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e., [Ba2+]  less then  10 mg/L and [Ra2+]  less then  50 pCi/L). Seeding the reactor with barium sulfate enhanced Ba2+ and Ra2+ removal through induced heterogeneous precipitation of barite. However, it was necessary to simultaneously adjust the Sr/Ba ratio and barite level to achieve treatment requirements while maintaining reasonable detention time in the reactor (i.e., less then 30 min) and minimizing sludge production. Experimental and modeling results revealed that low Ba2+ and Ra2+ effluent concentrations, with minimized sludge production, can be achieved only when the barium sulfate saturation index was above 4.7, Sr/Ba molar ratio was below 2 and there was at least 25 g/L of barite "seed" in the system. This study provides useful guidelines for centralized wastewater treatment facilities in shale plays and serves to optimize pretreatment of produced water to enable recovery of valuable resources (i.e., clean water and usable salts). Proper granular activated carbon (GAC) selection could improve the performance of biological activated carbon (BAC) filters through a combination of adsorption and biodegradation, while the GACs used in BAC filters are now mainly selected according to adsorption function, ignoring biodegradation. In this study, sand filter effluent obtained from a drinking water treatment plant was fed into continuous-flow bench-scale BAC columns operated in parallel over 245 days to examine the effects of GAC pore-size distribution on BAC filter performance, in terms of the dissolved organic carbon (DOC) and disinfection byproduct (DBP) precursors. A metagenomic analysis indicated that bacterial community structure played an important role in BAC filter performance. A significant correlation was found between metabolism-related proteins and the volume of micro-level macropores based on metaproteomic analysis. It is suggested that the adsorption saturation was dynamic and that adsorption played a role in the performance of the BAC filters throughout the 245-day operating period. Renewed adsorption capacity, or bioregeneration, was driven by bacterial metabolic activity. Such activity largely depended on the organic matter adsorbed by the GAC, in which micro-level macropores, especially those with diameters of 0.2-10 μm, played an important but previously unrecognized role. this website The results suggest that more attention should be paid to well-developed pores and pore-size distribution in the production and selection of GAC used for full-scale drinking water biofilters. In this paper we describe the preparation and testing of a new class of chitosan-based flocculants for the treatment of surface waters containing antibiotic compounds. Three forms of moderately hydrophobic chitosan flocculants (MHCs) were prepared by chemically grafting hydrophobic branches with different lengths onto hydrophilic chitosan and these were evaluated by jar tests and a bench-scale continuous flow ultrafiltration (UF) membrane process with coagulation/sedimentation pre-treatment. Tests were conducted using both synthetic and real surface water in which norfloxacin and tylosin were added as representative antibiotics at an initial concentration of 0.1 μg/L. In jar tests, the MHCs achieved similar high removal efficiencies (REs) of turbidity and UV254 absorbance, but much higher REs of the two antibiotics (71.7-84.7% and 68.7-76.6% for synthetic and river waters, respectively), compared to several commercial flocculants; the superior performance was attributed to an enhanced hydrophobic interaction and H-bonding between the flocculants and antibiotics. The presence of suspended kaolin particles and humic acid enhanced the antibiotic removal, speculated to be through MHC bridging of the kaolin/humic acid and antibiotic molecules. In the continuous flow tests involving flocculation/sedimentation-UF for 40 days, an optimal MHC achieved a much greater performance than polyaluminium chloride in terms of the overall removal of antibiotics (RE (norfloxacin) of ∼90% and RE (tylosin) of ∼80%) and a greatly reduced rate of membrane fouling; the latter resulting from a more porous and looser structure of cake layer, caused by a surface-modification-like effect of residual MHC on the hydrophobic PVDF membrane. The results of this study have shown that MHCs offer a significant advance over the use of existing flocculants for the treatment of surface water. Sand filtration is widely used in drinking water treatment processes, yet the hydraulic fundamentals at particle-scale are not well defined, especially the fluid velocity profile near the sand particles surface. In this study, a numerical model is developed by combining the Lattice Boltzmann (LBM) and the Discrete Element Method (DEM), used to describe the fluid flow over the sand particles surface and the micro-structure details of the sand packed bed respectively. The model is validated by comparing the simulation results with the experimental measurements using two systems, showing that the model can describe the fluid velocity distribution around the particles surface. Critical flow velocity is introduced as the balance between hydrodynamic and adhesive torques acting on sand particle surface. Furthermore, a new concept - effective filter surface (EFS), is defined as the area where the velocity near sand particles surface is less than the critical flow velocity, aiming for indirectly evaluating the performance of sand filtration. It is quantitatively demonstrated that increasing the sand particle size or feed flow velocity results in the decrease of both critical flow velocity and EFS under the given tested conditions. The LBM-DEM model provides a useful tool for understanding the fundamentals of liquid flow distribution and also estimating sand filtration performance under different operation conditions. Commercially available powdered activated carbon (PAC) with a median diameter of 12-42 μm was ground into 1 μm sized superfine PAC (SPAC) and 200 nm sized submicron SPAC (SSPAC) and investigated as a pretreatment material for the prevention of hydraulically irreversible membrane fouling during a submerged microfiltration (MF) process. Compared with PAC and SPAC, SSPAC has a high capacity for selective biopolymer adsorption, which is a characteristic found in natural organic matter and is commonly considered to be a major contributor to membrane fouling. Precoating the membrane surface with SSPAC during batch filtration further removes the biopolymers by straining them out. In lab-scale membrane filtration experiments, an increase in the transmembrane pressure (TMP) was almost completely prevented through a precoating with SSPAC based on its pulse dose after coagulation pretreatment. The precoated SSPAC formed a dense layer on the membrane preventing biopolymers from attaching to the membrane. Coagulation pretreatment enabled the precoated activated carbon to be rinsed off during hydraulic backwashing.