Dunnlemming9277

Therefore, Al-modified biochar can be considered a reliable sorbent in real-world application for the removal of SMX and SPY from wastewater.Soil geochemical data is compositional. Hence the studies targeting the potential of accumulation of toxic elements (TE) in plants have to consider the compositional nature of soil chemical environment. In this study, the combined application of compositional data analysis and geospatial mapping was used to investigate Pb geochemical associations in agricultural soils, revealing the link between these associations and Pb contents in plants, as well as identifying source-specific transfer of Pb from soil to plants. The obtained results showed that soil chemical composition was conditioned by the geological peculiarities of the study area and the potential sources of chemical elements' release. Particularly, k-means clustering and CoDa-biplot allows to identify three distinct subsamples and the application of HCA showed that both Pb soil and plants contents were in the same cluster in all subsamples. However, the geochemical association of elements in subsamples I and III suggested that Pb contents in plants were conditioned by the geochemical behaviors of carbonates whereas in subsample II Pb plant contents were presented in a geochemical association (K, Rb, Pb, and Zn) typical for both fertilizers and the potassium feldspar. The transfer factor (TF) for the comparatively higher values is observed for the subsample linked to K, Rb, Pb, and Zn geochemical association. At the same time, the negative influence of carbonates on the Pb availability in the plants was evidenced. The results of this study can serve as a good example for other investigations targeting the role of soil chemical elements compositional features in elements transfer to plant.Presence of excessive phosphorus in surface waters is the main cause for eutrophication. In this study, a lanthanum/chitosan (La/CS) bead was prepared so as to provide a cost-effective solution to the problem. C176 The optimization of bead for the treatment was conducted, leading to the optimal condition 30 wt% La/CS bead at a dosage of 30 g L-1 (wet weight). A higher phosphate removal around 90% was obtained in pH 4.0-10.0. Most of uptake occurred in the first 2 h and the equilibrium was reached in about 6 h. Coexisting ions of Cl-, [Formula see text] , [Formula see text] , and [Formula see text] had negligible effects on the treatment, while the presence of F- reduced the uptake by 10.39%. The maximum adsorption capacity of 261.1 mg-PO4·g-1 (dried weight) at pH 5.0 was achieved, which is much better than many reported La-based adsorbents. The adsorbed phosphate can be effectively recovered with an alkaline solution. A multi-cycle regeneration-reuse study illustrated that the treated water still met the phosphorus discharge standard. The characterization results demonstrated the disappearance of La(OH)3 and La2(CO3)3 on the bead and the formation of NH3+ … P and La-P groups after the adsorption, indicating the significant roles of ion exchange and electrostatic attraction on the uptake. The excellent performance found in this study clearly indicates that the optimized La/CS bead is promising in the treatment of phosphate and perhaps its recovery for industrial use.The growing needs of the rising population and blatant misuse of resources have contributed enormously to environmental problems. Among the various methods, photocatalysis has emerged as one of the effective remediation methods. The continuous search for effective photocatalysts that can be made from abundant, cheap, non-toxic materials is going on. Although sulfur is a known insulator, recent sulfur use as a visible light photocatalyst has ushered a new era in this direction. Sulfur is a non-toxic, cheap, and abundant photocatalyst, exhibiting significant photocatalytic properties. But, hydrophobicity, poor light-harvesting and high recombination rate of charge carriers in elemental sulfur photocatalyst are some of the major drawbacks of the elemental sulfur photocatalyst. The photocatalytic activity of sulfur as a single element was low, but various methods such as nanoscaling, heterojunction formation, doping and surface modifications have been used to enhance it. The review highlights sulfur's crystal structure, electronic and optical properties, and morphological changes, making it an excellent visible light photocatalyst. The article points to the limitations of sulfur as a single photocatalyst and various strategies to improve the shortcomings. More recently, there has been an emphasis on the synthesis of metal-free photocatalysts. This review provides its readers with a comprehensive detail of sulfur being used as a dopant in improving the photocatalytic properties of metal-free photocatalysts and their environmental remediation use. Finally, the conclusion and future perspectives for sulfur-based nanostructures are presented.The study assessed the effects of aeration on continuous electrocoagulation (EC) for tetracycline (TCL) removal from river water. Influence of hydraulic retention time (HRT) and initial drug concentration on treatment efficiency was tested. Best conditions for continuous EC operation were 12 min HRT, electrode spacing 2 cm, 9 V, and Al-Al electrode combination. Highest COD removal with non-aerated EC was 59.4% at 1 mg L-1 initial TCL concentration and further increasing TCL concentration decreased COD removal efficiency. Maximum TCL removal was 66.6% at 10 mg L-1 initial TCL concentration with non-aerated EC. Aerated EC enhanced COD and TCL removal to 61.4% and 71.5%, respectively. In XRD and FTIR spectra no new peaks were detected following EC treatment. XRD, FTIR and FESEM-EDS data supported that significant removal of TCL occurred by charge neutralization, entrapment, adsorption and precipitation driven by Al (OH)3 flocs. Pseudo-second order reaction rate constants