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Herein, we report a method to synthesize nitrogen self-doped hierarchical porous carbon materials derived from chitosan. This method uses potassium hydroxide (KOH) activation and rapid-freezing technology. The catalyst (CA-900Q 1-1) obtained after rapid-freezing and KOH activation treatment show excellent persulfate activation ability. It can remove 20 mg bisphenol A (BPA) within 10 min better than traditional metal oxidate and nanomaterials. In the aquatic environment, CA-900Q 1-1 has a high resistance to inorganic anions. CA-900Q 1-1, possessing a high proportion of graphitic nitrogen, provides a sufficient number of active sites for persulfate activation. In addition, the catalyst yielded sizeable specific surface areas (SSAs) (1756.1 m2/g) and a hierarchical pore structure, which helps to improve the mass transfer in the carbon framework. selleck compound of pollutants by the catalyst shortens the time required for target organic molecules to migrate to the catalyst surface and hierarchical pore structure. Furthermore, the catalyst has excellent electrical conductivity (R = 1.73 Ω), which enables pollutants adsorbed on the catalyst surface to transfer electrons to the persulfate through the N-doped sp2-hybrid carbon network faster.Groundwater recharge in hyper arid areas often depends on surface water infiltration and diffuse recharge of highly evaporated precipitation only contribute under favorable conditions. This happens in the Calama basin two-aquifer system, in the Central Andean area of northern Chile. A conceptual model of the groundwater system and its relationship with the Loa River is defined. #link# We focus on the confined aquifer of the Calama basin, combining hydrodynamic, hydrogeochemical and isotopic methods. Radiocarbon (14C) activity data of dissolved inorganic carbon (DIC), in conjunction with chemical data, are applied to evaluate groundwater residence time within the confined aquifer. The Loa River recharges the Calama basin aquifers in its northeastern part, with water that has chemical and isotopic characteristics inherited from the arid environment and volcanic rocks in its upper basin. In the central and northeastern part of the confined aquifer, minor variations in chloride concentration suggest that the deep aquifer is well confined. The δ18O and δ2H values in groundwater of the confined aquifer show an increasing isotopic fractionation from the recharge area (around -10‰ δ18O) to those in the discharge area (between -8.5‰ and -8‰) in the southwestern part of the aquifer. The 14C activity continuously decreases down flow from the recharge by the Loa River. Adjusted DIC radiocarbon ages indicate a groundwater travel time between 1500 and 4000 years in the confined aquifer of Calama. Despite the limitations and uncertainties of radiocarbon in DIC to estimate groundwater transit times for the confined aquifer and considering complementary chemical and isotopic constraints, the DIC 14C provides acceptable values. The approach may be applicable in other confined aquifers in hyper-arid climates in which the formation of aquifer systems linked to river damming by geological action took place. This information is needed for sound management of the scarce groundwater resources.Estuarine wetlands have experienced a variety of ecological and environmental problems caused by natural and anthropogenic factors. China has proposed a series of measures and made great efforts to control coastal degradation; however, decision makers still urgently need to know which measures to implement and how they will influence the estuarine environment and functions. This study used field observations, a hydrodynamic model, and statistical methods to investigate the effects of potential restoration scenarios on hydrodynamic conditions in the tidal-influenced estuarine wetland system, Liaodong Bay (China). Results reveal that the average total phosphorus, organic carbon, available phosphorus, pH, total nitrogen content, and moisture content in the soil and sediment environment were 0.04 ± 0.003%, 0.84 ± 0.25%, 16.3 ± 4.7 mg/kg, 8.3 ± 0.1, 0.07 ± 0.02%, and 44 ± 2%, respectively, exhibiting an overall trend of degradation. A series of restoration scenarios in regards to hydrodynamic regulation and tidal ty planning, and ecological sustainability.Despite combined plant/white-rot fungus remediation being effective for remediating polycyclic aromatic hydrocarbon (PAH)-contaminated soil, the complex organismal interactions and their effects on soil PAH degradation remain unclear. Here, we used quantitative PCR, analysis of soil enzyme activities, and sequencing of representative genes to characterize the ecological dynamics of natural attenuation, mycoremediation (MR, using Crucibulum laeve), phytoremediation (PR, using Salix viminalis), and plant-microbial remediation (PMR, using both species) for PAHs in soil for 60 days. On day 60, PMR achieved the highest removal efficiency of all three representative PAHs (65.5%, 47.5%, and 62.4% for phenanthrene, pyrene, and benzo(a)pyrene, respectively) when compared with the other treatments. MR significantly increased the relative abundance of Rhizobium and Bacillus but antagonized the other putative indigenous PAH-degrading bacteria, which were enriched by PR. PR significantly reduced soil nutrients, such as NO3- and NH4+, and available potassium (AK), thereby changing the microbial community composition as reflected by redundancy analysis, significantly reducing the soil bacterial biomass relative to that in other treatments. These disadvantages hampered phenanthrene and pyrene removal. MR provided additional nutrients, which counteracted the nutrient consumption associated with PR, thereby maintaining the microbial community diversity and bacterial biomass of PMR at a level achieved in the NA treatment. Combination remediation therefore overcame the disadvantages of using PR alone. These results indicated that inoculation with the combination of S. viminalis and C. laeve synergistically stimulated the growth of indigenous