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During the summer season, when beach use increases, the highest total litter concentration was found. Undefined and/or beach use-related sources were dominant in all sites and seasons. Mapping the predominant materials, types and potential sources of litter creates important baseline data that can contribute not only to beach monitoring, but also to the development of litter reduction strategies.A key challenge for phytoextraction is the identification of high efficiency, growth-supporting, and low cost chelating agents. To date, no substance has satisfied all above criteria. This study investigated nine traditional Chinese herbs and found that Phyllanthus emblica fruit (FPE) extract could be utilised as an optimal chelate for the phytoextraction of cadmium (Cd)-contaminated soils. FPE application into soil at a ratio of 0.1% (w/w) significantly increased extractable Cd (by 43%) compared to the control. The success of FPE as a chelating agent was attributed to high quantities of polyphenol compounds (0.76%) and organic acids (9.6%), in particular, gallic acid (7.6%). Furthermore, antioxidative properties (1.4%) and free amino acids in FPE alleviated Cd-induced oxidant toxicity and enhanced plant biomass. FPE promoted 78% higher phytoextraction efficiency in Platycladus orientalis compared to traditional chelating agents (EDTA). Furthermore, 76% of FPE was degraded 90 days after the initial application, and there was no difference in extractable Cd between the treatment and control. FPE has been commercially produced at a lower market price than other biodegradable chelates. As a commercially available and cost-effective chelator, FPE could be utilised to treat Cd-contaminated soils without adverse environmental impacts.The growth of Artificial Light At Night (ALAN) is potentially having widespread effects on terrestrial and coastal habitats. In this study we addressed both the individual effects of ALAN, as well as its combined effect with predation risk on the behaviour of Concholepas concholepas, a fishery resource and a keystone species in the southeastern Pacific coast. We measured the influence of ALAN and predation risk on this mollusc's feeding rate, use of refuge for light and crawling out of water behaviour. These behavioural responses were studied using light intensities that mimicked levels that had been recorded in coastal habitat exposed to ALAN. Cues were from two species known to prey on C. concholepas during its early ontogeny the crab Acanthocyclus hassleri and the seastar Heliaster helianthus. The feeding rates of C. concholepas were 3-4 times higher in darkness and in the absence of predator cues. In contrast, ALAN-exposed C. concholepas showed lower feeding activity and were more likely to be in a refuge than those exposed to control conditions. In the presence of olfactory predator cues, and regardless of light treatment, C. concholepas tended to crawl-out of the waterline. We provide evidence to support the hypothesis that exposure to either ALAN or predation risk can alter the feeding behaviour of C. concholepas. However, predator cue recognition in C. concholepas was not affected by ALAN in situations where ALAN and predator cues were both present C. concholepas continued to forage when predation risk was low, i.e., in darkness and away from predator cues. Whilst this response means that ALAN may not lead to increased predation mortality in C. concholepas, it will reduce feeding activity in this naturally nocturnal species in the absence of dark refugia. Such results may have implications for the long-term health, productivity and sustainability of this keystone species.The aim of this article was to assess whether and how BARX1 affects the progression of malignant phenotype of endometrial carcinoma (EC) cells. BARX1 levels and its prognostic value were evaluated using the EC-related RNA sequence dataset from The Cancer Genome Atlas (TCGA) database. Functional experiments were performed to evaluate the biological roles of BARX1 in EC HEC-1-A and KLE cells by silencing BARX1. BARX1 was upregulated in EC tissues according to the public database and in EC cells. High expression of BARX1 led to a poor prognosis and significantly related to clinical stage, pathological grade, death, histological subtypes, and menopause status in patients with EC. Silencing BARX1 notably suppressed the aggressive phenotypes of EC cells, as evidenced by inhibiting cells viability, growth, invasion and migration. Imatinib molecular weight Furthermore, depletion of BARX1 decreased the phosphorylation (p) levels of ERK and MEK, also reinforced the suppressive effects of ERK/MEK pathway blocker PD98059 on the p-ERK and p-MEK levels. Together, our results demonstrated that BARX1 functions as a carcinogen by regulating the cell viability, invasion, and migration at least partly through the ERK/MEK pathway.Cancer is the second leading cause of death worldwide and accounted for an estimated 9.6 million deaths, or 1 in 6 deaths, in 2018. Despite recent advances in cancer prevention, diagnosis, and treatment strategies, the burden of this disease continues to grow with each year, with dire physical, emotional, and economic consequences for all levels of society. Classic characteristics of cancer include rapid, uncontrolled cell proliferation and spread of cancerous cells to other parts of the body, a process known as metastasis. Transient receptor potential melastatin 7 (TRPM7), a Ca2+- and Mg2+-permeable nonselective divalent cation channel defined by the atypical presence of an α-kinase within its C-terminal domain, has been implicated, due to its modulation of Ca2+ and Mg2+ influx, in a wide variety of physiological and pathological processes, including cancer. TRPM7 is overexpressed in several cancer types and has been shown to variably increase cellular proliferation, migration, and invasion of tumour cells. However, the relative contribution of TRPM7 kinase domain activity to cancer as opposed to ion flux through its channel pore remains an area of active discovery. In this review, we describe the specific role of the TRPM7 