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Understanding of microplastics transport mechanism is highly important for soil contamination and remediation. The transport behaviors of microplastics in soils are complex and influenced by various factors including soil and particle properties, hydrodynamic conditions, and biota activities. Via a microfluidic experiments we study liquid film entrainment and microplastics transport and retention during two-phase displacement in microchannels with one end connected to the air and the other connected to the liquid with suspended particles. We discover three transport patterns of microplastic particles, ranging from no deposition to particle entrapment and to particle layering within liquid films, depending on the suspension withdrawal rates and the particle volume fraction in the suspension. The general behavior of particle motion is effectively captured by the film thickness evolution which is shown to be dependent on a modified capillary number Ca0 taking into account the effects of flow velocity, particle volume fraction, and channel shape. We also provide a theoretical prediction of the critical capillary number Ca0* for particle entrapment, consistent with the experimental results. In addition, the probability of microplastics being dragged into the trailing liquid film near the gas invading front is found to be proportional to both particle volume fraction and the capillary number. This work elucidates the microplastics transport mechanism during unsaturated flow, and therefore is of theoretical and practical importance to understand the contaminant migration in many natural and engineered systems spanning from groundwater sources to water treatment facilities.In this work, a rhamnolipid (RL) pretreatment technology was proposed to promote methane production from two-phase anaerobic digestion of waste activated sludge. link= selleck chemical In the first phase (i.e., acidogenic phase), the WAS hydrolysis and acidogenesis were significantly enhanced after RL pretreatment for 4 day, under which the concentration of soluble protein and the short-chain fatty acids (SCFA) in the presence of RL at 0.04 g/g TSS was respectively 2.50 and 5.02 times higher than that without RL pretreatment. However, methane production was inhibited in the presence of RL. In the second phase (i.e., methanogenic phase), batch biochemical methane potential tests suggested that the addition of RL is effective in promoting anaerobic methane production. With an increase of RL dosage from 0 to 0.04 g/g TSS, the cumulative methane yield increased from 100.42 ± 3.01 to 168.90 ± 5.42 mL. Although the added RL could be utilized to produce methane, it was not the major contributor to the enhancement of methane yield. Furtherdings reported not only expand the application field of RL, but also may provide supports for sustainable operation of wastewater treatment plants (WWTPs).Quorum sensing (QS) plays a crucial role during initial biofilm formation, however the QS threshold and the response of biofilm formation towards N-acyl-homoserine lactones (AHLs) remains largely unknown due to the limitation of nondestructive online methods for monitoring bacterial adherence and the complexity of QS system, which limits the application of QS signal reagents in biofilm reactors. In this study, bacterial QS threshold and its response of biofilm formation to AHLs in purely cultured Sphingomonas rubra biofilm as well as in three different wastewater biofilms #1-3 were investigated via real time cell analysis (RTCA). The main perspective was to study the biomass adherence in response to 12 different forms of AHLs at different concentrations. Results showed that bacterial adhesion was significantly improved by exogenous AHLs with the maximum increase of 2.26-, 2.36-, 2.52-, and 2.80- times biomass production in the four respective biofilms. Although the preferred form of AHL differed for various btion. selleck chemical According to the Pearson correlation analysis, 62% of the top 50 most abundant genera in bacterial communities were significantly negatively related to the response time of multiple AHLs, representing their fast QS response. The QS bacteria, Dechloromonas and Nitrospira have fast QS response for C4-HSL and C8-HSL while, Comamonadaceae has fast QS response for 3OC8-HSL, 3OC10-HSL, 3OC12-HSL, and 3OC14-HSL. In contrast, the rest 38% of the top most abundant genera, such as Ferruginibacter, Hyphomicrobium, and Terrimonas quickly responded to only one AHL, showing significant negative relationship with the response time of C6-HSL. Overall, this study provides an effective and convenient means to select appropriate AHL reagents to promote bacterial adhesion in biofilm systems. link2 Moreover, it also suggests that exogenous AHLs may be useful in improving the settling property of bulking sludge.PM2.5 in Shijiazhuang was collected from October 15, 2018 to January 31, 2019, and selected toxic elements were measured. Five typical haze episodes were chosen to analyze the health risks and critical risk sources. Toxic elements during the haze episodes accounted for 0.33% of PM2.5 mass. Non-cancer risk of toxic elements for children was 1.8 times higher than that for adults during the haze episodes, while cancer risk for adults was 2.5 times higher than that for children; cancer and non-cancer risks were primarily attributable to As and Mn, respectively. Health risks of toxic elements increased during the growth and stable periods of haze episodes. link2 Non-cancer and cancer risks of toxic elements during the haze stable periods were higher than other haze stages, and higher for children than for adults during the