Falkenbergjacobs6099

The X-ray diffraction spectra and scanning electron micrographs of the hydration products of the SAC-MKPC clinker showed that AFt and K-struvite crystals coexisted and adhered to form a dense structure. This work provides an innovative idea to produce green cementitious material using industrial solid wastes and may promote the sustainable development of the power and mining industries.The dynamics of transient plasma generated by UV ns-laser ablation of selected metals (Co, Cu, Ag, Bi) were investigated by the Langmuir Probe method in angle- and time-resolved modes. Multiple ionic and electronic structures were seen for all plasmas with some corresponding to anions or nanoparticle-dominated structures. The addition of an Ar atmosphere energetically confined the plasma and increased the charge density by several orders of magnitude. For pressure ranges exceeding 0.5 Pa fast ions were generated in the plasma as a result of Ar ionization and acceleration in the double layer defining the front of the plasma plume. Several correlations between the target nature plasma properties were attempted. The individual plasma structure expansion velocity increases with the melting point and decreases with the atomic mass while the corresponding charged particle densities decrease with the melting point, evidencing the relationship between the volatility of the sample and the overall abated mass.The fuel cell operation is associated with significant current density and durability problems, among other anode collectors. We used a numerical model based on flows with chemical reactions in a porous medium to solve these problems. We tested four variants of the anode channels. In the shape of the anode channel, we introduced changes to improve the current density. We also examined the influence of the channel shape on the stress field and rheological processes in the casing material. We verified the numerical model on the experimental data. Furthermore, we corrected the amount of the hydrogen stream and the produced water in the whole range of the cell's operation. The test results show that it is possible to increase the current density in all operating fields of the fuel cell while maintaining a low mechanical load on graphite elements and their safe operation time.A near 1-keV photons from the Xe/He plasma produced by the interaction of laser beam with a double stream gas puff target were employed for studies of L absorption edges of period 4 transitional metals with atomic number Z from 26 to 30. The dual-channel, compact NEXAFS system was employed for the acquisition of the absorption spectra. L1-3 absorption edges of the samples were identified in transmission mode using broadband emission from the Xe/He plasma to show the applicability of such source and measurement system to the NEXAFS studies of the transition metals, including magnetic materials.The aim of the research was to check whether the system of three fluxes based on lithium aluminium silicate and alkali feldspars has a eutectic point, i.e., with the lowest melting temperature. Lithium was introduced into the mixtures in the form of petalite, which occurs naturally in nature (Bikita Zimbabwe deposit). Using naturally occurring raw materials such as petalite, sodium feldspar, and potassium feldspar, an attempt was made to obtain eutectics with the lowest melting point to facilitate thermal processing of the mineral materials. In addition, the high-temperature viscosity of the mineral alloys and physical parameters such as density, linear shrinkage, and open porosity were studied. The study showed that in these systems, there is one three-component eutectic at 1345 °C, with the lowest viscosity of 1·105 Pas and the highest density of 2.34g/cm3, with a weight content of petalite 20%, sodium feldspar 20%, and potassium feldspar 20%.Among the unique opportunities and developments that are currently being triggered by the fourth industrial revolution, developments in cutting tools have been following the trend of an ever more holistic control of manufacturing processes. Sustainable manufacturing is at the forefront of tools development, encompassing environmental, economic, and technological goals. The integrated use of sensors, data processing, and smart algorithms for fast optimization or real time adjustment of cutting processes can lead to a significant impact on productivity and energy uptake, as well as less usage of cutting fluids. Diamond is the material of choice for machining of non-ferrous alloys, composites, and ultrahard materials. While the extreme hardness, thermal conductivity, and wear resistance of CVD diamond coatings are well-known, these also exhibit highly auspicious sensing properties through doping with boron and other elements. The present study focuses on the thermal response of boron-doped diamond (BDD) coatings in-situ temperature monitoring.The use of alternative cementitious binders is necessary for producing sustainable concrete. Herein, we study the effect of using alternative cementitious binders in ultra-high-performance concrete (UPHC) by calculating the phase assemblages of UHPC in which Portland cement is replaced with calcium aluminate cement, calcium sulfoaluminate cement, metakaolin or blast furnace slag. The calculation result shows that replacing Portland cement with calcium aluminate cement or calcium sulfoaluminate cement reduces the volume of C-S-H but increases the overall solid volume due to the formation of other phases, such as strätlingite or ettringite. The modeling result predicts that using calcium aluminate cement or calcium sulfoaluminate cement may require more water