PAH-degrading microorganisms and maintained bacterial biomass, thus accelerating the dissipation of soil PAHs.In this study, the effect of unstable pe + pH levels on the transformation of Fe oxides in different-sized soil fractions and its impact on Cd speciation were explored. Paddy soil samples collected from two locations in China were cultivated for two months under one of four pe + pH conditions flooding + N2 (T1), flooding (T2), 70% water holding capacity (T3), and 70% water holding capacity + O2 (T4). Chemical analysis and X-ray diffraction (XRD) were used to identify the mineralogical phases and species of Fe and Cd in paddy soils. The results show that the decrease of soil pe + pH level favored the transformation of well-crystallized Fe oxides (Fec), such as hematite and goethite, into poorly-crystallized (Feo) and organically-complexed (Fep) forms. The transformation promoted the binding of Cd to Fe oxides and was primarily responsible for up to a 41.8% decrease of soil DTPA (diethylenetriaminepentaacetic acid)-extractable-Cd content. In addition, the decline in pe + pH value reduced Fe concentrations in soil particle fractions of 0.2-2-mm (17.8%-30.6%) and less then 0.002-mm (20.7%-31.7%) of the two flooding treatments. The decreased Fe concentrations were closely associated with less Fec contents in these same fractions and more Feo and Fep in coarser aggregates (P less then 0.01). Importantly, the increase in contents of Feo and Fep in the 0.002-2 mm fraction were significantly correlated with content of Fe-/Mn-oxide-bound Cd (OX-Cd) in larger particle-size fractions (P less then 0.01). Furthermore, the increasing content of OX-Cd played a crucial role in reducing DTPA-Cd content. This study demonstrates that low pe + pH values favor the transformation of crystalline Fe oxides into a poorly-crystallized and organically-complexed phase, which facilitates Cd accumulation in coarser aggregates and enhances Cd stability in paddy soils.The effects of phenol on aerobic granular sludge including extracellular polymeric substances (EPS) and microbial community were investigated for low strength and salinity wastewater treatment. Elevated phenol over 20 mg/L stimulated biological phosphorus removal mainly via co-metabolism with nearly complete phenol degradation, whereas resulted in significant accumulation of nitrate around 4 mg/L. Aerobic granules kept structural stability via enhancing production of extracellular polymeric substances (EPS), especially folds of polysaccharides (PS) and varying functional groups identified through EEM, FTIR and XPS spectral characterizations at increasing phenol loads. Illumina MiSeq sequencing results indicated that elevated phenol decreased the bacterial diversity and richness, and caused remarkable variations in structural and compositions of microbial population. Multiple halophilic bacteria including Stappia, Luteococcus, and Formosa laid the biological basis for stability of aerobic granules and efficient biological nutrients and phenol removal. Redundancy analysis (RDA) suggested the key role of phenol in shaping the relative abundances and predominant genera. This study proved that aerobic granular sludge was feasible for low-saline and phenol-laden low-strength wastewater treatment.A city is the place where food, energy, and water consumption happen. This consumption leads to challenges and has a strong impact on natural sources. Although researchers broadly agree on the importance of incorporating the concept of the food, energy, and water nexus into policy strategies and decision-making, the assessment system for how governance methods can improve the provision of these three essential services is relatively blank. To clarify the policy mechanisms and heterogeneity of sustainability issues related to the food, energy and water nexus at the city level, this study develops an indicator system to guide the implementations and optimize urban sustainability. A qualitative approach is employed to form the priority strategies in in four selected cities Amsterdam, Eindhoven, Taipei, and Tainan. The results show that renewable energy plays an essential role in the food-energy-water nexus. link2 In addition, we also observed that future work should focus on technological innovation. These observations imply that the unique combination of influence factors in food-energy-water sustainability offers a comprehensive outlook of the broad and complex challenges that a city faces due to resource limitations, which can help inform future governance practices. Finally, some policy recommendations are made for highlighting and the activities needed to work. The results of the present evaluation could be used as a tool to strengthen food-energy-water management in the future. They can guide managers to develop possible solutions that ensure resources are applied successfully according to the visions of multiple perspectives and help the relevant ministries to improve future consultation plans.Barriers associated to human infrastructure are a widespread impact in freshwater ecosystems worldwide, disrupting connectivity along river networks and key processes. Restoration of connectivity has risen in the last decade, with thousands of dams, weirs and culverts removed. Spatial optimisation methods can help inform decision on what barriers to remove to maximise gain in connectivity under limited budgets. However, current optimisation approaches rely on programming skills that are not easily accessible to stakeholders, which restrict the use of these methods. We demonstrate how Marxan, a publicly available tool, can be used to prioritise the allocation of barrier removal projects. We mapped the distribution of >900 barriers in the Tagus River (Iberian Peninsula) and 29 freshwater fish species with different movement abilities and needs. We assessed the passability of each barrier by all species and relative removal cost. link3 We then identified priority barriers for removal to increase connectivity of populations of all species simultaneously.

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