explained the kinetics of TCL removal from river water. Sludge volume produced with continuous mode EC non-aerated and aerated EC was 31 cm3 and 39 cm3, respectively. Operating cost was estimated to 0.018 US$/m3 for non-aerated EC and 0.025 US$/m3 for aerated EC. EC can be augmented by aeration for enhanced removal of TCL from river water.As an important metal in industry, national defense, and production, nickel widely exists in nature and is also a necessary trace element for human beings and animals. Nickel deficiency will affect the growth and development of animals, the contents of related active substances, enzymes and other essential elements in vivo. However, excessive nickel or longer nickel exposure can induce excessive free radicals (reactive oxygen species and reactive nitrogen) in the body, which can lead to a variety of cell damage, apoptosis and canceration, and ultimately pose negative effects on the health of the body. Among them, the intestinal tract, as the largest interface between the body and the external environment, greatly increases the contact probability between nickel or nickel compounds and the intestinal mucosal barrier, thus, the intestinal structure and function are also more vulnerable to nickel damage, leading to a series of related diseases such as enteritis. Therefore, this paper briefly analyzed the damage mechanism of nickel or its compounds to the intestinal tract from the perspective of four intestinal mucosal barriers mechanical barrier, immune barrier, microbial barrier and chemical barrier, we hope to make a certain theoretical contribution to the further research and the prevention and treatment of nickel related diseases.Nowadays, we are critically facing various environmental issues. Among these, water contamination is the foremost issue, which worsens our health and living organisms in the water. Thus, it is necessary to provide an avenue to minimize the toxic matter through the development of facile technique and harmless photocatalyst. In this review, we intended to uncover the findings associated with various 0D, 1D, and 2D nanostructures featured photocatalysts for advancements in interfacial characteristics and toxic matter degradation. In this context, we evaluated the promising mixed-dimensional 0D/2D, 1D/2D, and 2D/2D bismuth oxyhalides BiOX (X = Cl, Br, and I) integrated TiO2 nanostructure interfaces. Tunable mixed-dimensional interfaces highlighted with higher surface area, more heterojunctions, variation in the conduction and valence band potential, narrowed band gap, and built-in electric field formation between BiOX and TiO2, which exhibits remarkable toxic dye, heavy metals, and antibiotics degradation. Further, this review further examines insights into the charge carrier generation, separation, and shortened charge transfer path at reduced recombination. Considering the advantages of type-II, S-scheme, and Z-scheme charge transfer mechanisms in the BiOX/TiO2, we heightened the combination of various reactive species generation. In a word, the concept of mixed-dimensional BiOX/TiO2 heterojunction interface endows toxic matter adsorption and decomposition into useful products. Challenges and future perspectives are also provided.The ecological impacts of antibiotics and antibiotic resistance genes (ARGs) on water ecology remain elusive in natural environments. We investigated the influence of antibiotics, ARGs and salinity gradient on the surface water ecosystem. Cefquinome (104.2 ± 43.6 ng/L) and cefminox (16.2 ± 7.50 ng/L) cephalosporins were predominant in all sites. Antibiotic contamination was increased in the estuary ecosystems compared to the freshwater ecosystems by 6%. Bacterial diversity could resist changes in salinity, but the relative abundance of some bacterial genera; Pseudoalteromonas, Glaciecola, norank_f__Arcobacteraceae, and Pseudohongiella was increased in the estuary zone (salinity>0.2%). The eukaryotic composition was increased in the subsaline environments ( less then 0.2%), but the higher salinity in the saline zone inhibited the eukaryotic diversity. The relative abundance of ARGs was significantly higher in the estuary than in freshwater ecosystems, and ARGs interactions and mobile elements (aac(6')-Ib(aka_aacA4)-01, tetR-02, aacC, intI1, intI-1(clinic), qacEdelta1-01, and strB) were the predominant factors responsible for the ARGs propagation. Antibiotics associated with corresponding and non-corresponding ARGs and potentially created an adverse environment that increased the predation and pathogenicity of the aquatic food web and inhibited the metabolic functions. Surface water are first-line-ecosystems receiving antibiotics and ARGs hence our findings provided vital insights into understanding their ecological consequences on surface water ecosystems.Many environmental pollutants caused by uncontrolled urbanization and rapid industrial growth have provoked serious concerns worldwide. These pollutants, including toxic metals, dyes, pharmaceuticals, pesticides, volatile organic compounds, and petroleum hydrocarbons, unenviably compromise the water quality and manifest a severe menace to aquatic entities and human beings. Therefore, it is of utmost importance to acquaint bio-nanocomposites with the capability to remove and decontaminate this extensive range of emerging pollutants. Recently, considerable emphasis has been devoted to developing low-cost novel materials obtained from natural resources accompanied by minimal toxicity to the environment. One such component is cellulose, naturally the most abundant organic polymer found in nature. Given bio-renewable sources, natural abundance, and impressive nanofibril arrangement, cellulose-reinforced composites are widely engineered and utilized for multiple applications, such as wastewater decontamination, energy storage devices, drug delivery systems, paper and pulp industries, construction industries, and adhesives, etc.