Hernandezrosenberg0435

In the present research, the kaolin adsorbents (beneficiated, raw powder, and calcined) were prepared from Ethiopian natural kaolin through mechanical, wet, and thermal processes. The geochemical and surface properties of kaolin adsorbent were characterized using FTIR, SEM/EDS, XRD, and XRF. In the batch experiment, basic operation parameters (initial dye concentrations, pH, temperature, contact time, and adsorbent dosage) were examined. Percentage removal efficiency basic yellow 28 (BY28) dye were recorded as 94.79%, 92.08%, and 87.08% onto beneficiated, raw, and calcined kaolin absorbents, respectively at an initial dye concentration of 20 mg/L, solution pH of 9, the temperature of 30 °C °C , and contact time of 60 min and adsorbent dosage of 1g/100L. The molar ratio of SiO2/Al2O3 was recorded as 2.911 Percent mass composition of Ethiopian kaolin which is higher than the expected pure kaolinite standard which allows us to classify the kaolin clay as a siliceous one. The calculated values of Δ G 0 for benefiin adsorbents was found as 1.896, 1.842, and 1.742 mg/g, respectively at a contact time of 1.0 h, the adsorbent dosage of 1.0 g, initial dye concentration = 20 mg/L and solution pH = 9 at 30 °C. The results found that these raw and prepared local kaolin adsorbents have a capacity as low-cost alternatives for the removal of dyes in industrial wastewater.Gamification, recently considered as a science, takes advantage of the benefits of games to induce desirable behaviors in a given "normal" activity. When applied in education, it is an approach to motivate and engage students in their learning process by incorporating game design principles. This paper presents the design and deployment of a game conducted in parallel with two groups of the engineering course "operations research". The game design is theoretically supported, and unlike literature, the game proposed has the main distinguishing features (a) it is carried out in parallel with the standard course, where player participation is optional, with extrinsic motivators regarding the final grade, (b) it lasts the entire semester, and it was applied to different groups with the same instructor, (c) in addition to academic performance, it has other social relatedness desired outcomes, (d) it combines the use of specific game elements divided in three types of activities Mastery, related to the core topics of the class, Institutional, related to the university life and community, and Teamwork activities; and (e) it uses a WhatsApp chat group as the common communication platform. The assessment is twofold the effects on learning, measured in two indicators, failure rate and average grade; and the perception of the game itself. Statistical results present empirical evidence of the positive effects of gamification on academic performance and other desired behaviors of social relatedness, such as a sense of belonging and teamwork.Though innovations for sustainable management of natural resources have emerged over time, the rising demand for nature based health solutions and integration of endemic flora into global value chains could have adverse impacts on ecosystems. The ecological risks in the exploitation of the wild endemic medicinal plant resources are exacerbated by a myriad of agrotechnological risks and challenges that highly constrain their domestication. Successful exploitation and commercialisation of medicinal plants thus require a clear understanding of their demand and production systems or value chain analysis. Accordingly there is need for innovative approaches towards their integration into global value chains. Since quality and safety, traceability, certification, as well as consumer tastes and preferences are critical drivers in purchasing decisions by global consumers, they are inadvertently exploited to weaken Indigenous knowledge (IK), undermine common property rights and entrench value chains that favour a few elite buyers. This tend to create pervasive incentives for overexploitation of medicinal plant resources and environmental degradation. Potential solution lies in the recognition of drivers of vulnerability to environmental degradation and the innovative use of policy bricolage, feedback loops and interactions between knowledge, power and agency on one hand, and collective action and property rights institutions on the other hand. We conceptualise a framework that can mediate a transformational agenda and enhance systematic understanding of sustainability lenses in endemic medicinal plant resources value chains. This could strengthen IK, enhance collective action and promote participation of local actors with positive impact on the utilisation and integration of endemic medicinal plant resources into global value chains.Vehicular pollution in cities is engendering the need to enhance the sequestration of CO2 through bio-edaphic factors, such as trees and soil. Hence, this pioneering study aimed to analyze the interdependencies of the bio-edaphic ecosystem during carbon sequestration on a national highway in Guwahati, Assam, India. To quantify the tree carbon stock, soil physicochemical properties, soil nutrients, bulk density, organic carbon, and soil carbon stock, trees with diameters at breast height (dbh) ≥ 2 cm and soil samples from different depths (0-15 cm, 15-30 cm, and 30-45 cm) were taken from six areas spread over 36 plots of equal size (2 × 10 m) arranged in a zig-zag manner. selleck chemicals The studied parameters were compared among the different areas. It was found that the tree and soil carbon stock, along with soil nutrients, were greater in the Garchuk-Lokhra area (sample area-4). A significantly strong correlation was observed between the soil carbon stock and the above and below-ground biomass of trees (AGB, r = 0.865; BGB, r = 0.847), which indicated