Hongbray0192

A decrease in mechanical properties of nanopapers was observed for the combined treatment and NaOH treatment alone compared to enzymatic hydrolysis alone, with Young's modulus of 8.94, 4.84 and 11.21 GPa respectively. However, optical properties were improved, with transmittance values of 42.2, 15.4 and 7.1 % respectively. This new pretreatment can therefore lead to CNF with tunable properties depending on the application, with possible industrialization thanks to the reduction of energy needs.In this paper, the effect of the electric field on the properties of a new chitosan-molybdenum (Chit-Mo) composite coating obtained by electrophoretic deposition (EPD) was investigated. The composite coatings obtained showed different morphologies depending on the conditions used during the deposition process. Chemical composition results and microstructure analysis showed homogeneous distribution of molybdenum in a chitosan matrix. Corrosion test results showed that the Chit-Mo composite coatings can increase corrosion resistance of 1020 steel in NaCl medium (3.5 %). The coatings obtained at 5 V, pH 5.5, and using a low concentration of reagents (suspension 1 chitosan 0.5 g/L and 1 mM sodium molybdate) reached an inhibition efficiency of up to 76.7 %. Therefore, the results obtained in this work prove the achievement of a new class of chitosan-based composite materials with potential application in the protection of metal structures against corrosion.To meet the increasing demand for polysaccharide-stabilized selenium nanoparticles (PS-Se°NPs) for industrial applications, in this study, we employed three commonly-used polysaccharides (i.e. chitosan (CS), carrageenan (Cg) and Gum Arabic (GA)) to fabricate Se°NPs, and compared their functional properties and their physicochemical stabilities, under varying conditions (ionic strength, pH, and temperature). The results showed that CS-Se°NPs had higher storage stability but easily aggregated in 500 mM NaCl or at pH > 8 because of their surface cationic groups. This, however, improved their DPPH free radical scavenging and antitumor activities. Compared to CS-Se°NPs, the anionic groups in Cg-Se°NPs increased their resistant to pH variations and reduced cellular toxicity, and the multi-branched structure of GA-Se°NPs increased their thermal stability. Overall, this study shows that the behaviors of PS-Se°NPs depends mainly on ionizable functional groups and the structure of polysaccharides, contributing to the development of PS-Se°NPs with applicability in the food and pharmaceutical industries.Growing attention has been focused on modifications of starch using electric field, but electrode corrosion and metal contamination remain unavoidable during the process. To solve these problems, the magneto-induced electric field was used to assist corn starch hydrolysis due to its thermal effect. Results indicated that the method accelerated corn starch acid hydrolysis and decreased the treatment time. The reducing sugar content increased to 0.59 g/L after a 60 s treatment, which was 353.44 % higher than the 20 s treatment, while the average degree of polymerization reached a minimum. The treated starch showed increased solubility and swelling power, as well as decreased freeze-thaw stability. selleck products X-ray diffraction, fourier transform infrared spectroscopy, and scanning electron microscopy results suggested that the physicochemical changes of corn starch were due to the thermal effect of the induced electric field. This study is expected to provide an important basis for applying new electric field hydrolysis technology to starch modification.Thermoresponsive colloidal chitosan systems forming the polymer structure in situ are an example of promising solutions in tissue engineering as an injectable scaffolds or drug carriers. Their application method, and thus shearing, may affect the aggregation process in accordance with the colloidal engineering approach. The aim of the study is to compare the kinetics of chitosan aggregation in the perikinetic regime (limited by Brownian motions) with the orthokinetic process carried out under the influence of an external shear field. The research was carried out using static multiple light scattering (S-MLS) and rheometric measurement techniques coupled with small-angle light scattering (Rheo-SALS). It has been found that the introduction of an external shear field (orthokinetic regime) accelerates the aggregation of chitosan systems. Simultaneously, the rotational measurements can even lead to spontaneous gelation, most likely caused by changes in the conformation of chitosan molecules, their deformation and ordering along the shear field.A sensitive detection strategy for ascorbic acid (AA), using sodium alginate reduced/stabilized gold nanoparticles (SA-AuNPs) as the optical probe, is reported. The SA-AuNPs were prepared by mixing gold salt and SA under stirring for 2 h at room temperature, without any further steps. The mixture was aged at 4 °C overnight, after which a faint-purple colloidal solution of SA-AuNPs was obtained. Characterization shows that the synthesis is incapable of reducing all Au3+ to Au°, but rather to mixture of Au°/Au+. The addition of AA to the SA-AuNPs probe reduced completely all Au+ to new AuNPs which were deposited on the pre-formed SA-AuNPs seed, leading to size increment and absorption spectra enhancement. The assay exhibited a good linearity between 12.5 and 150.0 μM AA and low limit of quantification of 11.2 μM. It was further used for AA quantitation in vitamin C injection and fruit juice with satisfactory accuracy and precision.Cellulose acetate (CA) is an attractive membrane polymer for CO2 capture market. However, its low CO2 permeability hampers its application as part of a membrane for most relevant types of CO2 containing feeds. This work investigates the enhancement of CA separation performance by incorporating ionic liquid-like pendants (1-methylimidazol, 1-methylpyrrolidine, and 2-hydroxyethyldimethylamine (HEDMA) on the CA backbone. These CA-based polyelectrolytes (PEs), synthesised by covalent grafting of cationic pendants with anion metathesis, were characterised by NMR, FTIR, DSC/TGA, and processed into thin-film composite membranes. The membrane performance in CO2/N2 mixed-gas permeation experiments shows a decrease in CO2 and N2 permeability and an initial decrease and then gradual increase in CO2/N2 selectivity with increasing HEDMA content. The amount of HEDMA attached to the CA backbone determines overall separation process in bifunctional PEs. This indicates that the hydroxy-substituted cationic pendants alter interactions between PEs network and permeating CO2 molecules, suggesting possibilities for further improvements.