Hooverjansen9413

The PAEs in the outdoor dust originated mainly from wide application of plasticizers as well as cosmetics and personal care products. The main pathways of human exposure to PAEs in the outdoor dust were ingestion and dermal absorption of dust particles. The total intakes of PAEs from outdoor dusts for children and adults were 1.50 × 10-5 and 2.47 × 10-6 mg·kg-1·d-1, respectively. Children were more susceptible to the PAEs intake than the adults. Although the estimated health risks of the six PAEs are currently acceptable, caution is needed given the likely future increase in use of these PAEs and the currently unknown contribution to human exposure by other medium.Urbanized coastal areas are well-recognized hotspots for the contaminant-enriched groundwater discharge, influencing sensitive coastal ecosystems. The present study investigates how muddy beaches in the semi-arid region alter the contaminant flux flowing into the sea using submarine groundwater discharge (SGD) estimation and hydrogeochemical analysis of coastal waters (groundwater, porewater, and seawater). Fresh SGD carries contaminants such as nutrients and trace metals in the coastal ecosystem, causing increased vulnerability towards eutrophication, harmful algal blooms, and human health. We found that SGD reaching the coast carries immense nutrient flux (155.6 mmol NO3- · day-1; 35 mmol P · day-1 and 12.4 mmol DSi · day-1) and trace metal load ranging from 0.1 to 14.9 mmol · day-1. The nutrient fluxes were higher in the upper saline plume compared to the lower plume. The muddy beach attenuates the nutrients in varying percentages of 9.7 to 22% of NO3-, 1.9 to 25.5% of P due to denitrification and phosphorus absorption, and also caused 19.6% reduction of SO42-. The reduction in SO42- leads to the formation of sulfide (HS-) that promotes the metal precipitation, resulting in the removal of Pb and Cu. This attenuation of nutrients leads to a change in the nutrient ratio (N/P = 7-11) approaching the Redfield ratio, implying the vulnerability of algal bloom at the Dehri beach. Overall, the muddy beach can serve as a natural biogeochemical reactor as it attenuates the nutrient and serves as a source for certain trace metals (Fe, Mn, Zn, and Ni), altering the composition of SGD. Probably this is the first study that emphasizes the attenuation of trace metals in the muddy beaches of a semi-arid region.Dynamic processes of organic contaminants in sediments can have important toxicological implications in aquatic systems. The current study used diffusive gradients in thin-films (DGT) devices in sandy sediments spiked with nine antipsychotics and in field sandy sediments. Samplers were deployed for 1 to 30 days to determine the flux of these compounds to DGT devices and the exchange rates between the porewater and sediment solid phase. The results showed a continuous removal of antipsychotics to a binding gel and induced a mobile flux from the DGT device to the adjacent sediment solution. A dynamic model, DGT-induced fluxes in soils and sediments, was used to derive rate constants of resupply of antipsychotics from solid phase to aqueous phase (response time, Tc) and distribution coefficients for labile antipsychotics. The largest labile pool was found for lamotrigine and carbamazepine in spiked sediments. Carbamazepine, clozapine, citalopram, and lamotrigine were resupplied rapidly by sediments with Tc (25-30 min). Tc values of bupropion and amitriptyline were the longest (≈5 h), which exhibited slow desorption rates in sediments. In field sediments, high resupply was found for carbamazepine and lamotrigine, which did not show higher labile pool. The Tc values were obviously higher in the filed sediments (52-171 h). Although the adsorption process is dominant for most studied antipsychotics in both spiked sediments and field sediments, the kinetic resupply of antipsychotic compounds may not be accurately estimated by laboratory-controlled incubation experiments. More studies are needed to explore the mechanisms of desorption kinetics by using in situ DGT technique in the field.Fine-grained sediments are a natural component of river systems. Human activities generate additional sources of fine sediment. In mountainous areas, the anthropogenic inputs of fine sediments are associated with forestry. The aim of this study was to analyse the differences in the macroinvertebrate communities between the reference and caused by forest harvesting activities increased influx of fine-sediment to mountain streams. The tested hypothesis was that the macroinvertebrate communities will differ depending on the intensity of forest harvesting practices in the stream catchment that causes excessive influx of fine sediment into the stream. The reintroduction of beavers in the study area, and the formation of in-stream beaver dams, contribute the accumulation of sediments in stream sections with slower water. Thus, it was also assumed that by capturing and storing fine sediments, may contribute to the restoration of the natural structure of the benthic communities downstream of the ponds. selleck chemical The study was carried out in a mountain stream catchment area (Carpathians, Poland), in which inflow of fine sediments in the stream sections varied in intensity. The study was conducted over three years (2018-2020). The extensive use of forest roads, timber skidding trails, and timber storage areas produced fine sediments that clogged the interstitial spaces between the stones in the riffles, limiting the presence of rheophilic taxa associated with coarse-grained substrates. The reduction of the number of scrapers and shredders (i.e. primary consumers) associated with the influx of fine