Gibbonsmathews2360

Soilborne microplastics can persist for decades and their consequences are of growing concern. Therefore, it is important to explore the feasible approaches for eliminating microplastic effects on soil properties. Through an incubation experiment, we evaluate the effects of thermal treatment on physical properties, enzymatic activities and microbial communities in polyester-microfibers contaminated soils. The effects of polyester-microfiber levels (0%, 0.1%, 0.3% and 1.0% of soil dry weight) on soil properties were detected under not heated (PMF), heated (mPMF) and added with natural-organic-matters (OM) following heated (mPMF+OM) conditions. Our results showed that 1.0% mPMF soil had lower bulk density and higher mean weight diameter than 0% mPMF soil, akin to PMF soils. Meanwhile, great volumes of less then 30 µm pores in 0.3% and 1.0% mPMF soils were observed than that in 0% mPMF soil. Additionally, the dose-effects of melted polyester-microfiber on soil enzymatic activities and bacterial communities were still observed following thermal treatment, even under the OM added condition. Furthermore, our results demonstrated that polyester microfibers influenced soil microbial communities and functioning via altering specific soil physical properties, regardless of thermal treatment or not. Results of this study should be useful to guide further develop viable methods for remediating soils contaminated with microplastics.It is critical to developing low-cost and efficient catalysts to activate peroxymonosulfate for the degradation of organic contaminants, whereas it remains challenging. In the study, a recycle method to synthesize efficient heterogeneous catalysts was developed by exploiting the anode electrode of spent lithium-ion batteries as the raw material based on a one-step calcination process. The recycled anode material (AM) composed of copper oxide and graphite carbon was capable of efficiently activating peroxymonosulfate (PMS) to degrade a wide range of organic contaminants. In addition, an investigation was conducted on the effect of reactive parameters (e.g., catalyst dose, PMS dose, RhB concentration, and coexisting matters). KPT 9274 Besides, the AM/PMS process could exhibit high effectiveness at a broad pH range (3-10) and in a real water matrix. The redox cycle of Cu(II)/Cu(I) in the AM acted as the predominated force to effectively facilitate the PMS activation for the formation of oxygen species, in which the SO4·- and 1O2 exerted a primary effect. Moreover, the non-radical pathway of electron transfer between RhB and PMS facilitated the removal of RhB. In this study, a reclamation approach was developed for the recycling of spent LIBs anodes, and insights into the development of catalysts in SR-AOPs were gained.Although short-term exposure to air pollution can trigger sudden heart attacks, evidence is scarce regarding the relationship between sub-daily changes in air pollution level and the risk of acute myocardial infarction (AMI). Here we assessed the intraday effect of air pollution on AMI risk and potential effect modification by pre-existing cardiac risk factors. Hourly data on emergency department visits (EDVs) for AMI and air pollutants in Brisbane, Australia during 2013-2015 were acquired from pertinent government departments. A time-stratified case-crossover analysis was adopted to examine relationships of AMI risk with hourly changes in particulate matters (aerodynamic diameter ≤ 2.5 μm (PM2.5) and ≤10 μm (PM10)) and gaseous pollutants (ozone and nitrogen dioxide) after adjusting for potential confounders. We also conducted stratified analyses according to age, gender, disease history, season, and day/night time exposure. Excess risk of AMI per 10 μg/m3 increase in air pollutant concentration was reported at four time windows within 1, 2-6, 7-12, and 13-24 h. Both single- and multi-pollutant models found an elevated risk of AMI within 2-6 h after exposure to PM2.5 (excessive risk 12.34%, 95% confidence interval (CI) 1.44%-24.42% in single-pollutant model) and PM10 within 1 h (excessive risk 5.21%, 95% CI 0.26%-10.40% in single-pollutant model). We did not find modification effect by age, gender, season or day/night time, except that PM2.5 had a greater effect on EDVs for AMI during night-time than daytime. Our findings suggest that AMI risk could increase within hours after exposure to particulate matters.Heavy metal pollution is becoming recurrent and threatens biota biosafety in many agricultural fields. Diverse solutions explore the application of amendments to enable remediation. Sulfur represents a nonmetallic chemical element that actively affects heavy metals phytoextraction, and promotes and alternatively mitigates soil functions. In this study, we conduct a meta-analysis to synthesize the current knowledge on the influence of sulfur amendments on plants heavy metals uptake from contaminated soil media. Random-effects model was used to summarize effect sizes from 524 data points extracted from 30 peer reviewed studies. The phytoextraction of cadmium, chromium and nickel were 1.6-, 3.3-, and 12.6-fold, respectively, higher when sulfur amendment was applied; while copper uptake was 0.3-fold lower. Irrespective of the sulfur type, heavy metal extraction increased with the raising sulfur stress. Individual organs showed significant differences of heavy metal uptake between sulfur applied and non-sulfur treatments, and combined organs did not. The heavy metals uptake in leaves and roots were higher in sulfur applied than non-sulfur applied treatments, while those in grain, husk, and stalks were lower. The heavy metals phytoextraction (response ratio) followed the order roots > leaves > stalk > grain > husk. Moreover, heavy metals uptake was 2-fold higher in the sulfur applied than the non-sulfur treatments under ideal (5.5-8) and alkaline conditions (8-14), and 0.2-fold lower under acidic pH (1-5.5). Cadmium, manganese and nickel, and chromium were the most extracted under sulfur application by Vicia sp., Sorghum sp. and Brassica sp., respectively; while