kinase domain in cancer processes as well as mechanisms of regulation and inhibition of the kinase domain.In this study, structured photocatalytic systems were successfully developed by a facile method based on Alginate molds and a wet-spinning/cross-linking technique, yielding commercial photocatalyst (Degussa P25) in the form of all-ceramic hollow fibers (HFs). Taking advantage of alginate's exceptional sorption properties, copper augmented HFs were also developed. The structured photocatalysts were thoroughly characterised by a variety of techniques, including nitrogen adsorption, SEM/EDS, XRD, XPS and Raman. Synthesis and heat treatment parameters were found to affect the fibers' properties, allowing their optimization. Treatment at 600 °C under Ar was found to produce the best performing photocatalysts in terms mechanical stability, resistance to attrition and photocatalytic performance. Ca-Alginate precursors led to structures with increased mechanical stability, while Cu-Alginate decorated the surface of the photocatalyst with highly dispersed copper nanoparticles, in the state of metallic and CuO. The developed materials were photo-catalytically active, while the copper decorated ceramic HFs exhibited the highest MO adsorption and photocatalytic degradation performance, reaching a MO removal of 73.4%. The synergestic effect of adsorption on the MO degradation performance was also noticed. Moreover, the copper addition facilitated the photocatalytic process by improving the electron-hole separation and inhibiting the recombination effects. The presence of carbon residue was also beneficial, enhancing the MO sorption on the photocatalysts. It is noteworthy that the structured photocatalysts retained their efficiency for at least four photocatalytic cycles. The prepared ceramic HFs exhibited enhanced mechanical properties and excellent resistance to attrition after subsequent cycles, rendering them excellent candidates for application in industrial wastewater processes.The rapidly growing demand for lithium has resulted in a sharp increase in its price. This is due to the ubiquitous use of lithium-ion batteries (LIBs) in large-scale energy and transportation sectors as well as portable devices. Recycling of the LIBs for being the supply of critical metals hence becomes environmentally and economically viable. The presently used approaches for the recovery of spent LIBs like pyrometallurgical process can effectively recover nickel, cobalt, and copper, while lithium is usually lost in slag. Bioleaching process as an alternative method of extraction and recovery of valuable metals from the primary and secondary resources has been attracting a large pool of attraction. This method can provide higher recovery yield even for low concentration of metals which makes it viable among conventional methods. The bioleaching process can work with lower operating cost and consumed water and energy along with a simple condition, which produces less hazardous by-products ultimately. Here, we comprehensively review the biological and chemical mechanisms of the bioleaching process with a conclusive discussion to help how to extend the use of bioleaching for lithium extraction and recovery from the spent LIBs with a focus on recovery yields improvement. We elaborate on the three main types of the reported bioleaching with considering effective parameters including temperature, initial pH, pulp density, aeration, and medium and cell nutrients to sustain microorganism activity. Finally, practical challenges and future opportunities of lithium are discussed to inspire future research trends and pilot studies to realize the full potential of lithium recovery using sustainable bioleaching processes to extend a clean energy future.As the marine industry develops, the importance of seawater treatment process is increasing. To treat seawater, oxidation processes have primarily been used, such as ballast water treatment systems, aquaculture farm operations, aquarium management, and seawater desalination. However, dissolved organic matter in seawater, whose characteristics vary spatially and seasonally, affects the efficiency of oxidation processes. Therefore, in this study, seawater samples were acquired from various locations in the Republic of Korea to understand the spatio-temporal patterns of marine dissolved organic matter. It was reported that the characterization of marine dissolved organic matter using liquid chromatography-organic carbon detector and excitation-emission matrix-parallel factor modeling. Furthermore, the effects of marine dissolved organic matter were evaluated on ozonation, an oxidation process. The results demonstrate that marine dissolved organic matter varies in its aquagenic, pedogenic, and intermediate characteristics based on region and season. These variations affect ozonation by influencing the consumption of oxidants (e.g., bromine). As a result, it was concluded that characterizing marine dissolved organic matter can help improve the effectiveness of oxidation processes, particularly ozonation.A zinc-blende/wurtzite (ZB/WZ) copper indium sulfide (CuInS2/CIS) polymorph with high visible-light absorption ability and high charge separation rate was developed by using a facile polyol method. Results showed that when thioacetamide served as a sulfur precursor, the crystalline phase of CIS was zinc-blende. Meanwhile, when thiourea served as a sulfur precursor, the crystalline phase of CIS was wurtzite, which exhibited good photocatalytic acid red 1 (AR1) dye decolorization efficiency. When the precursor/ethylene glycol ratio was 1/50-7/50, the AR1 decolorization efficiency followed the order T-5-CIS > T-7-CIS > T-3-CIS > T-1-CIS, and the TOC removal efficiency of T-5-CIS was 45.7%. The PL and EIS analyses indicated that T-5-CIS showed the highest charge separation rate. Mott-Schottky analysis demonstrated that the remarkably enhanced photocatalytic decolorization rate was ascribed to the stronger reduction potential of CIS with the mixed ZB/WZ phases and the redox potential difference between the ZB and WZ phases, leading to a good oxidation ability and charge separation.