stable period. Mn was the largest contributor to non-cancer risk during different haze stages, while As was the largest contributor to cancer risk. Crustal dust, vehicle emissions, and industrial emissions were critical sources of cancer risk during the clean-air periods; while vehicle emissions, coal combustion, and crustal dust were key sources of cancer risk during the haze episodes. selleck chemical Cancer risks of crustal dust and vehicle emissions during the haze episodes were 2.0 and 1.7 times higher than those in the clean-air periods. link3 Non-cancer risks from emission sources were not found during different periods. Cancer risks of biomass burning and coal combustion increased rapidly during the haze growth period, while that of coal combustion decreased sharply during the dissipation period. Vehicle emissions, crustal dust, and coal combustion were significant cancer risk sources during different haze stages, cancer risk of each source was the highest during the stable period. Southern Hebei, Northern and central Shaanxi were potential risk regions that affected the health of both adults and children in Shijiazhuang.The space-borne measured fine-mode aerosol optical depth (fAOD) is a gross index of column-integrated anthropogenic particulate pollutants, especially over the populated land. link3 The fAOD is the product of the AOD and the fine-mode fraction (FMF). While there exist numerous global AOD products derived from many different satellite sensors, there have been much fewer, if any, global FMF products with a quality good enough to understand their spatiotemporal variations. This is key to understanding the global distribution and spatiotemporal variations of air pollutants, as well as their impacts on global environmental and climate changes. Modifying our newly developed retrieval algorithm to the latest global-scale Moderate Resolution Imaging Spectroradiometer (MODIS) aerosol product (Collection 6.1), a global 10-year FMF product is generated and analyzed here. We first validate the product through comparisons with the FMF derived from Aerosol Robotic Network (AERONET) measurements. Among our 169,313 samples, the satellite-derived FMFs agreed with the AERONET spectral deconvolution algorithm (SDA)-retrieved FMFs with a root-mean-square error (RMSE) of 0.22. Analyzed using this new product are the global patterns and interannual and seasonal variations of the FMF over land. In general, the FMF is large (>0.80) over Mexico, Myanmar, Laos, southern China, and Africa and less than 0.5 in the Sahelian and Sudanian zones of northern Africa. Seasonally, higher FMF values occur in summer and autumn. The linear trend in the satellite-derived and AERONET FMFs for different countries was explored. The upward trend in the FMFs was particularly strong over Australia since 2008. This study provides a new global view of changes in FMFs using a new satellite product that could help improve our understanding of air pollution around the world.The determination of both stable nitrogen (δ15N-NO3-) and stable oxygen (δ18O-NO3-) isotopic signatures of nitrate in PM2.5 has shown potential for an approach of assessing the sources and oxidation pathways of atmospheric NOx (NO+NO2). In the present study, daily PM2.5 samples were collected in the megacity of Beijing, China during the winter of 2017-2018, and this new approach was used to reveal the origin and oxidation pathways of atmospheric NOx. Specifically, the potential of field δ15N-NO3- signatures for determining the NOx oxidation chemistry was explored. Positive correlations between δ18O-NO3- and δ15N-NO3- were observed (with R2 between 0.51 and 0.66, p less then 0.01), and the underlying environmental significance was discussed. The results showed that the pathway-specific contributions to NO3- formation were approximately 45.3% from the OH pathway, 46.5% from N2O5 hydrolysis, and 8.2% from the NO3+HC channel based on the δ18O-δ15N space of NO3-. The overall nitrogen isotopic fractionation factor (εN) from NOx to NO3- on a daily scale, under winter conditions, was approximately +16.1‰±1.8‰ (consistent with previous reports). Two independent approaches were used to simulate the daily and monthly ambient NOx mixtures (δ15N-NOx), respectively. Results indicated that the monthly mean values of δ15N-NOx compared well based on the two approaches, with values of -5.5‰ ± 2.6‰, -2.7‰ ± 1.9‰, and -3.2‰ ± 2.2‰ for November, December, and January (2017-2018), respectively. The uncertainty was in the order of 5%, 5‰ and 5.2‰ for the pathway-specific contributions, the εN, and δ15N-NOx, respectively. Results also indicated that vehicular exhaust was the key contributor to the wintertime atmospheric NOx in Beijing (2017-2018). Our advanced isotopic perspective will support the future assessment of the origin and oxidation of urban atmospheric NOx.The measurement of 210Pb and 210Po in seafood samples has attracted tremendous interest because of their radiotoxicity. In this study, a fast and cost-efficient method for the simultaneous determination of 210Pb and 210Po in seafood samples by ultralow-level liquid scintillation counting after separation on a Sr•spec column was developed. The recoveries of 210Pb and 210Po were ~70% and ~85%, respectively. The minimum detectable activity of the proposed method for 210Pb and 210Po was 3.85 Bq/kg and 1.50 Bq/kg, respectively, which is suitable for the determination of 210Pb and 210Po in seafood samples. The radiochemical procedure was validated by measuring 210Pb and 210Po activity concentrations in IAEA-certified reference materials and successfully applied to shrimp and clam samples.

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