chromium, manganese, and iron were the most uptake without sulfur amendments by Oryza sp., Zea sp. and Sorghum sp., respectively. Our study highlights that the influence of sulfur on heavy metal phytoextraction depends on the single or combined effects of sulfur stress intensity, sulfur compounds, plant organ, plant type, and soil pH condition.Despite a growing focus on anthropogenic toxic metal pollution in urban environments, few studies have addressed the problem of quantification when more than two pollution sources are likely present, particularly within complex urban settings in the United States (U.S.). In this study, we utilize the MixSIAR package in R for source apportionment based on Pb isotopic signatures in lichen and road sediment in two urban-industrial centers in SW Ohio (OH). We show that ranges of pollutant contributions are more useful than only visualizing mean or raw values of source apportionment, because this avoids overinterpretation of data when certain sources have a large range of uncertainty. We point out both the dominance of industrial pollution as well as the legacy of leaded gasoline pollution in typical mid-sized U.S. cities, which is evident in both road sediment and lichens. Leaded gasoline contribution to Pb in Middletown, OH lichens mostly vary between ~10 and 25%, while in Hamilton, OH the contribution to lichens and road sediment tends to be relatively negligible except for two road sediment samples and one lichen sample, where median contributions are ~20-30%. Industrial combustion pollution source contributions vary between ~25 and 75% in Hamilton, and ~50-100% in Middletown, OH. Furthermore, comparing pollution sources in lichens to modern particulate matter can provide a record of how pollutant sources change over time, such as our traffic lichen (Sample Li-9) plotting closer to leaded gasoline on a bivariate mixing diagram than modern traffic particulate matter, or our coke plant lichen containing slightly less Pb contribution from industrial combustion sources relative to modern coke plant particulate matter. Lastly, when applicable, multi-source mixing models should be complimented in future studies with additional isotopic source tracers such as Cu, Zn, Nd, and Os to further elucidate unique sources of metal pollutants in addition to Pb.Known as a cause of food poisoning, Bacillus cereus (B. cereus) is widespread in nature. Cereulide, the heat-stable and acid-resistant emetic toxin which is produced by some B. cereus strains, is often associated with foodborne outbreaks, and causes acute emetic toxicity at high dosage exposure. However, the toxicological effect and underlying mechanism caused by chronic low-dose cereulide exposure require to be further addressed. In the study, based on mouse model, cereulide exposure (50 μg/kg body weight) for 28 days induced intestinal inflammation, gut microbiota dysbiosis and food intake reduction. According to the cell models, low dose cereulide exposure disrupted the intestinal barrier function and caused intestinal inflammation, which were resulted from endoplasmic reticulum (ER) stress IRE1/XBP1/CHOP pathway activation to induce cell apoptosis and inflammatory cytokines production. For gut microbiota, cereulide decreased the abundances of Lactobacillus and Oscillospira. Furthermore, cereulide disordered the metabolisms of gut microbiota, which exhibited the inhibitions of butyrate and tryptophan. Interestingly, cereulide exposure also inhibited the tryptophan hydroxylase to produce the serotonin in the gut and brain, which might lead to depression-like food intake reduction. Butyrate supplementation (100 mg/kg body weight) significantly reduced intestinal inflammation and serotonin biosynthesis suppression caused by cereulide in mice. In conclusion, chronic cereulide exposure induced ER stress to cause intestinal inflammation, gut microbiota dysbiosis and serotonin biosynthesis suppression. IRE1 could be the therapeutic target and butyrate supplementation is the potential prevention strategy.In soils, the presence of clinically relevant bacteria carrying ARGs, including extended-spectrum β-lactamase- and plasmid-mediated AmpC β-lactamase-encoding genes, is an underestimated public health problem that requires more attention. For this investigation, 300 samples from agricultural and non-agricultural soils were used to obtain 41 MDR E. coli isolates, standing out the resistance to β-lactams, fluoroquinolones and colistin. Virulence genes related to diarrheagenic E. coli and extraintestinal pathogenic E. coli were detected. Several ARGs were found, highlighting the presence of at least one β-lactamase-encoding gene (blaTEM, blaCMY, blaSHV, blaOXA-1-like, blaCTX-M-2, and/or blaCTX-M-15) in each isolate. Among the fluoroquinolone-resistant E. coli isolates, the plasmid-mediated quinolone resistance genes (qnrB and oqxA) and substitutions in the quinolone resistance-determining regions were detected. Some isolates were resistant to colistin (MICs of 4-8 mg/L) and, although no mcr-like gene was detectedcrobial resistance surveillance.Rice plants accumulate Hg from the soil and ambient air, however, evaluating the contribution of Hg from these two sources remains challenging. Here, we proposed a practical method to predict the contribution of total gaseous mercury (TGM) to Hg in white rice in Wanshan Hg mine area (WMM). In this study, rice was planted in the same low-Hg soil at different sites of WMM with varying TGM levels. Comparing to the control sites at IG (Institute of Geochemistry, Guiyang), TGM is the dominant source of Hg in rice leaves and white rice at TB (Tianba) and ZJW (Zhangjiawan) sites of WMM. Subsequently, a good correlation between the Hg concentrations in rice leaves and the concentration contributions of TGM to Hg in white rice was obtained. Such a correlation enabled feasible quantification of the contribution of TGM to Hg in white rice collected from the Wanshan Hg mine. The contribution of TGM to Hg in white rice across the WMM area was also estimated, demonstrating that white rice receives 14-83% of Hg from the air.