than it would for plain UHPC, while a similar or lower amount of water is needed for chemical reactions when using blast furnace slag or metakaolin.We report on thermal stability and phase transition behaviors of triangular Au nanoprisms through in situ heating transmission electron microscopy. With rising temperature, Au nanoprisms exhibit fluctuating surface reconstructions at the corner regions. When a quasi-melting state is reached at the temperature below bulk melting points, the evaporation is initiated commonly at a corner with low curvature and containing sharp intersection points. The subsequent annealing process leads to the gradual evaporation, which, in the absence of thick carbon coverages, is accompanied by marked shape reconstructions. The thermal stability and evaporation behaviors are not evidently regulated by nanoprism aggregations.This study carried out modeling of the contact between a pair of antagonist teeth with/without individual mouthguards with different geometric configurations. Comparisons of the stress-strain state of teeth interacting through a multilayer mouthguard EVA and multilayer mouthguards with an A-silicon interlayer were performed. The influence of the intermediate layer geometry of A-silicone in a multilayer mouthguard with an A-silicon interlayer on the stress-strain state of the human dentition was considered. The teeth geometry was obtained by computed tomography data and patient dental impressions. The contact 2D problem had a constant thickness, frictional contact deformation, and large deformations in the mouthguard. The strain-stress analysis of the biomechanical model was performed by elastoplastic stress-strain theory. Four geometric configurations of the mouthguard were considered within a wide range of functional loads varied from 50 to 300 N. The stress-strain distributions in a teeth pair during contact interaction at different levels of the physiological loads were obtained. The dependences of the maximum level of stress intensity and the plastic deformation intensity were established, and the contact parameters near the occlusion zone were considered. It was found that when using a multilayer mouthguard with an A-silicone interlayer, there is a significant decrease in the stress intensity level in the hard tissues of the teeth, more than eight and four times for the teeth of the upper and lower teeth, respectively.On-chip exciting electric modes in individual plasmonic nanostructures are realized widely; nevertheless, the excitation of their magnetic counterparts is seldom reported. Here, we propose a highly efficient on-chip excitation approach of the magnetic dipole mode of an individual split-ring resonator (SRR) by integrating it onto a photonic crystal nanocavity (PCNC). A high excitation efficiency of up to 58% is realized through the resonant coupling between the modes of the SRR and PCNC. A further fine adjustment of the excited magnetic dipole mode is demonstrated by tuning the relative position and twist angle between the SRR and PCNC. Finally, a structure with a photonic crystal waveguide side-coupled with the hybrid SRR-PCNC is illustrated, which could excite the magnetic dipole mode with an in-plane coupling geometry and potentially facilitate the future device application. Our result may open a way for developing chip-integrated photonic devices employing a magnetic field component in the optical field.Environmental pollution today is a latent risk for humanity, here the need to recycle waste of all kinds. This work is related to the kinetic study of the leaching of gold and copper contained in waste electrical and electronic equipment (WEEE) and silver contained in mining wastes (MW), using the O2-thiosemicarbazide system. The results obtained show that this non-toxic leaching system is adequate for the leaching of said metals. Reaction orders were found ranging from 0 (Cu), 0.93 (Ag), and 2.01 (Au) for the effect of the reagent concentration and maximum recoveries of 77.7% (Cu), 95.8% (Au), and 60% (Ag) were obtained. Likewise, the activation energies found show that the leaching of WEEE is controlled by diffusion (Cu Ea = 9.06 and Au Ea = 18.25 kJ/Kmol), while the leaching of MW (Ea = 45.55 kJ/Kmol) is controlled by the chemical reaction. For the case of stirring rate, it was found a low effect and only particles from WEEE and MW must be suspended in solution to proceed with the leaching. The pH has effect only at values above 8, and finally, for the case of MW, the O2 partial pressure has a market effect, going the Ag leaching from 33% at 0.2 atm up to 60% at a 1 atm.The paper presents the results of experimental studies on the impact of impulse shot peening parameters on surface roughness (Sa, Sz, Sp, Sv), surface layer microhardness, and the mean positron lifetime (τmean). In the study, samples made of the Inconel 718 nickel alloy were subjected to impulse shot peening on an originally designed stand. The variable factors of the experiment included the impact energy, the diameter of the peening element, and the number of impacts per unit area. The impulse shot peening resulted in changes in the surface structure and an increase in surface layer microhardness. After the application of impulse shot peening, the analyzed roughness parameters increased in relation to post-milling values. Sapanisertib mouse An increase in microhardness was obtained, i.e., from 27 HV 0.05 to 108 HV 0.05 at the surface, while the maximum increase the microhardness occur at the depth from 0.04 mm to 0.08 mm. The changes in the physical properties of the surface layer were accompanied by an increase in the mean positron lifetime τmean.