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he shoulder joint and decreased rates of return to sport after rotator cuff repairs.The purpose of the present study was to perform a comprehensive scientific literature review and pooled data risk factor analysis of excited delirium syndrome (ExDS) and agitated delirium (AgDS). All cases of ExDS or AgDS described individually in the literature published before April 23, 2020 were used to create a database of cases, including demographics, use of force, drug intoxication, mental illness, and survival outcome. Odds ratios were used to quantify the association between death and diagnosis (ExDS vs. AgDS) across the covariates. There were 61 articles describing 168 cases of ExDS or AgDS, of which 104 (62%) were fatal. ExDS was diagnosed in 120 (71%) cases, and AgDS in 48 (29%). Fatalities were more likely to be diagnosed as ExDS (OR 9.9, p  less then  0.0001). Aggressive restraint (i.e. manhandling, handcuffs, and hobble ties) was more common in ExDS (ORs 4.7, 14, 29.2, respectively, p  less then  0.0001) and fatal cases (ORs 7.4, 10.7, 50, respectively, p  less then  0.0001). Sedation was more common in AgDS and survived cases (OR11, 25, respectively, p  less then  0.0001). The results of the study indicate that a diagnosis of ExDS is far more likely to be associated with both aggressive restraint and death, in comparison with AgDS. There is no evidence to support ExDS as a cause of death in the absence of restraint. These findings are at odds with previously published theories indicating that ExDS-related death is due to an occult pathophysiologic process. When death has occurred in an aggressively restrained individual who fits the profile of either ExDS or AgDS, restraint-related asphyxia must be considered a likely cause of the death.Thiophanate methyl is a broad-spectrum benzimidazole fungicide extensively applied in pre- and post-harvest, for the control of a wide range of fruit and vegetable pathogens. In the current work, the residue behavior of thiophanate methyl after application on strawberries and an estimation of the consumer dietary exposure was performed. Supervised field trials were conducted in Egypt (Qaluobiya Governorate) as to investigate the residue dynamics and terminal residues at different PHIs of thiophanate methyl and its metabolite carbendazim in strawberries under Egyptian conditions. For the measurement of residues in fruits, a QuEChERS-based protocol coupled with LC-MS/MS was optimized and successfully validated at 0.01 mg kg-1. The half-life (t1/2) of thiophanate methyl in strawberries was estimated, and a dietary risk assessment was performed employing both FAO/WHO and EFSA approaches.Rapid urbanization has been recognized as the primary cause of deteriorating water quality. Thus, it is crucial to take into account urbanization in water quality forecasting. The present study aims at finding the causal relationship between urbanization and water quality, and then predicting water quality based on this causality. For this purpose, nine urbanization indicators and 12 water quality parameters from 2006 to 2018 in Nanjing were collected as urbanization and water quality indices. Correlation and path analyses were firstly used to identify causal relationships between urbanization and water quality indices. Based on these causal relationships, comprehensive water quality indicators and their correlated urbanization parameters were input into a back-propagation neural network (BPNN) to predict water quality. In the improved BPNN, the R2 of the training sets were all greater than 0.99, and those of the test sets were all greater than 0.76, demonstrating that the optimized model is able to predict the water quality with reasonable accuracy. It also showed that the overall water quality in Nanjing will remain good from 2019 to 2028, which means that, when undergoing future urbanization process, water quality is not necessarily negatively affected. The transfer of industrial structure can have a positive influence on water quality. After 2028, the biological water environment index remained in a good state but the volatile phenol index continued to increase, making it a potential threat to future water quality. Industrial wastewater and fertilizer usage, as the primary sources of volatile phenols, should be prioritized for continued governmental control and monitoring into the future. This study provides new insight into the relationship between urbanization and water quality, and the presented models can assist in future-proofing water management strategies.The correct equations are presented below.The coronavirus (COVID-19) pandemic is infecting the human population, killing people, and destroying livelihoods. This research sought to explore the associations of daily average temperature (AT) and air quality (PM2.5) with the daily new cases of COVID-19 in the top four regions of Spain (Castilla y Leon, Castilla-La Mancha, Catalonia, and Madrid). To this end, the authors employ Pearson correlation, Spearman correlation, and robust panel regressions to quantify the overall co-movement between temperature, air quality, and daily cases of COVID-19 from 29 February to 17 July 2020. Overall empirical results show that temperature may not be a determinant to induce COVID-19 spread in Spain, while the rising temperature may reduce the virus transmission. However, the correlation and regression findings illustrate that air quality may speed up the transmission rate of COVID-19. Our findings are contrary to the earlier studies, which show a significant impact of temperature in raising the COVID-19 spread. The conclusions of this work can serve as an input to mitigate the rapid spread of COVID-19 in Spain and reform policies accordingly.We have reported the removal performance from the synthetic aqueous solution of copper of a low-cost and eco-friendly biochar (WHC) produced by facile thermal pyrolysis of wild herbs (WH), a new feedstock, at 550 °C under anoxic conditions. The characteristics of WHC were determined by physicochemical techniques. It exhibited a low BET surface area, total pore volume, and mean pore size of 16.45 m2/g, 0.01 cm3/g, and, 2.34 nm respectively. Batch sorption studies were performed by examining the effects of varying pH, WHC dosage, initial Cu(II) concentrations, interaction time, and temperature to determine optimum removal conditions. In modeling of sorption, data were used the pseudo-first- and pseudo-second-order kinetics and the Langmuir and Freundlich isotherm models. GSK1120212 The maximum Cu(II) sorption capacity of WHC was 24.21 mg/g. Thermodynamic parameters were computed for predicting the nature of WHC-Cu(II) sorption system.