Edmondsonwentworth3180

In this study, lincomycin residue (LR, a type of antibiotic mycelial residue) derived hydrochar samples (LR-HCs) were obtained from hydrothermal carbonization (HTC), and pyrolysis applied to these LR-HCs to produce activated pyrolyzed samples (LR-APs). Transformation of phosphorus (P) and nitrogen (N) species during HTC and pyrolysis was of primary interest and characterized by several techniques. Nitrogen content of dry LR was calculated by elemental analysis, being 7.91 wt. %, decreasing to 2.51 after HTC and 1.12 wt. % after concesutive HTC and pyrolysis. FT-IR analysis provided evidence for amine groups in LR samples. XPS analysis described N species (Pyridinic-N, Amine-N, Protein-N, Pyrrolic-N, and Quaternary-N) and P species (ortho-P/pyro-P and Ar-P) in LR samples, effectively. Sequential extraction showed that the HTC and pyrolysis changed the proportion of the P species from labile (P-NaHCO3 and P-NaOH) to stable ones (P-residue). Utilization and suitability of as-prepared LR-HCs and LR-APs for heavy metal Pb (II) immobilization show promising results. To help understand immobilization process, kinetic (pseudo-1st-order and pseudo-2nd-order) and isotherm (Freundlich) models were tested and verified. Results confirmed that P and N species were transformed during HTC and pyrolysis and that these processes lead to an advantageous effect on Pb (II) removal from solution. Cadmium is toxic to humans, although Cd-based quantum dots exerts less toxicity. Human hepatocellular carcinoma cells (HepG2) and macrophages (THP-1) were exposed to ionic Cd, Cd(II), and cadmium sulfide quantum dots (CdS QDs), and cell viability, cell integrity, Cd accumulation, mitochondrial function and miRNome profile were evaluated. Cell-type and Cd form-specific responses were found CdS QDs affected cell viability more in HepG2 than in THP-1; respective IC20 values were ∼3 and ∼50 μg ml-1. In both cell types, Cd(II) exerted greater effects on viability. Mitochondrial membrane function in HepG2 cells was reduced 70 % with 40 μg ml-1 CdS QDs but was totally inhibited by Cd(II) at corresponding amounts. In THP-1 cells, CdS QDs has less effect on mitochondrial function; 50 μg ml-1 CdS QDs or equivalent Cd(II) caused 30 % reduction or total inhibition, respectively. The different in vitro effects of CdS QDs were unrelated to Cd uptake, which was greater in THP-1 cells. For both cell types, changes in the expression of miRNAs (miR-222, miR-181a, miR-142-3p, miR-15) were found with CdS QDs, which may be used as biomarkers of hazard nanomaterial exposure. The cell-specific miRNome profiles were indicative of a more conservative autophagic response in THP-1 and as apoptosis as in HepG2. The monitoring of soil contamination deriving from oil and gas industry remains difficult in vegetated areas. Over the last decade, optical remote sensing has proved helpful for this purpose. By tracking alterations in vegetation biochemistry through its optical properties, multi- and hyperspectral remote sensing allow detecting and quantifying crude oil and petroleum products leaked following accidental leakages or bad cessation practices. Recent advances in this field have led to the development of various methods that can be applied either in the field using portable spectroradiometers or at large scale on airborne and satellite images. Experiments carried out under controlled conditions have largely contributed to identifying the most important factors influencing the detection of oil (plant species, mixture composition, etc.). In a perspective of operational use, an important effort is still required to make optical remote sensing a reliable tool for oil and gas companies. The current methods used on imagery should extend their scope to a wide range of contexts and their application to upcoming satellite-embedded hyperspectral sensors should be considered in future studies. In the present study, the levels of bisphenol A (BPA) and analagous compounds in muscle and liver of fish (Dicentrarchus labrax, Trachurus trachurus, Scomber colias) from the North East Atlantic Ocean were determined and the risk of their consumption by humans was assessed. The potential relationship between bisphenol concentrations and microplastic (MP) contamination of fish was also investigated. Fish from all the species had BPA in the liver and muscle, and bisphenol B (BPB) and bisphenol E (BPE) in the muscle. The highest concentration of BPA in the liver (302 ng/g dry weight - dw) was found in S. colias and the lowest one (5 ng/g dw) in T. trachurus. In the muscle, the bisphenol with the highest concentration was BPE in S. colias (272 ng/g dw). Fish with microplastics had significantly higher concentrations of bisphenols than fish where no microplastics were found, suggesting a relation between MP and bisphenol contamination in fish. In all species, the concentration of bisphenols was correlated with higher MP intake. Regarding human food safety, the estimated daily intake (EDI), target hazard quotient (THQ) and hazard index (HI) of bisphenols were higher than those established by the European Food Safety Authority suggesting hazardous risk for human consumers. These findings highlight the need of more research on fish contamination by MP and associated chemicals and inherent human food safety risks. The removal of particulate matters (PM) has emerged as one of the most significant issues in public health and environment worldwide. Environmentalists have proposed the use of indoor air-purifying plants as an eco-friendly strategy to resolve PM-related problems and effectively remove fine particulate matter (PM2.5). Among air-purifying plants, Tillandsia usneoides (L.) L. (T. usneoides) has been used as a biomonitor for heavy metals and air pollutants. However, the PM removal effect of T. usneoides and its primary mechanism remain unclear. Here, we investigated the PM removal performance of T. usneoides in a closed chamber under flow conditions, the effects of trichomes, and the array density according to the different types of PM. The chamber with bulk T. usneoides under flow conditions exhibited 16.5 % and 9.2 % higher removal efficiency in PM2.5T. selleck chemical usneoides for incense and A1 rigid PM, respectively, than that without T. usneoides. T. usneoides with trichome structure exhibited larger removal efficiencies of 7% and 2% in PM2.