Haganbaxter4450

This result is mainly attributed to an increased quantum yield resulting from the Purcell enhanced radiative rate in the nanocrystals. The ease of fabrication, low cost, long-term stability and great emission properties of the hybrid nanoparticles make them a great candidate for bio-imaging or even targeted cancer treatment.The dynamics of the magnetic moment reversal is studied for ErFeO3 and NdFeO3 single crystals. The reversal occurs at 41 and 5.1 K for ErFeO3 and NdFeO3, respectively, at a field of 300 Oe. The dynamics of the magnetization reversal process depends on the temperature at which the reversal occurs. The reversal is abrupt if the thermal energy is far higher than the energy of Zeeman splitting of the rare earth ion levels by internal fields, as observed for ErFeO3. A gradual magnetization reversal occurs for NdFeO3 over 64 s, when the thermal energy at the temperature of the reversal is well below the Zeeman splitting energy of Nd3+ spins. A mechanism for this gradual magnetization reversal is proposed in terms of the thermal re-population of Zeeman doublets of Nd3+ ions, the splitting energy of which continuously changes during the magnetization reversal.Solutions of semiflexible polymers confined in cylindrical pores with repulsive walls are studied by Molecular Dynamics simulations for a wide range of polymer concentrations. Both the case where both lengths are of the same order and the case when the persistence length by far exceeds the contour length are considered, and the enhancement of nematic order along the cylinder axis is characterized. With increasing density the character of the surface effect changes from depletion to the formation of a layered structure. For binary 50  50 mixtures of the two types of polymers an interplay between surface enrichment of the stiffer component and the isotropic-nematic transition is found, and a phase separated structure with cylindrical symmetry occurs, with the isotropic phase located around the cylinder axis. For melt densities the mixed nematic phase forms at the wall a layer with a screw-like structure of a tilted smectic phase. The observed behavior is tentatively interpreted in terms of the competition of the chain orientational entropy with entropy of mixing and excluded volume due to the wall.The construction of anode materials for sodium-ion batteries (SIBs) and potassium-ion batteries (PIBs) with a high energy and a long lifespan is significant and still challenging. Here, sulfur-defective vanadium sulfide/carbon fiber composites (D-V5S8/CNFs) are designed and fabricated by a facile electrospinning method, followed by sulfuration treatment. The unique architecture, in which V5S8 nanoparticles are confined inside the carbon fiber, provides a short-range channel and abundant adsorption sites for ion storage. Moreover, enlarged interlayer spacings could also alleviate the volume changes, and offer small vdW interactions and ionic diffusion resistance to store more Na and K ions reversibly and simultaneously. The DFT calculations further demonstrate that sulfur defects can effectively facilitate the adsorption behavior of Na+ and K+ and offer low energy barriers for ion intercalation. find more Taking advantage of the functional integration of these merits, the D-V5S8/CNF anode exhibits excellent storage performance and long-term cycling stability. It reveals a high capacity of 462 mA h g-1 at a current density of 0.2 A g-1 in SIBs, while it is 350 mA h g-1 at 0.1 A g-1 in PIBs, as well as admirable long-term cycling characteristics (190 mA h g-1/17 000 cycles/5 A g-1 for SIBs and 165 mA h g-1/3000 cycles/1 A g-1 for PIBs). Practically, full SIBs upon pairing with a Na3V2(PO4)3 cathode also exhibit superior performance.Controlled bottom-up synthesis of amorphous coordination polymers with tailored metal coordination is a research field in its infancy. In this study, synthesis control was achieved to selectively prepare one-dimensional (1D) crystalline and amorphous zinc(ii)-based coordination polymers and a dimeric molecular compound, all with similar coordination geometry as evidenced by X-ray diffraction and total scattering studies. The compounds were obtained by bottom up self-assembly of Zn(ii) with terephthalate (tph2-) as linker and the enantiopure chelating ligand S-(1,2)-bis(1H-benzimidazol-2-yl)ethanol (L). The solvent and the coordination ability of the precursor zinc salt anion control the crystalline products formed by slow diffusion at room temperature perchlorate allows isolation of the phase pure crystalline 1D polymer [Zn(tph)(L)]·H2O·3DMFn (1·H2O·3DMF, DMF = N,N-dimethylformamide). In contrast, zinc chloride leads to the formation of either a mixture of polymeric 1·H2O·3DMF and a dimeric molecular species [Zn2Cl2(tph)(L)2]·4DMF (2·4DMF), or to the phase pure dimer 2·4DMF, depending on the Zn(ii)  tphH2 stoichiometry. A modified synthesis using zinc nitrate and fast precipitation by base addition results in an amorphous analogue of the 1D polymer (3). Chains of 1·H2O·3DMF pack into a non-porous crystalline material with a surface area of just 6 m2 g-1, while the outer surface area of amorphous polymer 3 is a factor of eight larger. Hence, the amorphous compound provides larger metal site accessibility for potential surface chemical reactions, while maintaining the coordination geometry of the metal sites. The temperature response of crystalline polymer 1·H2O·3DMF was studied using multi-temperature single crystal X-ray diffraction (100-300 K). The a = b axes display normal positive thermal expansion, while the c axis remains constant with increasing temperature due to partial relaxation of the terephthalate linkers and slightly changed geometry within the individual polymer chains.Inspired by the nanostructure of bone, biomimetic nanocomposites comprising natural polymers and inorganic nanoparticles have gained much attention for bone regenerative applications. However, the mechanical and biological performances of nanocomposites are largely limited by the inhomogeneous distribution, uncontrolled size and irregular morphology of inorganic nanoparticles at present. In this work, an innovative in situ precipitation method has been developed to construct a biomimetic nanocomposite which consists of spherical hydroxyapatite (HA) nanoparticles and gelatin (Gel). The homogeneous dispersion of HA nanoparticles in nHA-Gel endowed it with a low swelling ratio, enhanced mechanical properties and slow degradation. Moreover, strontium (Sr) was incorporated into HA nanoparticles to further enhance the bioactivity of nanocomposites. In vitro experiments suggested that nHA-Gel and Sr-nHA-Gel facilitated cell spreading and promoted osteogenic differentiation of bone-marrow-derived mesenchymal stem cells (BMSCs) as compared to pure Gel and mHA-Gel conventional composites developed by mechanical mixing.