sediments may significantly affect the entire food-web structure in stream ecosystems. The capture and deposition of fine sediments in beaver ponds may accelerate the revitalisation of the flowing sections of the stream. Beaver-induced sediment management is strongly recommended as a beneficial practice that could contribute to ecological preservation and the potential of streams, particularly in mountain areas.Seaweeds are widely known superfood in coasts where most anthropogenic heavy metal discharges are inputted and stored. The present study analyzed 11 seaweed species and 13 heavy metals to test the hypothesis that the species-specific capacity of heavy metal bioaccumulation had great significance to health risk of human. The seaweeds were collected from tropic coasts of Hainan Island. We comparatively determined the bioaccumulation level of metals in different species. The results revealed that the red algae mainly concentrated V, Se, Mn, Ni, and Ag. The brown algae mainly concentrated Cr, Co, Cu, Cd, As and Fe, while the green algae mainly concentrated Zn and Pb. The cluster analysis, principal component analysis and metal pollution index indicated that Padina crassa, Sargassum thunbergii, Caulerpa racemosa and Asparagopsis taxiformis showed similar metal bioaccumulation behavior. The health risk assessment revealed that the overall hazard index (HI) of seaweeds consumption to adults was less than 1, while the HI of Sargassum oligocystum, Turbinaria ornate, Sargassum polycystum and Sargassum thunbergii consumption to children was greater than 1, suggesting a moderate or high risk to children. Moreover, the exposure amount and the carcinogenic risk parameter indicated that As and Cr were the limiting factor for seaweeds consumption. Overall, our findings here largely supported our hypothesis that the heavy metal bioaccumulation behavior and health risk was highly variable and complex among different species. We thus suggested that the species-specific health risk of heavy metals in seaweeds should be cautiously evaluated in natural environments.Urban agriculture in post-industrial cities faces concerns on human health risks posed by elevated lead (Pb) concentrations of edible plant tissues grown in Pb-enriched soils. A recommended mitigation strategy to decrease soil Pb bioavailability to humans is the addition of soluble phosphate (PO43--P), but it is unclear if this strategy can also reduce crop Pb uptake and accumulation in edible tissues. Across urban agriculture sites in Chicago, Illinois (6 site-years) with elevated total soil Pb, we tested the hypothesized decrease in tomato fruit Pb following soil-based application of three phosphate-based mitigation amendments triple superphosphate, composted biosolids, and air dried biosolids. Fruit Pb concentrations (mg Pb kg-1 dry mass) and loads (mg Pb m-2) were unaffected by mitigation amendments. However, fruit Pb concentrations were higher by an order of magnitude in 2020 (≥0.13 mg kg-1) compared to 2019 (0.01 mg kg-1) for two of the three sites. Though highly variable across site-years, the bioconcentration factor (BCF) of Pb from soil to fruit varied was unaffected by mitigation amendments. Relatively low BCF values were consistent with fruit Pb concentrations being below FAO/WHO risk limits. Collectively, our findings support previous propositions that fruits of plants grown in soils with elevated Pb generally pose lower risk to consumers. To mitigate health risks of consuming tomatoes grown in soils with Pb contamination, the seasonality of Pb uptake should be investigated, and greater focus should be placed on where tomatoes are grown rather than phosphate-based immobilization strategies originally designed to mitigate human bioavailability.Greenness could theoretically increase the impact of physical activity (PA) and reduce the adverse effects of air pollution on overweight/obesity. However, no evidence systematically compares these two pathways, especially in longitudinal studies of children and adolescent's cohort. Greenness, PA, and air pollution were assessed by Normalized Difference Vegetation Index (NDVI), International Physical Activity Short Form, and 7 pollutants (PM1, PM2.5, PM10, SO2, NO2, CO, and O3). Each exposure was divided into low-/high-level groups based on the 50% quantile. Proportional hazards and logistic regression model were used to assess the associations of greenness, PA, pollutants with overweight/obesity. The incidence of overweight/obesity was 1.98% in the national survey, and the cumulative incidence and incidence density were 12.76% and 3.43 per 100 person-year in the dynamic cohort, separately. An increase of 0.1 units in NDVI was associated with a 12% lower risk of overweight/obesity, but no significant link between PA and incidence was observed. The HRs of the high-level of PM1, PM2.5, PM10, SO2, NO2, CO, and O3 on the risk of overweight/obesity were 2.21, 2.63, 1.88, 2.38, 1.33, 2.43, and 1.33 in the low-level of greenness, which was higher than those in the high-level of greenness. The AFs of PM1, PM2.5, PM10, SO2, NO2, CO, and O3 were 25.58%, 44.37%, 22.96%, 29.15%, 11.55%, 29.50%, and 10.92% in the low-level of greenness, which simultaneously was higher than those in the high-level of greenness. Moreover, the risk of overweight/obesity associated with high-level of greenness in the high-level of PM10, SO2, CO were 0.83, 0.81, and 0.83 respectively. Our findings confirmed that greenness has a moderating effect on the effects of air pollutants on childhood overweight/obesity especially in heavy-industry areas where PM10, SO2, and CO are the major pollutants, although it did not influence the association between PA and overweight/obesity risks.