations in soil microbial biomass carbon (MBC) and P (MBP) and P fractions after 30% animal manures substitution (pig manure (PM), chicken manure (CM), and dairy manure (DM)) in paddy soil. Furthermore, a 30-day incubation experiment was used to explore the mechanisms of soil P transformation induced by 100% manures addition. Two-year field experiment results showed that, compared to the chemical NPK fertilizer, 30% manure substitution didn't influence rice and wheat yields significantly but decreased soil total P loss from runoff by 3.2%. However, 30% manure substitution significantly enhanced MBC and MBP by 11.3-18.4% and 57.1-81.2%, respectively, which also promoted the transformation of moderately labile P (M-P) to labile P (L-P). Moreover, the incubation experiment also convinced that all manures caused higher MBC than chemical P fertilizer. Meanwhile, compared to the no P fertilizer, manures increased L-P and organic P by 2.7%-14.7% and 6.4%-20.0%, respectively. Redundancy analysis indicated that soil MBC/MBP ratio was the main factor to soil L-P and M-P, indicating that animal manures can improve soil microbial abundance and thus promote M-P to L-P in soil. Among three animal manures, PM could improve the mobilization potential of P mostly, due to the highest C source activity by 13C NMR analysis. Our study indicated that animal manures especially PM can be considered as a good candidate for agricultural P management in paddy soils because of their capacity to promote soil P transformation.