Grantdodson4263

To deal with the threat of urban flooding, it is necessary to assess the flood resilience of urban drainage systems at the planning and design stage. This study proposes a system resilience assessment methodology based on a 'do-nothing' benchmark. In this new benchmark, the number of flooded nodes used in computation of mean flood duration in the system is that observed under a 'do-nothing' scenario (i.e. with no intervention), irrespective of the scenario under evaluation. This methodology is demonstrated using a case study in Chizhou city, China, a simple stormwater drainage network with seven subcatchments. Schemes of interventions (with distributed storage tanks) that aim to mitigate flooding are then produced by zero-one integer programming and schemes sampling. The results show that the proposed method can compute the mean flood duration and system resilience reasonably and helps identify effective intervention schemes. Compared with traditional methods, this resilience assessment method based on a 'do-nothing' scenario can correctly indicate the change in trend of system resilience provided by different schemes, and aids understanding of different interventions to improve system resilience to urban flooding. This study also provides a new way to test different interventions and to explore which provide the greatest improvement in system resilience.Chromate and phosphate are contaminant frequently present in industrial effluents such as tanneries. The objective of this work is to evaluate the efficiency of different operational combinations with dolomite and banana peel for the adsorption of phosphate and chromate in binary solutions. Both adsorbents are residuals from construction and food industries, respectively. Therefore, its use propitiates the reduction of treatment costs and it is an approach to the premises of the circular economy. In this work, the dolomite and banana peel adsorption efficiencies in simple and binary systems were studied. Equilibrium and kinetics tests were carried out in batch and in a fixed bed reactor. Dolomite was found to be selective for the adsorption of phosphate and banana peel for that of chromate. The mixture of adsorbents produced similar phosphate and chromate removal than each adsorbent individually. Therefore, the removals of both contaminants from binary solutions were tested using a fixed bed reactor filled with the mix of adsorbents and the breakthrough curves were analyzed. The obtained removals were 99% of phosphate and 70% of chromate. Finally, a brief discussion was held on the reuse and disposal of saturated adsorbents.Concentrations of genetic markers for antibiotic resistance genes (ARGs) were measured in the effluents of three Norwegian wastewater treatment plants (WWTPs) and in a receiving river upstream and downstream of the discharge point of one WWTP. Calculations based on mass balances were carried out to evaluate the impact of river flow rates and treatment effectivity on the WWTP's contribution to the load of genetic markers in the river. At average river flow rates, the WWTP effluent contributes 5-15% to the genetic marker load of the respective river. However, at minimum river flow rates, the WWTP effluent contributes 22-55% to the loads of different genetic markers. Scenarios of an improved or worsened removal of genetic markers in the WWTP showed that a further 1-log removal using additional treatment would be sufficient to improve considerably the river water quality with respect to genetic markers. Then, at an average flow rate, the contribution of the WWTP effluent to the load of the river would be less than 2%. However, in the case of low treatment effectivity or malfunction of the WWTP, the marker load of the river would increase dramatically. MYCi361 Even at average flow rate, 75-92% of the marker load would then originate from the WWTP. The results demonstrate the importance of considering the flow rates and hydrologic characteristics of the recipient water body when deciding on priorities regarding the upgrade of WWTPs for further removal of ARGs.Environmental impacts from coal-fired power generation that produces large amounts of CO2 and fly ash are of great interest. To reduce negative environmental impacts, fly ash utilization was investigated via a direct aqueous carbonation with a low-energy input in which the alkali calcium content in the fly ash reacted with CO2 to form carbonate. Raw fly ash was characterized to understand the potential for direct aqueous carbonation of fly ash. The performance of the fly ash as a calcium source for direct aqueous carbonation at atmospheric pressure was investigated for different solid-liquid ratios and introduced CO2 concentrations. Variations in fly ash elemental composition, reaction solution pH, CO2 concentration in the reactor outlet, CO2 uptake efficiency, CaCO3 content and degree of carbonation were used to illustrate this process reaction. The maximum CO2 uptake efficiency was ~0.016 g-CO2/g-fly ash. This value was compared with previous studies, and the CO2 uptake efficiency was comparable despite the use of a low-energy input method, i.e., direct aqueous carbonation with atmospheric pressure and unconcentrated CO2. The calculated maximum degree of carbonation was 31.0%, which corresponds to 0.0063 g-CO2/g-fly ash. Carbonated product characterization confirmed the carbonation reaction mechanism and safety for further utilization. A comparison of CO2 uptake efficiency in this work with previous work, and considering the energy input and reactive species content, is provided. An assessment of the CO2 reduction potential is provided.In this review, bibliometric analysis was made of recent