the co-dependencies of the bio-edaphic ecosystem in accumulating carbon. Peltophorum ferrugineum (Decne.) Benth is recommended for planting because it has emerged as a tolerant species and has the greatest carbon storage potential. The bio-edaphic ecosystem of the national highway is now on a carbon-friendly trajectory that follows the UNFCCC guidelines and the REDD+ (reducing emissions from deforestation and forest degradation) strategy. However further research on carbon budgeting is required.The environmental surface contamination by radioactive elements following a nuclear research reactor hypothetical accident is evaluated employing the hotspot code, IAEA safety guide, and NRC guidelines. Gaussian plume depositions of radioactive contaminants are calculated under very conservative assumptions for a worst-case accident scenario, and site most probable wind speed and metrological conditions. link2 Results reveal that the contamination strongly decreases with distance, dropping seven orders of magnitude from 2.2E+09 kBq/m2 at the reactor site to 9.5E+2 kBq/m2 60 km from the reactor at the plume centerline. In rainy weather, the wet deposition is depleted to 6.0E+2 kBq/m2 after 50 km, limiting the spread of contaminants to a much smaller area. Although the results of this work tend to overestimate the surface deposition of radionuclides, they present a clear insight into the radiological consequences of nuclear accident worst-case scenario. Thus, it assists with the development of a comprehensive emergency preparedness program by identifying all areas with potential risk to contamination.Fruit seed is a by-product of fruit processing into juice and other products. Despite being treated as waste, fruit seed contains oil with health benefits comparable or even higher than the conventional seed oil from field crops. In addition to essential fatty acids, the fruit seed oil is a rich source of bioactive compounds such as tocopherols, carotenoids, flavonoids, phenolic acids and phytosterols, which have been implicated in the prevention of chronic and degenerative diseases such as cancer, diabetes and cardiovascular diseases. The emerging potential of fruit seed oil application in food and nutraceuticals has prompted researchers to study the effect of preharvest and processing factors on the seed oil quality with respect to nutritional qualities, antioxidant compounds and properties. Herein, the effect of cultivar, fruit-growing region, seeds pretreatment, seeds drying and seed oil extraction on tocopherols, polyphenols, phytosterols, carotenoids, fatty acids, antioxidant activity and oxidative stability of the fruit seed oil is critically discussed. Understanding the influence of these factors on seed oil bioactive phytochemicals, nutritional qualities and antioxidant properties is critical not only for genetically improving the oilseeds plants with desired characteristics, but also in seed oil processing and value addition. Therefore, preharvest and processing factors are essential considerations when determining the application of fruit seed oil.The presence of internal rotation in sigma bonds is essential for conformational analysis of organic molecules and its understanding is of great relevance in chemistry, as well as in several other areas. However, for aromatic compounds that have substituent groups, withdrawers or donors of electron, there are no data in the literature to explain their rotational barriers. In this context, the work studied the internal rotational barriers of electron donating and withdrawing groups in aromatic compounds using the MP3, MP4, and CCSD(T) methods and the influence of substituents' nature on barrier heights was investigated through calculations based on the theory of Natural Bond Orbitals (NBO) and Quantum Theory of Atoms in Molecules (QTAIM). The results obtained showed that the CCSD(T) method is the one that best describes the internal rotational barriers, followed by MP4 and MP3 and the electron donating groups decrease the barrier, whereas electron withdrawing groups increase. Through the NBO analysis it was possible to observe that for withdrawing groups the interaction of the molecular orbitals is more accentuated promoting the increase of the rotational barrier of these compounds. Through the QTAIM analysis it was possible to show that, for electron donating groups, the internal rotation is influenced by the loss of electronic density when the substituents is perpendicular to the ring plane, however, for withdrawing groups the density is little influenced, regardless of the two conformations (minimum and maximum energy). Two molecules showed free rotation, trichloromethylbenzene and methylbenzene, and the theoretical calculations NBO and QTAIM showed that for these species there is no difference in the properties studied when there is rotation of the dihedral angle.Combination of arylidene hydrazinyl moiety with pyrido[2,3-d]pyrimidin-4-one skeleton in compounds 7‒26 results in the output of unprecedented anti-microbial agents. Arylidene hydrazinyl based on Pyrido[2,3-d]pyrimidin-4-one analoges 7‒26 prepared by the treatment of [2,3-d]pyrimidin-4-ones 6a,b with various aromatic aldehydes. The antimicrobial action for recently synthesized compounds was considered towards gram positive bacterial species (Staphylococcus aurous ATCC- 47077; Bacillus cereus ATCC-12228), gram negative bacterial species (Escherichia coli ATCC-25922; Salmonella typhi ATCC-15566) and Candida albicans ATCC-10231 as fungal strains. The antimicrobial action expanded by expanding the electron donating group in position 2 and 5 for Pyrido[2,3-d]pyrimidin-4-one core. link3 Derivatives 13, 14, 15, 16 and 12; individually appeared hopeful anti-microbial action towards all strains utilized with inhibition zone higher than that of standard reference drug with lowest MIC.