studies and current trends concerning the application of lignocellulosic materials as bioadsorbents for the removal of arsenic from aqueous systems. Evaluation was made of lignocellulosic adsorbents and their chemical characteristics, as well as interactions involved in the adsorption of arsenic, bioadsorbent reusage (desorption and re-adsorption), competition between co-existing ions in multi-element aqueous solutions, and applications of bioadsorbents in batch and continuous systems. Lignocellulosic biomass has been shown to be a promising source of new adsorbents, since it is a low-cost and renewable material. However, there seems to be no commercially available technology that uses bioadsorbents based on lignocellulosic biomass for arsenic removal. In addition, the structural modification of lignocellulosic biomass to improve its adsorption capacity and selectivity has proved to be a suitable strategy, with the service time and the selectivity of tho pilot-scale experiments with real contaminated water with low arsenic concentration; and iii) the life-cycle assessment of biosorbents produced from lignocellulosic biomass.The presence of nonylphenol (NP) in the wastewater of the tank truck cleaning industry is a major concern because of its endocrine disruptive properties. In this paper, the use of ozone for degrading NP from tank truck cleaning wastewater was investigated by operating a pilot-scale biological wastewater treatment in combination with an ozonation unit. The impact of the added ozonation step on the removal of NP, soluble chemical oxygen demand (sCOD) and total organic carbon (TOC) was monitored over one year. sCOD and TOC removal were not significantly enhanced, but the NP peak concentrations in the effluent were significantly lower than those obtained after biological treatment only a relatively low NP concentration was observed, even when peak loads were present in the influent of the pilot-scale biological wastewater treatment plant (influentbio). Contrariwise, the effluent of the sole biological treatment follows the peak load trends of the influentbio. During the ozonation period, the average NP concentration in the combined biological-ozone unit was 0.29 μg/L, compared to 1.89 μg/L for the effluent obtained after a sole biological treatment, resulting in an improved average removal efficiency of 32%.Phytoremediation is a sustainable technology capable of efficiently removing low or moderate contamination. However, complex pollution conditions can drastically reduce efficiency, as plants can show themselves sensitive to organic contaminants, growing slowly and thus impairing metals' absorption. In cases where the action of indigenous bacteria degrading hydrocarbons and promoting plant growth is not sufficient, more sophisticated strategies are necessary. This investigation aims to evaluate the effectiveness of a train of technologies that sees advanced phytoremediation in combination with other biological approaches to remediate soil from a disused industrial area contaminated by N-containing compounds, alkyl aromatic hydrocarbons, copper, and nickel. In particular, a stepwise procedure was used with a pre-treatment (landfarming and bioaugmentation), significantly affecting the soil's fertility, increasing germinability up to 85%, and allowing the plants to extract the metals adequately. Furthermore, with EDTA as a mobilizing agent, nickel absorption has increased up to 36% in Helianthus annuus and up to 88% in Zea mays. For copper, an increase of up to 262% in Helianthus annuus and up to 202% in Zea Mays was obtained. Analysis through Fourier-Transform Ion Cyclotron Resonance Mass Spectrometry highlighted the biodegradation of some of the N-containing compounds recording, after phytoremediation, a decrease of up to almost 90%. Metagenomic analysis of the soil showed a typical microbial population of oxidizing hydrocarbon strains with a prevalence of the Nocardiaceae family (43%). The results obtained appear to confirm the usefulness of the approach developed, and the employed cutting-edge analytical techniques allowed a top-notch characterization of the remediation scenario.Photocatalytic removal of estrogenic compounds (ECs), 17β-estradiol (E2), and 17α-ethinylestradiol (EE2) were assessed using a TiO2-ZnO nanocomposite (NC) over a range of initial EC concentration (Co; 10 mg/L - 0.05 mg/L). Photocatalytic removal was evaluated under UV and visible irradiation using 10 mg/L NC over 240 min duration. After 240 min, analysis using GCxGC TOF MS revealed 100% transformation at Co ≤ 1 mg/L and ≥25% transformation at Co ≤ 10 mg/L under visible irradiation. Degradation was accompanied by breakdown of the fused ring structure of E2, generating smaller molecular weight by-products which were subsequently mineralized as revealed through TOC removal. With UV photocatalysis, ~30% and ~20% mineralization was attained for E2 and EE2, respectively, for Co of 10 mg/L. Under visible irradiation, ~25% and ~10% mineralization was achieved for E2 and EE2, respectively. Estrogenicity variation was estimated using the E-screen assay conducted with estrogen receptor-positive MCF-7 breast cancer cells. Complete removal of estrogenicity of ECs was confirmed after 240 min of photocatalysis under UV and visible irradiation. FTIR spectroscopy-based analysis of the NC after E2 photocatalysis revealed the presence of sorbed organics. Desorption, followed by GC × GC TOF-MS analysis revealed these organics as by-products of photocatalysis. Desorption of sorbed organics followed by recalcination at 600 °C for 1 h regenerated the active sites on the NC, enabling its efficient reuse for 3 cycles under visible irradiation without loss in activity.